In terms of rock engineering and technology in hydropower construction,the slope stability and monitoring techniques for high slopes of Three Gorges Project,the stability and support technology for high slopes of hydr...In terms of rock engineering and technology in hydropower construction,the slope stability and monitoring techniques for high slopes of Three Gorges Project,the stability and support technology for high slopes of hydropower projects in deep river valley,the stabilization techniques for underground cavern group with large span and high side walls are introduced in this paper.As for rock engineering and technology in highway and railway construction,the Qinghai-Tibet Railway — new construction techniques in permafrost,the support techniques for large squeezing deformation in Wuqiaoling Tunnel,the construction techniques for tunnels in alpine and high-altitude region,the geological prediction techniques for tunnels in karst region,the microseismic monitoring and early warning techniques for rockbursts in deep and long tunnels are presented.For rock engineering and technology inmining engineering,the innovative techniques for roadway support inmines,the simultaneous extraction technique of pillarless coal and gas in coal seams with low permeability,the safe and efficient deep openmining technology,advances in monitoring,early warning and treatment ofmine dynamic disasters are discussed.In addition,the new anchorage techniques and precision blasting technique in rock engineering are introduced.展开更多
The development of stable and efficient visible light-absorbing oxide-based semiconductor photocatalysts is a desirable task for solar water splitting applications.Recently,we proposed that the low photocurrent densit...The development of stable and efficient visible light-absorbing oxide-based semiconductor photocatalysts is a desirable task for solar water splitting applications.Recently,we proposed that the low photocurrent density in film-based BiFeO_(3)(BFO)is due to charge recombination at the interface of the domain walls,which could be largely reduced in particulate photocatalyst systems.To demonstrate this hypothesis,in this work we synthesized particulate BFO and Mn-doped BiFeO_(3)(Mn-BFO)by the sol-gel method.Photocatalytic water oxidation tests showed that pure BFO had an intrinsic photocatalytic oxygen evolution reaction(OER)activity of 70μmol h^(-1) g^(-1),while BFO-2,with an optimum amount of Mn doping(0.05%),showed an OER activity of 255μmol h^(-1) g^(-1) under visible light(λ≥420 nm)irradiation.The bandgap of Mn-doped BFO could be reduced from 2.1 to 1.36 eV by varying the amount of Mn doping.Density functional theory(DFT)calculations suggested that surface Fe(rather than Mn)species serve as the active sites for water oxidation,because the overpotential for water oxidation on Fe species after Mn doping is 0.51 V,which is the lowest value measured for the different Fe and Mn species examined in this study.The improved photocatalytic water oxidation activity of Mn-BFO is ascribed to the synergistic effect of the bandgap narrowing,which increases the absorption of visible light,reduces the activation energy of water oxidation,and inhibits the recombination of photogenerated charges.This work demonstrates that Mn doping is an effective strategy to enhance the intrinsic photocatalytic water oxidation activity of particulate ferroelectric BFO photocatalysts.展开更多
文摘In terms of rock engineering and technology in hydropower construction,the slope stability and monitoring techniques for high slopes of Three Gorges Project,the stability and support technology for high slopes of hydropower projects in deep river valley,the stabilization techniques for underground cavern group with large span and high side walls are introduced in this paper.As for rock engineering and technology in highway and railway construction,the Qinghai-Tibet Railway — new construction techniques in permafrost,the support techniques for large squeezing deformation in Wuqiaoling Tunnel,the construction techniques for tunnels in alpine and high-altitude region,the geological prediction techniques for tunnels in karst region,the microseismic monitoring and early warning techniques for rockbursts in deep and long tunnels are presented.For rock engineering and technology inmining engineering,the innovative techniques for roadway support inmines,the simultaneous extraction technique of pillarless coal and gas in coal seams with low permeability,the safe and efficient deep openmining technology,advances in monitoring,early warning and treatment ofmine dynamic disasters are discussed.In addition,the new anchorage techniques and precision blasting technique in rock engineering are introduced.
文摘The development of stable and efficient visible light-absorbing oxide-based semiconductor photocatalysts is a desirable task for solar water splitting applications.Recently,we proposed that the low photocurrent density in film-based BiFeO_(3)(BFO)is due to charge recombination at the interface of the domain walls,which could be largely reduced in particulate photocatalyst systems.To demonstrate this hypothesis,in this work we synthesized particulate BFO and Mn-doped BiFeO_(3)(Mn-BFO)by the sol-gel method.Photocatalytic water oxidation tests showed that pure BFO had an intrinsic photocatalytic oxygen evolution reaction(OER)activity of 70μmol h^(-1) g^(-1),while BFO-2,with an optimum amount of Mn doping(0.05%),showed an OER activity of 255μmol h^(-1) g^(-1) under visible light(λ≥420 nm)irradiation.The bandgap of Mn-doped BFO could be reduced from 2.1 to 1.36 eV by varying the amount of Mn doping.Density functional theory(DFT)calculations suggested that surface Fe(rather than Mn)species serve as the active sites for water oxidation,because the overpotential for water oxidation on Fe species after Mn doping is 0.51 V,which is the lowest value measured for the different Fe and Mn species examined in this study.The improved photocatalytic water oxidation activity of Mn-BFO is ascribed to the synergistic effect of the bandgap narrowing,which increases the absorption of visible light,reduces the activation energy of water oxidation,and inhibits the recombination of photogenerated charges.This work demonstrates that Mn doping is an effective strategy to enhance the intrinsic photocatalytic water oxidation activity of particulate ferroelectric BFO photocatalysts.
