Heterojunction has been widely used in vibration-driven piezocatalysis for enhanced charges separation,while the weak interfaces seriously affect the efficiency during mechanical deformations due to prepared by tradit...Heterojunction has been widely used in vibration-driven piezocatalysis for enhanced charges separation,while the weak interfaces seriously affect the efficiency during mechanical deformations due to prepared by traditional step-by-step methods.Herein,the intimate contact interfaces with shared S atoms are ingeniously constructed in SnS_(2)/SnS anchored on porous carbon by effective interface engineering,which is in-situ derived from temperature-dependent self-transformation of SnS_(2).Benefiting from intimate contact interfaces,the piezoelectricity is remarkably improved due to the larger interfacial dipole moment caused by uneven distribution of charges.Importantly,vibration-induced piezoelectric polarization field strengthens the interfacial electric field to further promote the separation and migration of charges.The dynamic charges then transfer in porous carbon with high conductivity and adsorption for significantly improved piezocatalytic activity.The degradation efficiency of bisphenol A(BPA)is 6.3 times higher than SnS_(2) and H2 evolution rate is increased by 3.8 times.Compared with SnS_(2)/SnS prepared by two-step solvothermal method,the degradation efficiency of BPA and H2 evolution activity are increased by 3 and 2 times,respectively.It provides a theoretical guidance for developing various multiphase structural piezocatalyst with strong interface interactions to improve the piezocatalytic efficiency.展开更多
The diversity of interface morphologies is observed for directionally solidified Sn-0.65%Cd alloy under a travelling magnetic field （TMF） in the 4 mm-diameter sample. Under an upward TMF, planar and cellular interfa...The diversity of interface morphologies is observed for directionally solidified Sn-0.65%Cd alloy under a travelling magnetic field （TMF） in the 4 mm-diameter sample. Under an upward TMF, planar and cellular interface morphologies transform alternately with increasing magnetic flux density （B≤10.3 mT）. The interface morphology transforms from shallow cellular to deep cellular morphology under a weak downward TMF （B=3.2 mT）. When the magnetic flux density increases further, both sides of the interface morphology appear to be slightly inconsistent, but they roughly tend to be planar under a strong downward TMF （BS10.3 mT）. The interface instability may be attributed to the flow driven by the TMF. Moreover, the shape of interface appears to be almost flat under an upward TMF, but deflective under a downward TMF.展开更多
文摘Heterojunction has been widely used in vibration-driven piezocatalysis for enhanced charges separation,while the weak interfaces seriously affect the efficiency during mechanical deformations due to prepared by traditional step-by-step methods.Herein,the intimate contact interfaces with shared S atoms are ingeniously constructed in SnS_(2)/SnS anchored on porous carbon by effective interface engineering,which is in-situ derived from temperature-dependent self-transformation of SnS_(2).Benefiting from intimate contact interfaces,the piezoelectricity is remarkably improved due to the larger interfacial dipole moment caused by uneven distribution of charges.Importantly,vibration-induced piezoelectric polarization field strengthens the interfacial electric field to further promote the separation and migration of charges.The dynamic charges then transfer in porous carbon with high conductivity and adsorption for significantly improved piezocatalytic activity.The degradation efficiency of bisphenol A(BPA)is 6.3 times higher than SnS_(2) and H2 evolution rate is increased by 3.8 times.Compared with SnS_(2)/SnS prepared by two-step solvothermal method,the degradation efficiency of BPA and H2 evolution activity are increased by 3 and 2 times,respectively.It provides a theoretical guidance for developing various multiphase structural piezocatalyst with strong interface interactions to improve the piezocatalytic efficiency.
基金Project(50774061) supported by the National Natural Science Foundation of ChinaProject(28-TP-2009) supported by the Research Fund of State Key Laboratory of Solidification Processing(NWPU),China
文摘The diversity of interface morphologies is observed for directionally solidified Sn-0.65%Cd alloy under a travelling magnetic field （TMF） in the 4 mm-diameter sample. Under an upward TMF, planar and cellular interface morphologies transform alternately with increasing magnetic flux density （B≤10.3 mT）. The interface morphology transforms from shallow cellular to deep cellular morphology under a weak downward TMF （B=3.2 mT）. When the magnetic flux density increases further, both sides of the interface morphology appear to be slightly inconsistent, but they roughly tend to be planar under a strong downward TMF （BS10.3 mT）. The interface instability may be attributed to the flow driven by the TMF. Moreover, the shape of interface appears to be almost flat under an upward TMF, but deflective under a downward TMF.
