SH波绕界面孔的散射

用波函数展开方法研究了ＳＨ波绕界面孔的散射问题．由入射、反射和透射波组成的自由波场与孔的散射场叠加成总波场．按照一定方式将两个半平面散射波场延拓于全平面，通过Ｈａｎｋｅｌ－Ｆｏｕｒｉｅｒ展开方法求得了任意形状孔散射场的级数解．以椭圆形孔为例计算了孔边缘的动应力集中系数．

SH波在界面孔上散射的远场解

采用Green函数和复变函数方法研究了界面上任意形柱状孔洞对SH波散射的远场解。取含有任意形凹陷的弹性半空间,在其水平表面上任意一点承受时间谐和的反平面线源荷载作用时的位移解作为Green函数,按"契合"的方式构造出两种不同介质交界面上任意形孔洞对SH波的散射模型,利用Green函数建立求解问题的第一类Fredholm积分方程组,求解散射波的远场位移模式和散射截面。通过算例,分析了不同材料组合情况下界面椭圆孔和方孔对SH波散射的远场特性。

用波函数展开法求解界面圆孔的SH波散射问题

研究了ＳＨ波绕界面圆孔散射的波函数展开理论。由入射，反射和透射波组成的自由波场与孔 的散射场叠加成总波场．将定义于两个半平面的散射场按一定方式延拓到全平面，通过 Ｈａｎｋｅｌ—Ｆｏｕｒｉｅｒ型积分来满足界面与孔缘处的边界条件，得到了确定待定系数的封闭代数方程组．给 出了具体算例，计算了在孔缘处的动应力集中系数分布．

SH波作用下界面任意形状孔洞附近的动应力集中

采用Green函数和复变函数法求解了平面SH波在界面任意形状孔洞上的散射问题.首先,取含有任意形状凹陷的弹性半空间,在其水平表面上任意一点承受时间谐和的反平面线源荷载作用时的位移场作为Green函数.然后,按契合方式构造出界面任意形状孔洞对SH波的散射模型,利用所得Green函数按界面位移连续条件建立求解问题的定解积分方程组,求解界面孔附近的动应力集中系数.最后,给出了界面上椭圆孔和方孔边缘动应力集中系数的数值结果,并讨论了不同介质参数和孔洞形状对孔附近动应力集中系数的影响.

深海沉积物–结构界面仪试验装置研发及其验证试验

深海沉积物–结构界面特性是海洋平台结构设计与计算的关键之一;然而,目前针对深海沉积物–结构界面特性的试验装置与测试方法尚比较缺乏。基于大连理工大学"土工静-动力液压三轴剪切仪",改造三轴压力室,研制一套深海沉积物–结构界面仪;首先系统介绍了试验装置的研发思路、技术优势以及使用方法,通过开展静/动载作用下不排水深海沉积物–结构界面特性试验,验证所研制界面仪的可靠性和准确性;续而初步探讨粗糙度、动载ICSR等因素对界面的力学性能和孔压发展的影响规律。研究结果表明:静载作用下界面应力曲线随着粗糙度的增加由折线型转变为双曲线型,剪切过程中近界面土体经历了先剪缩后剪胀的发展趋势,界面破坏形式随粗糙度增大呈现由深海沉积物–结构表面向土体内的迁移现象;动力循环荷载作用下粗糙度Ⅱ结构物随循环周次增加呈上拔滑移状,伴随着动孔压的累积界面呈现刚度弱化现象,界面累积塑性应变在循环周次为300时趋于稳定,最终归一化界面动孔压u/σ_(3)为0.22;该界面仪为深海沉积物–结构界面特性和机理研究、以及界面本构模型的建立提供有利支撑。

In-situ building of multiscale porous NiFeZn/NiZn-Ni heterojunction for superior overall water splitting

The development of efficient nonprecious bifunctional electrocatalysts for water electrolysis is crucial to enhance the sluggish kinetics of the oxygen evolution reaction(OER)and hydrogen evolution reaction(HER).A self-supporting,multiscale porous NiFeZn/NiZn-Ni catalyst with a triple interface heterojunction on nickel foam(NF)(NiFeZn/NiZn-Ni/NF)was in-situ fabricated using an electroplating-annealing-etching strategy.The unique multiinterface engineering and three-dimensional porous scaffold significantly modify the mass transport and electron interaction,resulting in superior bifunctional electrocatalytic performance for water splitting.The NiFeZn/NiZn-Ni/NF catalyst demonstrates low overpotentials of 187 m V for HER and 320 mV for OER at a current density of 600 mA/cm^(2),along with high durability over 150 h in alkaline solution.Furthermore,an electrolytic cell assembled with NiFeZn/NiZn-Ni/NF as both the cathode and anode achieves the current densities of 600 and 1000 m A/cm^(2) at cell voltages of 1.796 and 1.901 V,respectively,maintaining the high stability at 50 mA/cm^(2) for over 100 h.These findings highlight the potential of NiFeZn/NiZn-Ni/NF as a cost-effective and highly efficient bifunctional electrocatalyst for overall water splitting.

碳酸钙粒子对聚偏氟乙烯膜结构与性能的影响

采用Loeb-Sourirajan相转化法成膜技术制备了碳酸钙(CaCO3/)聚偏氟乙烯(PVDF)复合膜,讨论了加入Ca-CO3对PVDF膜的结构与性能的影响,并应用卵清蛋白截留实验、扫描电子显微镜、动态粘弹谱仪分别对膜分离性能、微观结构及动态力学性能进行了测试.结果表明,加入CaCO3引入了界面孔,增加了非界面孔的连通性,提高了复合膜的孔隙率,在保持甚至提高复合膜的截留率的基础上,增大了膜的水通量,与此同时,增加了复合膜的模量.另外,与微米级粒径的CaCO3相比,纳米级粒径的CaCO3的加入更能有效提高膜的水通量和截留率.

Interfacial-interaction-induced fabrication of biomass-derived porous carbon with enhanced intrinsic active sites

Carbon catalysis is an attractive metal-free catalytic transformation,and its performance is significantly dependent on the number of accessible active sites.However,owing to the inherent stability of the C-C linkage,only limited active sites at the edge defects of the basal plane can be obtained even after a harsh oxidation treatment.In this study,the concept of interfacial interactions was adopted to propose an efficient strategy to develop highly active carbon catalysts.The alumina/carbon interface formed in situ acted as a cradle for the generation of oxygen-containing functional groups.In the absence of oxidation treatment,the concentration of oxygen-containing functional groups and the specific surface area can reach 1.27 mmol·g^(-1) and 2340 m^(2)·g^(-1),respectively,which are significantly higher than those of carbon prepared by traditional hard template methods.This active carbon shows a significant enhancement in catalytic performance in the oxidative coupling of amine to imine,about 22-fold higher than that of a well-known graphite oxide catalyst.Such interfacial interaction strategies are based on sustainable carbon sources and can effectively tune the porous structure of carbon in the micro-and meso-ranges.This conceptual finding offers new opportunities for the development of high-performance carbon-based metal-free catalysts.

Methods for Reducing Interface Aperture Inconsistency During NC Orbital Milling of Aircraft Laminates with Coarse Pitch

The methods for reducing interface aperture inconsistency are studied in NC orbital milling(NCOM)of CFRP/Ti6Al4V laminates with coarse pitch.Comparative experiments show burr,aperture inconsistency and error are typical interface defects.Meanwhile,aperture inconsistency and error are more serious than burr in NCOM with coarse pitch.As one of the major causes of interface defects,axial force and radial force are intensively studied.Based upon the machining principle of orbital milling(OM)and the actual hole-making condition in laminated structures,NCOM experiments with coarse pitch are conducted on CFRP/Ti6Al4V laminates under different cutting conditions.Then,the effects of interlayer clamping,minimal quantity lubrication(MQL),twice milling instead of reaming,and interlayer speed change on interface aperture are analyzed.Research shows that interlayer clamping,interlayer speed change and MQL can effectively reduce out-of-tolerance of interface aperture.When making holes of different diameters with one cutter,axial feed has a greater effect on interface aperture precision than tangential feed.When making holes of the same diameter with different cutters,small diameter cutter will reduce interface aperture precision in a single processing.But the method of“twice milling instead of reaming”can improve the aperture precision effectively.

Parametric study on the axial performance of a fully grouted cable bolt with a new pull-out test

Modified cable bolts are commonly used in underground mines due to their superior performance in preventing bed separation when compared with plain strands. To better test the axial performance of a wide range of cable bolts,a new laboratory short encapsulation pull test(LSEPT) facility was developed. The facility simulates the interaction between cable bolts and surrounding rock mass,using artificial rock cylinders with a diameter of 300 mm in which the cable bolt is grouted. Furthermore,the joint where the load is applied is left unconstrained to allow shear slippage at the cable/grout or grout/rock interface.Based on this apparatus,a series of pull tests were undertaken using the MW9 modified bulb cable bolt.Various parameters including embedment length,test material strength and borehole size were evaluated. It was found that within a limited range of 360 mm,there is a linear relationship between the maximum bearing capacity of the cable bolt and embedment length. Beyond 360 mm,the peak capacity continues to rise but with a much lower slope. When the MW9 cable bolt was grouted in a weak test material,failure always took place along the grout/rock interface. Interestingly,increasing the borehole diameter from 42 to 52 m in weak test material altered the failure mode from grout/rock interface to cable/grout interface and improved the performance in terms of both peak and residual capacity.

Relationship between interfacial structure and property of steel-mushy Al-28Pb bonding pate

The interfacial properties of steel-mushy Al-28Pb bonding plate with different interfacial structures, and the influence of ratio of Fe-Al compound at the interface on interfacial shear strength were investigated. The results show that there is a nonlinear relationship between the ratio of Fe-Al compound at the interface and the interfacial shear strength. When the ratio of Fe-Al compound at the interface is smaller than 71.4%, with the increase of the ratio of Fe-Al compound at the interface, the interfacial shear strength increases gradually; when the ratio of Fe-Al compound at the interface is larger than 71.4%, with the increase of the ratio of Fe-Al compound at the interface, the interfacial shear strength decreases continuously; when the ratio of Fe-Al compound at the interface is 71.4%, the largest interfacial shear strength 70.2MPa is obtained.

Development of experimental study on coupled heat and moisture transfer in porous building envelope

A new facility was presented which can expediently and cheaply measure the transient moisture content profile in multi-layer porous building envelope.Then,a common multi-layer porous building envelope was provided,which was constructed by cement mortar-red brick-cement plaster.With this kind of building envelope installed in the south wall,a well-controlled air-conditioning room was set up in Changsha,which is one of typical zones of hot and humid climate in China.And experiments were carried out to investigate the temperature and moisture distribution in multi-layer building envelope in summer,both in sunny day and rainy day.The results show that,the temperature and humidity at the interface between the brick and cement mortar are seriously affected by the changes of outdoor temperature and humidity,and the relative humidity at this interface keeps more than 80% for a long-term,which can easily trigger the growth of mould.The temperature and humidity at the interface between the brick and cement plaster change a little,and they are affected by the changes of indoor temperature and humidity.The temperature and humidity at the interface of the wall whose interior surface is affixed with a foam plastic wallpaper are generally higher than those of the wall without wallpaper.The heat transfer and moisture transfer in the envelope are coupled strongly.

Dual-network hydrogel based on ionic nano-reservoir for gastric perforation sealing

In recent years,remarkable progress has been made in the research of injectable hydrogel for internal tissue healing.However,the therapeutic outcome is usually limited when the hydrogel is used for the treatment of gastric perforation due to the high acidic gastric juice and violent deformation of the gastric wall.Regarding these challenges,we proposed an ionic nano-reservoir(INR)-based dual-network hydrogel,which has excellent adhesion and mechanical properties,and can be easily applied to the perforation site to block the perforation while promoting tissue repairing.The results showed that the first network made of polyacrylamide had cross-linked on the stomach tissue within 5 s under blue light,and enhanced the adhesion performance through mechanical interlock.The nano-hydroxyapatite acted as ionic INR,which can gradually release Ca^(2+) under acid environments to form the second network with sodium alginate and inhibit the swelling of hydrogel in gastric juice.Meanwhile,the adhesion was further enhanced through amide covalent bonds at the hydrogel-tissue interface with the presence of 1-ethyl-3-(3-dimethylaminopropyl)carbodiimide/N-hydroxysuccinimide(EDC/NHS).The dual network hydrogels obtained by the INR strategy could be employed as a potential therapeutic option for gastric perforation and other similar biomedical prolems.

Energy flux characteristics of seismic waves at the interface between soil layers with different saturations

Based on the multiphase poroelasticity theory describing the propagation of waves in the unsaturated fluid-saturated porous medium,the reflection and transmission coefficients of the seismic waves at the interface between soil layers with different saturations are obtained.Our unsaturated model consists of a deformable skeleton in which two compressible and viscous fluids(i.e.,water and gas)flow in the interstices.Three compressional waves(i.e.,P1,P2,and P3 waves)and one shear(i.e.,S wave)wave exist in the unsaturated soils.The expressions for the energy ratios of the various reflected and transmitted waves at the interface during the transmission and reflection processes are presented in explicit forms accordingly.At last,numerical computations are performed and the results obtained are respectively depicted graphically.The variation of the energy ratios with the incident angle,wave frequency and saturation degrees of the upper and lower soil layers is illustrated in detail.The calculation results show that the allocation of incident seismic waves at the interface is influenced not only by the angle and frequency of the incident seismic waves,but also by the saturations of the upper and lower soil layers.It is also verified that,at the interface,the sum of energy ratios of the reflected and transmitted waves is approximately equal to unity as was expected.This study is of importance to several fields such as geotechnical engineering,seismology,and geophysics.

Formation of efficient dye-sensitized solar cells by introducing an interfacial layer of hierarchically ordered macro-mesoporous TiO_2 film

Hierarchically ordered macro-mesoporous TiO2 films (Ti-Ma-Me) were fabricated on fluorine-doped tin oxide (FTO) substrates through the confinement self-assembly method. The prepared Ti-Ma-Me possesses periodically ordered structure and a large specific surface area, which was applied as an interfacial layer between the nanocrystalline TiO2 film (P25-TiO2) and FTO electrode in the dye-sensitized solar cell (DSSC). The introduction of a Ti-Ma-Me interfacial layer increased the shortcircuit current density (Jsc) from 7.49 to 10.65 mA/cm2 and the open-circuit voltage (Voc) from 0.65 to 0.70 V as the result of its improved light harvesting efficiency by allowing for the high roughness factor and enhanced multiple internal reflection or scattering as well as reducing the back-transport reaction by blocking direct contact between the electrolyte and FTO electrode. Therefore, the photovoltaic conversion efficiency (η) was improved by 83% from 3.04% to 5.55%, as compared to a device using a bare P25 TiO2 photoanode.

Carbon-CeO interface confinement enhances the chemical stability of Pt nanocatalyst for catalytic oxidation reactions

Noble metals are downsized to nano-/subnanoscale to improve their catalytic activity and atom-economy.However,the stabilities in chemical state and catalytic performance of these nanocatalysts often suffer during harsh conditions.For Pt nanoparticles(NPs)supported on CeO2,activated oxygen diffused from the support over-stabilizes the active sites of Pt,degrading its performance at mild temperature.In this work,Pt nanocatalysts with unique structure of triple-junction are synthesized by selectively growing Pt NPs on the carbon-CeO2 interface.Impressively,the Pt NPs exhibit much enhanced catalytic stability and high activity for CO oxidation at mild temperature.The enhancement is attributed to electron donation from graphitized carbon and the confinement effect from the high-density nanopores of the CeO2 support.The triple-junction of Pt-C-CeO2,combining the merits of CeO2 for activating O2 and electron donating capability of carbon,provides new inspiration to the fabrication of high-performance nanocatalysts.