Electrochemical impedance(EIS)and thin electrical resistance(ER)sensors were invented for atmospheric corrosion measurement of copper(Cu)during cyclic wetting−drying/high−low temperature tests and field exposure tests...Electrochemical impedance(EIS)and thin electrical resistance(ER)sensors were invented for atmospheric corrosion measurement of copper(Cu)during cyclic wetting−drying/high−low temperature tests and field exposure tests.Three-month field exposure results showed that average corrosion rate of Cu measured by ER sensor was well in accordance with that by weight loss method.During cyclic wetting−drying test,EIS was proven to reflect sensitively time of wetting and drying on the surface of sensor.Although corrosion rate obtained from EIS had a similar tendency to that obtained from ER sensors,the former was more dependent on environmental humidity than the latter.When relative humidity was low than 60%,corrosion rate of Cu measured by EIS was much lower than that by weight loss method,mainly attributing to the fact that impedance sensor failed to detect corrosion current of interlaced Cu electrodes due to the breakdown of conductive passage composed of absorbed thin liquid film under low humidity condition.Promisingly,ER sensor was proven to be more suitable for atmospheric corrosion monitoring than electrochemical techniques because it could sensitively monitor thickness loss of Cu foil according to the Ohmic law,no matter how dry or wet the sensor surface is.展开更多
Holistic tin-plating on the outer conductor is one of the key processes in the manufacture of semi-flexible coaxial cable, which is widely applied to the third generation (3G) mobile communication system. However, in ...Holistic tin-plating on the outer conductor is one of the key processes in the manufacture of semi-flexible coaxial cable, which is widely applied to the third generation (3G) mobile communication system. However, in the traditional horizontal tin-plating process, disadvantages such as the pinhole defects and low productivity effect cannot be avoided. In this paper, a vertical tin-plating process was proposed to reduce the pinhole defects and improve the tincoating quality. Compared with the traditional horizontal tin-plating process, the immersion length was reduced from 300-400 mm to 10-100 mm and the tin-plating time was reduced from 7 s to 3 s in the proposed method. The experimental results indicate that immersion length and time are key parameters for the tin-plating quality. With this new tin-plating process, the experimental results show that the pinhole defects can be eliminated effectively by controlling the immersion depth below 100 mm and tin-plating time at 3 s. The thickness of tin-coating increased from not more than 5 μm to 12.3 μm with the proposed vertical tin-plating process. Meanwhile, the thickness of the intermetallic compounds (IMCs) layer between the tin-coating and copper wires was reduced from 3.26 μm to 0.62 μm if the immersion time decreased from 30 s to 1 s. Besides, a self-developed flux, which possesses a boiling point or decomposed temperature of active components over 300℃, exhibits a better efficiency in reducing the pinhole formation.展开更多
Cu-based catalysts are the most promising candidates for electrochemical CO_(2)reduction(CO_(2)RR)to multi-carbon(C_(2))products.Optimizing the C-C coupling process,the rate-determining step for C_(2)product generatio...Cu-based catalysts are the most promising candidates for electrochemical CO_(2)reduction(CO_(2)RR)to multi-carbon(C_(2))products.Optimizing the C-C coupling process,the rate-determining step for C_(2)product generation,is an important strategy to improve the production and selectivity of the C_(2)products.In this study,we determined that the local electric field can promote the C-C coupling reaction and enhance CO_(2)electroreduction to C_(2)products.First,finite-element simulations indicated that the high curvature of the Cu nanoneedles results in a large local electric field on their tips.Density functional theory(DFT)calculations proved that a large electric field can promote C-C coupling.Motivated by this prediction,we prepared a series of Cu catalysts with different curvatures.The Cu nanoneedles(NNs)exhibited the largest number of curvatures,followed by the Cu nanorods(NRs),and Cu nanoparticles(NPs).The Cu NNs contained the highest concentration of adsorbed K+,which resulted in the highest local electric field on the needles.CO adsorption sensor tests indicated that the Cu NNs exhibited the strongest CO adsorption ability,and in-situ Fourier-transform infrared spectroscopy(FTIR)showed the strongest*COCO and*CO signals for the Cu NNs.These experimental results demonstrate that high-curvature nanoneedles can induce a large local electric field,thus promoting C-C coupling.As a result,the Cu NNs show a maximum FEC_(2)of 44%for CO_(2)RR at a low potential(-0.6 V vs.RHE),which is approximately 2.2 times that of the Cu NPs.This work provides an effective strategy for enhancing the production of multi-carbon products during CO_(2)RR.展开更多
基金the National Natural Science Foundation of China(No.51771079)the China Postdoctoral Science Foundation(No.2020M682650).
文摘Electrochemical impedance(EIS)and thin electrical resistance(ER)sensors were invented for atmospheric corrosion measurement of copper(Cu)during cyclic wetting−drying/high−low temperature tests and field exposure tests.Three-month field exposure results showed that average corrosion rate of Cu measured by ER sensor was well in accordance with that by weight loss method.During cyclic wetting−drying test,EIS was proven to reflect sensitively time of wetting and drying on the surface of sensor.Although corrosion rate obtained from EIS had a similar tendency to that obtained from ER sensors,the former was more dependent on environmental humidity than the latter.When relative humidity was low than 60%,corrosion rate of Cu measured by EIS was much lower than that by weight loss method,mainly attributing to the fact that impedance sensor failed to detect corrosion current of interlaced Cu electrodes due to the breakdown of conductive passage composed of absorbed thin liquid film under low humidity condition.Promisingly,ER sensor was proven to be more suitable for atmospheric corrosion monitoring than electrochemical techniques because it could sensitively monitor thickness loss of Cu foil according to the Ohmic law,no matter how dry or wet the sensor surface is.
基金Supported by Science and Technology Support Project of Tianjin Science and Technology Commission (No.10ZCKFGX3500)
文摘Holistic tin-plating on the outer conductor is one of the key processes in the manufacture of semi-flexible coaxial cable, which is widely applied to the third generation (3G) mobile communication system. However, in the traditional horizontal tin-plating process, disadvantages such as the pinhole defects and low productivity effect cannot be avoided. In this paper, a vertical tin-plating process was proposed to reduce the pinhole defects and improve the tincoating quality. Compared with the traditional horizontal tin-plating process, the immersion length was reduced from 300-400 mm to 10-100 mm and the tin-plating time was reduced from 7 s to 3 s in the proposed method. The experimental results indicate that immersion length and time are key parameters for the tin-plating quality. With this new tin-plating process, the experimental results show that the pinhole defects can be eliminated effectively by controlling the immersion depth below 100 mm and tin-plating time at 3 s. The thickness of tin-coating increased from not more than 5 μm to 12.3 μm with the proposed vertical tin-plating process. Meanwhile, the thickness of the intermetallic compounds (IMCs) layer between the tin-coating and copper wires was reduced from 3.26 μm to 0.62 μm if the immersion time decreased from 30 s to 1 s. Besides, a self-developed flux, which possesses a boiling point or decomposed temperature of active components over 300℃, exhibits a better efficiency in reducing the pinhole formation.
文摘Cu-based catalysts are the most promising candidates for electrochemical CO_(2)reduction(CO_(2)RR)to multi-carbon(C_(2))products.Optimizing the C-C coupling process,the rate-determining step for C_(2)product generation,is an important strategy to improve the production and selectivity of the C_(2)products.In this study,we determined that the local electric field can promote the C-C coupling reaction and enhance CO_(2)electroreduction to C_(2)products.First,finite-element simulations indicated that the high curvature of the Cu nanoneedles results in a large local electric field on their tips.Density functional theory(DFT)calculations proved that a large electric field can promote C-C coupling.Motivated by this prediction,we prepared a series of Cu catalysts with different curvatures.The Cu nanoneedles(NNs)exhibited the largest number of curvatures,followed by the Cu nanorods(NRs),and Cu nanoparticles(NPs).The Cu NNs contained the highest concentration of adsorbed K+,which resulted in the highest local electric field on the needles.CO adsorption sensor tests indicated that the Cu NNs exhibited the strongest CO adsorption ability,and in-situ Fourier-transform infrared spectroscopy(FTIR)showed the strongest*COCO and*CO signals for the Cu NNs.These experimental results demonstrate that high-curvature nanoneedles can induce a large local electric field,thus promoting C-C coupling.As a result,the Cu NNs show a maximum FEC_(2)of 44%for CO_(2)RR at a low potential(-0.6 V vs.RHE),which is approximately 2.2 times that of the Cu NPs.This work provides an effective strategy for enhancing the production of multi-carbon products during CO_(2)RR.
