不同封装形式压接型IGBT器件的电-热应力研究

基于多物理场建模对比分析全压接和银烧结封装压接型IGBT器件的电-热应力。首先根据全压接和银烧结封装压接型IGBT的实际结构和材料属性,建立3.3 kV/50 A压接型IGBT器件的电-热-力多耦合场有限元模型;其次仿真分析额定工况下2种封装IGBT器件的电-热性能,并通过实验平台验证所建模型的合理性;然后研究了3.3 kV/1500 A多芯片压接型IGBT模块的电-热应力,并探究了不同封装压接型IGBT器件电-热应力存在差异的原因;最后比较了2种封装压接型IGBT器件内部的电-热应力随夹具压力和导通电流变化的规律。结果表明银烧结封装降低了压接型IGBT器件的导通压降和结温,提升了器件散热能力;但银烧结封装也增大了IGBT芯片表面的机械应力,应力增大对IGBT器件疲劳失效的影响亟需实验验证。

基于稳态集-射极饱和电压的IGBT功率模块疲劳失效模型的研究

随着绝缘栅双极型晶体管(insulated gate bipolar transistor, IGBT)功率模块在民用和军用领域应用的不断深入,IGBT功率模块在长时间电-热应力下的疲劳老化问题越来越突出。本文基于半导体物理和器件可靠性理论,研究IGBT功率模块封装失效的产生原因,分析焊料层和键丝失效的作用机理和表现特征。在研究IGBT通态电压模型的基础上,提出了一种基于稳态集-射极饱和电压的IGBT功率模块疲劳老化模型,实现对焊料层疲劳和键丝疲劳等封装老化问题的综合表征。搭建IGBT功率模块的电-热老化实验测试平台,进行了功率循环老化实验验证,结果表明本文模型可以较为准确地评估IGBT功率模块封装的疲劳老化程度。

Experimental Evidence of Interface-Trap-Related SILC in Ultrathin (4nm- and 2.5nm-Thick) n-MOSFET and p-MOSFET Under Hot-Carrier Stress

Stress-induced leakage current (SILC) of ultrathin gate oxide is investigated by observing the generation of interface traps for n-MOSFET and p-MOSFET under hot-carrier stress.It is found experimentally that there is linear correlation between the generation of interface traps and SILC for both types of MOSFET with different channel lengths (including 1,0.5,0.275,and 0.135μm) and different gate oxide thickness (4nm and 2.5nm).These experimental evidences show that the SILC has a strong dependence on interface traps.

Effect of working condition on thermal stress of NiFe_2O_4-based cermet inert anode in aluminum electrolysis

Based on the FEA software ANSYS,a model was developed to simulate the thermal stress distribution of inert anode.In order to reduce its thermal stress,the effect of some parameters on thermal stress distribution was investigated,including the temperature of electrolyte,the current,the anode cathode distance,the anode immersion depth,the surrounding temperature and the convection coefficient between anode and circumstance.The results show that there exists a large axial tensile stress near the tangent interface between the anode and bath,which is the major cause of anode breaking.Increasing the temperature of electrolyte or the anode immersion depth will deteriorate the stress distribution of inert anode.When the bath temperature increases from 750 to 970 ℃,the maximal value and absolute minimal value of the 1st principal stress increase by 29.7% and 29.6%,respectively.When the anode immersion depth is changed from 1 to 10 cm,the maximal value and absolute minimal value of the 1st principal stress increase by 52.1% and 65.0%,respectively.The effects of other parameters on stress distribution are not significant.

Efficient synthesis of 1,6-hexamethylene diurethane through coupling transesterification and methoxycarbonylation with methyl phenyl carbonate as intermediate

A reaction coupling system of transesterification and methoxycarbonylation with methyl phenyl carbonate （MPC） as intermediate was established to efficiently prepare 1,6-hexamethylene diurethane （HDU） from 1,6- bexametbylene diamine （HDA）. The feasibility of the system was explored using the thermodynamics analysis, the reaction mechanism and the experiment results. The optimal reaction was carried out to get higher HDU yield. The thermodynamic analysis showed that the metboxycarbonylation of HDA with MPC, the Gibbs free energy of which was negative, was a spontaneous process. Furthermore, the equilibrium constant of the methoxycarbonylation of HDA with MPC was much greater than that of the transesterification of dimethyl carbonate （DMC） with phenol, so the reaction coupling could be realized under mild conditions. The reaction mechanism analysis indicated that phenoxy anion was the key spedes for reaction coupling. Higher MPC concentration was detected when sodium phenoxide was used as transesterification reactant with DMC, since the phenoxy anion of sodium phenoxide could be dissociated more easily. Sodium pbenoxide was more suitable to prepare HHDU through reaction coupling. A yield of HDU as high as 98.3% could be reached under the optimal conditions of mPhONa/mDMC = 0.027 and nDMC/nHDa = 8/1 at 90 ℃ in 2 h.

Design of High-Speed PM Synchronous Motor Thermal and Mechanical Analyzes Study for Aerospace Retraction Wheel Motor Application

A 3-D modeling of FEA （finite element analysis） design provides for high-speed synchronous with PMs （permanent magnets） applied in aerospace application will be examined under design considerations ofn = 12,000 rpm, short-duty operation, and etc. for an ARWM （aerospace retraction wheel motor）. First, lumped-elements will be fine-tuned following numerical method results is reported steady-state and transient solutions. Besides, the equations of thermal modeling such as Re, N,,, G,. and Pr numbers in order to calculate heat-transfer coefficient of convection on the rotor and stator surfaces in the air-gap have calculated. This section illustrates the temperature distribution of each point in a clear view. By CFD （fluid dynamic analysis） analysis, the fluid dynamics were modeled, pressure and velocity streamlines of cooling-flow have analyzed. An optimization algorithm was derived in order to have optimized number of water-channels as well. Second, calculation of nodal and tangential forces which deal with mechanical stresses of the ARWM have represented. The paper discusses an accurate magnetic-field analysis that addresses equivalent stress distribution in the magnetic core through using the transient FEA to estimate motor characteristics. The whole model shear and normal mechanical stresses and total deformation oftbe ARWM has been investigated by transient FEA. The end-winding effects were included by the authors.

Kinetics Study on O2 Adsorption and OHad Desorption at Pt（111）, Its Implication to Oxygen Reduction Reaction Kinetics

Kinetics of dissociative O2 adsorption, OHad desorption, and oxygen reduction reaction （ORR） at Pt（111） electrode in 0.1 mol/L HClO4 has been investigated. Reversible OHad adsorption/desorption occurs at potentials from 0.6 V to 1.0 V （vs. RHE） with the exchange current density of ca. 50 mA/cm^2 at 0.8 V, the fast kinetics of OHad desorption indicates that it should not be the rate determining step for ORR. In the kineticor kinetic-mass transport mix controlled potential region, ORR current at constant potential displays slight decrease with reaction time. ORR current in the positive-going potential scan is slightly larger than that in the subsequent negative-going scan with electrode rotation speed （〉800 r/min） and slow potential scan rate （〈100 mV/s）. The open circuit potential of Pt/0.1 mol/L HClO4 interface increases promptly from 0.9 V to 1.0 V after switch from O2 free- to O2-saturated solution. The increase of open circuit potential as well as ORR current decays under potential control due to the accumulation of OHad from dissociative adsorption of O2. It indicates that at Pt（111） the net rate for O2 decomposition to OHad is slightly faster than that for OHad removal, one cannot simply use the assumption of rate determining step to discuss ORR kinetics. Instead, the ORR kinetics is determined by both the kinetics for O2 decomposition to OHad as well as the thermo-equilibrium of OHad＋H^＋＋e→←H2O.

Research on thermode of operation of wisdom Logistics in large data background

With the rapid development of China＇ s economy and the accelerating pace of economic globalization, the rapid expansion of trade appears in goods, materials; space to move also will expand in breadth and depth, and thus the efficiency of the logistics activities, rapid response capabilities and the level of information logistics put forward higher requirements. Meanwhile, the logistics needs of personalization, diversification and sophistication, require that logistics service companies must constantly improve and optimize enterprise business model, and target to develop new logistics services to adapt to changes in the logistics market, and improve the competitiveness of enterprises.Modem logistics enterprises refer to the concept of modem logistics as a guide, and the use of modem logistics and organization of modem logistics technology, it is to provide customers help and reduce logistics costs and improve the level of integrated logistics services to rationalize logistics enterprises. Modem logistics enterprises are in terms of philosophy, mode of operation, services, information technology degree, logistics technology, enterprise systems and others have higher requirements to react quickly, service serialization, standardization of operations, the target of systematic, modem means are the features of the organization which are different from the traditional network of logistics enterprises.

Cationic-potential tuned biphasic layered cathodes for stable desodiation/sodiation

Sodium layered oxides generally suffer from deep-desodiation instability in P2 structure and sluggish kinetics in O3 structure.It will be great to design P2/O3 biphasic materials that bring the complementary merits of both structures.However,such exploration is hindered by the ambiguous mechanism of material formation.Herein,supported by theoretical simulations and various spectroscopies,we prove that P2/O3 biphasic structures essentially originate from the internal heterogeneity of cationic potential,which can be realized by constraining the temperature-driven ion diffusion during solid-state reactions.Consequently,P2/O3 biphasic Na_(0.7)Ni_(0.2)Cu_(0.1)Fe_(0.2)Mn_(0.5)O_(2)-δ with well-designed quaternary composition is successfully obtained,exhibiting much-improved rate capabilities(62 mAh g^(-1)at 2.4 A g^(-1)) and cycling stabilities(84%capacity retention after 500 cycles)than its single-phase analogues.Furthermore,synchrotron-based diffraction and X-ray absorption spectroscopy are employed to unravel the underlying sodium-storage mechanism of the P2/O3 biphasic structure.This work presents new insights toward the rational design of advanced layered cathodes for sodium-ion batteries.

Electrocaloric Effect of P(VDF-TrFE)/SrTiO_3 Bilayer Thin Films

A phenomenological thermodynamic theory is applied to investigate the effect of misfit strgin and electric field on the electrocaloric effect of P（VDF-TrFN）/SrTiO3 bilayer thin films. Theoretical results indicate that the low electric field results in the decrease of the average polarization with the increase of the relative thickness of SrTi03 layer, and the high electric field has an opposite effect on it. Moreover, the electroealoric effect strongly depends on the electric field. The low electric field and the small field change can lead to a maximum of the electrocaloric effect, meanwhile the high electric field or the large field change results in the opposite trend.

In-situ interaction of nano-PbS with gelatin

Water-soluble gelatin-PbS bionanocomposites （BNCs） were synthesized via a facile one-pot chemical reaction method at pH 7.40. The samples were characterized by transmission electron microscopy （TEM）, X-ray diffraction （XRD）, UV-vis absorption spectra （UV-vis）, Fourier transform infrared spectra （FT-IR） and circular dichroism （CD）. FT-IR data were used to envis- age the binding of PbS particles with oxygen atoms of carbonyl groups of gelatin molecule. The possible integration mechanism between gelatin and PbS was discussed in detail. The effect of Pb2＋ and PbS on the conformations of gelatin has also been analyzed by means of UV-vis, CD and FT-IR spectra, resulting in less c^-helix content and more open structures （[3-sheet, r-turn, or expanded）. A new formula to calculate the association constant was proposed according to the relationship between the absorbance of gelatin-PbS BNCs and the free concentration of PbS, and apparent association constants K （298/303/308 K： 3.11/2.00/1.60 × 10^6 tool/L） at three different temperatures were calculated based on this formula. Thermodynamic parameters such as AG^θ, △Hθ and △S^θ were also determined. The results of the thermodynamic investigations indicated that the reaction was spontaneous （AG^θ 〈 0）, and enthalpy-driven （△H^8 〈 0）.

Stress Analysis of CR Superferric Magnet

Finite Element Method is used in this article to analyze the stress of CR superferric magnet.Magnetic force and the stress caused by this force are calculated.The thermal stress and strain of the coil caused by cooling down is also analyzed.The result will be taken as a check for the design of the coil and coilcase,and also as a reference for the optimization of further design and quench protection.

Experimental and thermal stress investigation on side wall deformation at the pendent convective pass in a utility boiler

An experimental investigation is performed on side wall deformation at the pendant convective pass (PCP) in a 300 MW and a 600 MW utility boiler. The temperature distributions are measured on the side wall areas of the water-cooled wall, the PCP and the horizontal convective pass (HCP) in the two utility boilers. These experiments show that there are great temperature differences in the side wall areas during the startup process in both utility boilers. These temperature differences can reach 80～150 °C with the side wall temperature in the PCP area higher than those in the water-cooled wall and the HCP. The highest temperature in the PCP is close to the flue gas side temperature at the same position in the horizontal flue gas pass. Thermal stress analyses are conducted in the side wall areas in the water-cooled wall, the PCP and the HCP with the software ANSYS. The results show that, at great temperature differences, the PCP side wall undergoes negative thermal stresses that exceed the yield strength causing deformation in the PCP side wall.