Two CaCO3-based materials （limestone and clamshells） and steel slag were used as mineral admixtures in cement to produce ternary blends and their influences on hydration and portlandite formation were analyzed. Addi...Two CaCO3-based materials （limestone and clamshells） and steel slag were used as mineral admixtures in cement to produce ternary blends and their influences on hydration and portlandite formation were analyzed. Additionally, mechanical properties were determined. These properties were determined using X-ray diffraction and scanning electron microscopic/energy dispersive X-ray analytical techniques as well as applying methods specified by EN （European Standards） and ASTM （American Standards for Testing and Materials）. The portlandite （Ca（OH）E） content was considerably reduced from 36.9% of reference cement to between 13.79% and 15.5%. With the water demand and setting times of the cements containing up to 10%, admixtures did not change significantly. The mechanical tests results showed that ternary blends produced 2-day strengths higher than that specified by EN 197-1 and that blends containing up to 20% admixtures can be used to produce both Class 32.5N and 42.5N cements.展开更多
Based on the techniques of X-ray diffraction analysis, identification of the thin sections of core cast, phys- ical analysis and scanning electron microscopy analysis, this paper studied the reservoir characteristics ...Based on the techniques of X-ray diffraction analysis, identification of the thin sections of core cast, phys- ical analysis and scanning electron microscopy analysis, this paper studied the reservoir characteristics of the Carboniferous strata in Donghe well No.1 of Tarim region. The results show that the reservoir lithology is mainly the fine-grained quartz sandstone with ferrocalcite and pyrite, mud cement-based, the permeability concentrated in 5-40 × 10-3 μm2, a small part of the high permeability up to 150-327 ×10-3 μm2 and porosity ranged from 10% to 20%. The most part of the reservoirs is low perme- ability with a small part of the layer in moderate-high permeability. The types of reservoir space include intergranular pores, intra particle-molding pores, micro-pores and cracks, which mainly are intergranular pores with the pore diameter of 15-200 μm, 95.5μm on average. And the types of the throats are comolex with the main tvne of constricted l：hroats in this area and large contribution to the permeability.展开更多
The main purpose of this work was to obtain Sm-Sr nickelates nanoparticles with Ruddelsden-Popper type structures obtained by a simple process such as gelatin synthesis. The powders were calcinated at 900 ℃ and chara...The main purpose of this work was to obtain Sm-Sr nickelates nanoparticles with Ruddelsden-Popper type structures obtained by a simple process such as gelatin synthesis. The powders were calcinated at 900 ℃ and characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy and high-resolution transmission electron microscopy techniques. The effect of chemical substitution of the Sm^3＋ by Sr^2＋ ions on the structural properties of the powders was studied. The Rietveld＇s method was successfully applied for determination of the quantitative phase analysis of the powders and revealed that the main phase of the powders for different strontium content is of Ruddelsden-Popper type structure. A symmetry change from orthorhombic to tetragonal is observed as increasing strontium.展开更多
The bio-limited forming technology, a new technology organically integrating microbiology, manufacturing science and materials science, is used in the manufacturing of magnetic or conductive microstructures of differe...The bio-limited forming technology, a new technology organically integrating microbiology, manufacturing science and materials science, is used in the manufacturing of magnetic or conductive microstructures of different standard shapes. This paper explores the feasibility of magnetizing microorganism with thermal decomposition method. The principle of thermal decomposition of iron pentacarbonyl has been adopted to investigate the cells of Spirulina (a type of nature micro-helical microorganism) coated with pure iron. Further analysis have been conducted on the observations results of hollow micro-helical magnetic particles form, components and the phase structure obtained by using various tools including optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray detector (EDX), transmission electron microscopy (TEM), and X-ray diffraction analysis (XRD). Results showed that Spirulina cells could be coated with iron particles after the completion of thermal decomposition process, with well-kept shape of natural helixes and consistent components of different sampling points on the surface layer and thickness of layer. After the heat treatment at 700°C, the type of the surface iron layer formed was α-Fe. The paper also investigates the kinetics of the cell magnetization technology by thermal decomposition.展开更多
Spirulina platensis were chosen as templates to produce microscopic helical soft-core magnetic particles by way of depositing ferromagnetic alloy onto their surface using electroplating technique,and the process of el...Spirulina platensis were chosen as templates to produce microscopic helical soft-core magnetic particles by way of depositing ferromagnetic alloy onto their surface using electroplating technique,and the process of electroplating ferromagnetic alloy onto microorganism cells was studied.The morphology and appearance of the coated Spirulina platensis were analyzed with optical microscopy and scanning electron microscopy,respectively,and the ingredients and phase structure of the alloy coating were analyzed with energy dispersive X-ray detector(EDX) and X-ray diffractive analysis(XRD),respectively.The result showed that the particles were successfully coated with uniform metal coating and their initial helical shape was perfectly replicated.The coating was NiFe alloy,and its phase structure was face-centered cubic structure.The magnetic properties of the coated particles were tested with vibrating sample magnetometer(VSM),and the result showed that the particles were ferro-magnetic,which means the magnetic electroplating of the microorganism cells was successfully achieved.The electrochemical reaction mechanism of the magnetic plating process was also analyzed;the result showed that the deposition of NiFe on the microorganism cells was anomalous codeposition,and that Fe2+ ion was preferential deposited when magnetic stirring was applied.展开更多
文摘Two CaCO3-based materials （limestone and clamshells） and steel slag were used as mineral admixtures in cement to produce ternary blends and their influences on hydration and portlandite formation were analyzed. Additionally, mechanical properties were determined. These properties were determined using X-ray diffraction and scanning electron microscopic/energy dispersive X-ray analytical techniques as well as applying methods specified by EN （European Standards） and ASTM （American Standards for Testing and Materials）. The portlandite （Ca（OH）E） content was considerably reduced from 36.9% of reference cement to between 13.79% and 15.5%. With the water demand and setting times of the cements containing up to 10%, admixtures did not change significantly. The mechanical tests results showed that ternary blends produced 2-day strengths higher than that specified by EN 197-1 and that blends containing up to 20% admixtures can be used to produce both Class 32.5N and 42.5N cements.
基金financially supported by the National Major Special Projects of China (No. 2011ZX05005-002-009HZ)the Natural Science Foundation Project of CQ CSTC of China (No. cstc2012jjA90009)+1 种基金the Research Foundation of Chongqing University of Science & Technology of China (Nos. CK20111312, CK2013Z04)the Program of Educational Reform of Chongqing University of Science & Technology of China (No. 201424).
文摘Based on the techniques of X-ray diffraction analysis, identification of the thin sections of core cast, phys- ical analysis and scanning electron microscopy analysis, this paper studied the reservoir characteristics of the Carboniferous strata in Donghe well No.1 of Tarim region. The results show that the reservoir lithology is mainly the fine-grained quartz sandstone with ferrocalcite and pyrite, mud cement-based, the permeability concentrated in 5-40 × 10-3 μm2, a small part of the high permeability up to 150-327 ×10-3 μm2 and porosity ranged from 10% to 20%. The most part of the reservoirs is low perme- ability with a small part of the layer in moderate-high permeability. The types of reservoir space include intergranular pores, intra particle-molding pores, micro-pores and cracks, which mainly are intergranular pores with the pore diameter of 15-200 μm, 95.5μm on average. And the types of the throats are comolex with the main tvne of constricted l：hroats in this area and large contribution to the permeability.
文摘The main purpose of this work was to obtain Sm-Sr nickelates nanoparticles with Ruddelsden-Popper type structures obtained by a simple process such as gelatin synthesis. The powders were calcinated at 900 ℃ and characterized by X-ray diffraction, thermogravimetric analysis, scanning electron microscopy and high-resolution transmission electron microscopy techniques. The effect of chemical substitution of the Sm^3＋ by Sr^2＋ ions on the structural properties of the powders was studied. The Rietveld＇s method was successfully applied for determination of the quantitative phase analysis of the powders and revealed that the main phase of the powders for different strontium content is of Ruddelsden-Popper type structure. A symmetry change from orthorhombic to tetragonal is observed as increasing strontium.
基金supported by the Foundation for the Author of National Excellent Doctoral Dissertation of PR China (Grant No. 2007B32)the National High Technology Research and Development Program of China (Grant No. 2009AA043804)
文摘The bio-limited forming technology, a new technology organically integrating microbiology, manufacturing science and materials science, is used in the manufacturing of magnetic or conductive microstructures of different standard shapes. This paper explores the feasibility of magnetizing microorganism with thermal decomposition method. The principle of thermal decomposition of iron pentacarbonyl has been adopted to investigate the cells of Spirulina (a type of nature micro-helical microorganism) coated with pure iron. Further analysis have been conducted on the observations results of hollow micro-helical magnetic particles form, components and the phase structure obtained by using various tools including optical microscopy, scanning electron microscopy (SEM), energy dispersive X-ray detector (EDX), transmission electron microscopy (TEM), and X-ray diffraction analysis (XRD). Results showed that Spirulina cells could be coated with iron particles after the completion of thermal decomposition process, with well-kept shape of natural helixes and consistent components of different sampling points on the surface layer and thickness of layer. After the heat treatment at 700°C, the type of the surface iron layer formed was α-Fe. The paper also investigates the kinetics of the cell magnetization technology by thermal decomposition.
基金supported by the National High Technology Research and Development Program of China (Grant No 2009AA043804)Foundation for the Author of National Excellent Doctoral Dissertation of PR China (Grant No 2007B32)
文摘Spirulina platensis were chosen as templates to produce microscopic helical soft-core magnetic particles by way of depositing ferromagnetic alloy onto their surface using electroplating technique,and the process of electroplating ferromagnetic alloy onto microorganism cells was studied.The morphology and appearance of the coated Spirulina platensis were analyzed with optical microscopy and scanning electron microscopy,respectively,and the ingredients and phase structure of the alloy coating were analyzed with energy dispersive X-ray detector(EDX) and X-ray diffractive analysis(XRD),respectively.The result showed that the particles were successfully coated with uniform metal coating and their initial helical shape was perfectly replicated.The coating was NiFe alloy,and its phase structure was face-centered cubic structure.The magnetic properties of the coated particles were tested with vibrating sample magnetometer(VSM),and the result showed that the particles were ferro-magnetic,which means the magnetic electroplating of the microorganism cells was successfully achieved.The electrochemical reaction mechanism of the magnetic plating process was also analyzed;the result showed that the deposition of NiFe on the microorganism cells was anomalous codeposition,and that Fe2+ ion was preferential deposited when magnetic stirring was applied.
