With the principles of microwave circuits and semiconductor device physics, two microwave power device test circuits combined with a test fixture are designed and simulated, whose properties are evaluated by a paramet...With the principles of microwave circuits and semiconductor device physics, two microwave power device test circuits combined with a test fixture are designed and simulated, whose properties are evaluated by a parameter network analyzer within the frequency range from 3 to 8GHz. The simulation and experimental results verify that the test circuit with a radial stub is better than that without. As an example, a C-band AlGaN/GaN HEMT microwave power device is tested with the designed circuit and fixture. With a 5.4GHz microwave input signal,the maximum gain is 8.75dB,and the maximum output power is 33.2dBm.展开更多
GaN高电子迁移率晶体管(HEMT)器件受制于陷阱效应,建立准确的非线性模型非常困难。介绍了表面势物理基高电子迁移率高级电路模型(ASM-HEMT),分析了标准ASM-HEMT模型在表征陷阱效应方面的不足,进而建立了新的陷阱模型电路拓扑及模型方程...GaN高电子迁移率晶体管(HEMT)器件受制于陷阱效应,建立准确的非线性模型非常困难。介绍了表面势物理基高电子迁移率高级电路模型(ASM-HEMT),分析了标准ASM-HEMT模型在表征陷阱效应方面的不足,进而建立了新的陷阱模型电路拓扑及模型方程,新陷阱模型可以更好地表征器件陷阱俘获和释放电子的不对称性。基于0.25μm GaN HEMT器件,进行了脉冲I-V、多偏置S参数、负载牵引仿真及测试,并对新模型进行参数提取和建模。经过对比仿真和测试结果发现,新模型的仿真结果与实测结果比标准ASM-HEMT模型更加吻合,说明新模型表征陷阱效应更加准确,提升了模型的准确性,进而提高GaN HEMT功率放大器设计仿真的准确性。展开更多
The electrochemical migration(ECM) behavior and mechanism of immersion silver processing circuit board(PCB-ImAg)and hot air solder leveling circuit board(PCB-HASL) under the 0.1 mol/L Na2SO4 absorbed thin liquid...The electrochemical migration(ECM) behavior and mechanism of immersion silver processing circuit board(PCB-ImAg)and hot air solder leveling circuit board(PCB-HASL) under the 0.1 mol/L Na2SO4 absorbed thin liquid films with different thicknesses were investigated using stereo microscopy and scanning electron microscopy(SEM).Meanwhile,the corrosion tendency and kinetics rule of metal plates after bias application were analyzed with the aid of electrochemical impedance spectroscopy(EIS)and scanning Kelvin probe(SKP).Results showed that under different humidity conditions,the amount of migrating corrosion products of silver for PCB-ImAg was limited,while on PCB-HASL both copper dendrites and precipitates such as sulfate and metal oxides of copper/tin were found under a high humidity condition(exceeding 85%).SKP results indicated that the cathode plate of two kinds of PCB materials had a higher corrosion tendency after bias application.An ECM model involving multi-metal reactions was proposed and the differences of ECM behaviors for two kinds of PCB materials were compared.展开更多
Two-dimensional single-crystalline p-n junctions of organic semiconductors(pn-2 DCOSs) show great potential in organic logic circuits due to their single crystal nature and excellent ambipolar charge transport. Howeve...Two-dimensional single-crystalline p-n junctions of organic semiconductors(pn-2 DCOSs) show great potential in organic logic circuits due to their single crystal nature and excellent ambipolar charge transport. However,there are only few reports on pn-2 DCOSs because it is difficult to obtain such highly ordered structure in p-n junction.Herein, a novel and effective solution processing method of secondary transfer technology based on the facile drop casting is used to fabricate devices of pn-2 DCOSs based on C8-BTBT(p-type) and TFT-CN(n-type) successfully. The high-performance ambipolar field transistors based on such ultrathin pn-2 DCOSs with several molecular layers thickness show wellbalanced ambipolar charge transport behaviors with hole mobility as high as 0.43 cm^2 V^-1 s^-1 and electron mobility up to 0.11 cm^2 V^-1 s(^-1), respectively. This work is essential for studying the intrinsic properties of organic p-n junctions and achieving high performance in organic complementary circuits.展开更多
Ternary strategy has been considered as an efficient method to achieve high performance polymer solar cells(PSCs). A power conversion efficiency(PCE) of 17.22% is achieved in the optimized ternary PSCs with10 wt% MF1 ...Ternary strategy has been considered as an efficient method to achieve high performance polymer solar cells(PSCs). A power conversion efficiency(PCE) of 17.22% is achieved in the optimized ternary PSCs with10 wt% MF1 in acceptors. The over 8% PCE improvement by employing ternary strategy is attributed to the simultaneously increased JSCof 25.68 mA cm^-2, VOCof 0.853 V and FF of 78.61% compared with Y6 based binary PSCs. The good compatibility of MF1 and Y6 can be confirmed from Raman mapping, contact angle,cyclic voltammetry and morphology, which is the prerequisite to form alloy-like state. Electron mobility in ternary active layers strongly depends on MF1 content in acceptors due to the different lowest unoccupied molecular orbital(LUMO) levels of Y6 and MF1, which can well explain the wave-like varied FF of ternary PSCs. The third-party certified PCE of 16.8% should be one of the highest values for single bulk heterojunction PSCs. This work provides sufficient references for selecting materials to achieve efficient ternary PSCs.展开更多
Three new electron donating small molecules (SMs), Pyr(EH-DPP)2, Pyr(HD-DPP)2 and PyrA(EH-DPP)2, are designed and synthesized through coupling electron rich pyrene core with electron deficient diketopyrrolopyr...Three new electron donating small molecules (SMs), Pyr(EH-DPP)2, Pyr(HD-DPP)2 and PyrA(EH-DPP)2, are designed and synthesized through coupling electron rich pyrene core with electron deficient diketopyrrolopyrrole (DPP) terminals, of which the derived organic solar cells (OSCs) exhibit interesting structure-performance correlation. It shows that the tune of their solubilizing side chains and n-bridge for the acceptor-donor-acceptor (A-D-A) SMs can significantly alter the resultant short-circuit current density and power conversion efficiency (PCE) in OSCs. The Pyr(EH-DPP)2 with short side chains displays broader absorption and higher hole mobility than the Pyr(HD-DPP)2 with long side chains. Although showing planar structure, the acetylene bridge-incorporated PyrA(EH-DPP)2 adapts an undesired edge-on packing and strong aggregation in film, leading to non-ideal morphology and poor miscibility with fullerene acceptors. As a result, the PCE of the solar cell based on Pyr(EH-DPP)2 is several times higher than those based on Pyr(HD-DPP): and PyrA(EH-DPP)2, indicating the A-D-A combination of polyaromatics with DPP would be the promising skeleton for developing photovoltaic semiconductors.展开更多
文摘With the principles of microwave circuits and semiconductor device physics, two microwave power device test circuits combined with a test fixture are designed and simulated, whose properties are evaluated by a parameter network analyzer within the frequency range from 3 to 8GHz. The simulation and experimental results verify that the test circuit with a radial stub is better than that without. As an example, a C-band AlGaN/GaN HEMT microwave power device is tested with the designed circuit and fixture. With a 5.4GHz microwave input signal,the maximum gain is 8.75dB,and the maximum output power is 33.2dBm.
文摘GaN高电子迁移率晶体管(HEMT)器件受制于陷阱效应,建立准确的非线性模型非常困难。介绍了表面势物理基高电子迁移率高级电路模型(ASM-HEMT),分析了标准ASM-HEMT模型在表征陷阱效应方面的不足,进而建立了新的陷阱模型电路拓扑及模型方程,新陷阱模型可以更好地表征器件陷阱俘获和释放电子的不对称性。基于0.25μm GaN HEMT器件,进行了脉冲I-V、多偏置S参数、负载牵引仿真及测试,并对新模型进行参数提取和建模。经过对比仿真和测试结果发现,新模型的仿真结果与实测结果比标准ASM-HEMT模型更加吻合,说明新模型表征陷阱效应更加准确,提升了模型的准确性,进而提高GaN HEMT功率放大器设计仿真的准确性。
基金Project(51271032)supported by the National Natural Science Foundation of China
文摘The electrochemical migration(ECM) behavior and mechanism of immersion silver processing circuit board(PCB-ImAg)and hot air solder leveling circuit board(PCB-HASL) under the 0.1 mol/L Na2SO4 absorbed thin liquid films with different thicknesses were investigated using stereo microscopy and scanning electron microscopy(SEM).Meanwhile,the corrosion tendency and kinetics rule of metal plates after bias application were analyzed with the aid of electrochemical impedance spectroscopy(EIS)and scanning Kelvin probe(SKP).Results showed that under different humidity conditions,the amount of migrating corrosion products of silver for PCB-ImAg was limited,while on PCB-HASL both copper dendrites and precipitates such as sulfate and metal oxides of copper/tin were found under a high humidity condition(exceeding 85%).SKP results indicated that the cathode plate of two kinds of PCB materials had a higher corrosion tendency after bias application.An ECM model involving multi-metal reactions was proposed and the differences of ECM behaviors for two kinds of PCB materials were compared.
基金financially supported by the Ministry of Science and Technology of China (2016YFB0401100 and 2017YFA0204503)the National Natural Science Foundation of China (51633006, 51725304, 51733004 and 51703159)the Strategic Priority Research Program of the Chinese Academy of Sciences (XDB12030300)
文摘Two-dimensional single-crystalline p-n junctions of organic semiconductors(pn-2 DCOSs) show great potential in organic logic circuits due to their single crystal nature and excellent ambipolar charge transport. However,there are only few reports on pn-2 DCOSs because it is difficult to obtain such highly ordered structure in p-n junction.Herein, a novel and effective solution processing method of secondary transfer technology based on the facile drop casting is used to fabricate devices of pn-2 DCOSs based on C8-BTBT(p-type) and TFT-CN(n-type) successfully. The high-performance ambipolar field transistors based on such ultrathin pn-2 DCOSs with several molecular layers thickness show wellbalanced ambipolar charge transport behaviors with hole mobility as high as 0.43 cm^2 V^-1 s^-1 and electron mobility up to 0.11 cm^2 V^-1 s(^-1), respectively. This work is essential for studying the intrinsic properties of organic p-n junctions and achieving high performance in organic complementary circuits.
基金This work was supported by the National Natural Science Foundation of China(61805009,61675017,61975006)China Postdoctoral Science Foundation(2018M641170)+1 种基金Beijing Natural Science Foundation(4192049)The authors gratefully acknowledge the assistance of the Shanghai Synchrotron Radiation Facility(beamline BL16B1)for GWAIXS and GISAXS measurements.
文摘Ternary strategy has been considered as an efficient method to achieve high performance polymer solar cells(PSCs). A power conversion efficiency(PCE) of 17.22% is achieved in the optimized ternary PSCs with10 wt% MF1 in acceptors. The over 8% PCE improvement by employing ternary strategy is attributed to the simultaneously increased JSCof 25.68 mA cm^-2, VOCof 0.853 V and FF of 78.61% compared with Y6 based binary PSCs. The good compatibility of MF1 and Y6 can be confirmed from Raman mapping, contact angle,cyclic voltammetry and morphology, which is the prerequisite to form alloy-like state. Electron mobility in ternary active layers strongly depends on MF1 content in acceptors due to the different lowest unoccupied molecular orbital(LUMO) levels of Y6 and MF1, which can well explain the wave-like varied FF of ternary PSCs. The third-party certified PCE of 16.8% should be one of the highest values for single bulk heterojunction PSCs. This work provides sufficient references for selecting materials to achieve efficient ternary PSCs.
基金supported by the National Natural Science Foundation of China(51473142,21674093,21374075)the Major State Basic Research Development Program(2014CB643503)International Science and Technology Cooperation Program of China(2016YFE0102900)
文摘Three new electron donating small molecules (SMs), Pyr(EH-DPP)2, Pyr(HD-DPP)2 and PyrA(EH-DPP)2, are designed and synthesized through coupling electron rich pyrene core with electron deficient diketopyrrolopyrrole (DPP) terminals, of which the derived organic solar cells (OSCs) exhibit interesting structure-performance correlation. It shows that the tune of their solubilizing side chains and n-bridge for the acceptor-donor-acceptor (A-D-A) SMs can significantly alter the resultant short-circuit current density and power conversion efficiency (PCE) in OSCs. The Pyr(EH-DPP)2 with short side chains displays broader absorption and higher hole mobility than the Pyr(HD-DPP)2 with long side chains. Although showing planar structure, the acetylene bridge-incorporated PyrA(EH-DPP)2 adapts an undesired edge-on packing and strong aggregation in film, leading to non-ideal morphology and poor miscibility with fullerene acceptors. As a result, the PCE of the solar cell based on Pyr(EH-DPP)2 is several times higher than those based on Pyr(HD-DPP): and PyrA(EH-DPP)2, indicating the A-D-A combination of polyaromatics with DPP would be the promising skeleton for developing photovoltaic semiconductors.