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第一类鱼抗冻蛋白对冰晶生长界面层结构的影响 被引量:2
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作者 谢文静 刘俊杰 李前忠 《生物物理学报》 CAS CSCD 北大核心 2011年第1期66-76,共11页
根据冰晶在水溶液中生长的基本热力学性质,应用多层界面模型,分别得到了冰晶在纯水及抗冻蛋白溶液中生长界面层的吉布斯自由能。由冰晶生长界面层的吉布斯自由能,分析了冰晶在三种不同第一类鱼抗冻蛋白分子溶液中,热平衡状态下生长界面... 根据冰晶在水溶液中生长的基本热力学性质,应用多层界面模型,分别得到了冰晶在纯水及抗冻蛋白溶液中生长界面层的吉布斯自由能。由冰晶生长界面层的吉布斯自由能,分析了冰晶在三种不同第一类鱼抗冻蛋白分子溶液中,热平衡状态下生长界面层的微观平衡结构,发现冰晶在抗冻蛋白溶液中生长与其在纯水中生长相比,界面层结构有明显变化,结合抗冻蛋白后,冰晶的生长界面由粗糙界面向光滑界面转变;并讨论了结合抗冻蛋白后,冰晶生长界面层微观平衡结构的变化对冰晶生长形态的影响。为理解冰晶在抗冻蛋白溶液及纯水中有不同的生长习性和生长形态这一实验事实,提供了理论依据。 展开更多
关键词 冰晶 抗冻蛋白 界面层结构
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新型热镀锌双相钢的合金成分对界面层和镀层结构的影响
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作者 李沅沅 梁健 +4 位作者 熊自柳 苗斌 田秀刚 齐建军 郑士建 《材料研究学报》 EI CAS CSCD 北大核心 2024年第6期446-452,共7页
用对粘方式制备热镀锌双相钢DP980样品,用TEM表征其截面,用TEM结合电子衍射和EDS表征其界面层结构和镀锌层结构并构建其空间关系。结果表明,与DP780在退火阶段合金元素Mn的外氧化不同,DP980主要发生内氧化和Cr元素与Mn元素的竞争性氧化... 用对粘方式制备热镀锌双相钢DP980样品,用TEM表征其截面,用TEM结合电子衍射和EDS表征其界面层结构和镀锌层结构并构建其空间关系。结果表明,与DP780在退火阶段合金元素Mn的外氧化不同,DP980主要发生内氧化和Cr元素与Mn元素的竞争性氧化,界面层中较少的MnO促进热镀锌过程中的Fe-Al反应而生成了连续致密的Fe_(2)Al_(5)抑制层,抑制了镀锌阶段的Fe-Zn反应而使DP980具有较好的热镀锌性能。同时,这种结构使弥散分布在镀锌层中的η-Zn基体生成Fe3Zn10纳米晶而避免生成有较大脆性Fe-Zn相的镀层结构,使DP980保持较好的力学性能。 展开更多
关键词 材料表面与界面 镀锌双相钢 微观结构表征 选择性氧化 界面层结构 镀锌结构
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三层LDPE/MgO纳米复合材料界面空间电荷特性 被引量:1
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作者 何丽娟 马玥 +2 位作者 杨雄 曾均吉 陈春天 《电机与控制学报》 EI CSCD 北大核心 2020年第8期109-114,130,共7页
为了研究LDPE/Mg O纳米复合材料界面对不同三层结构空间电荷特性的影响,制备了纯LDPE薄膜以及4种不同界面的三层LDPE/MgO纳米复合薄膜。分别用电声脉冲法和光刺激放电法测试了这些薄膜的空间电荷特性和陷阱能级分布。实验结果表明,纳米M... 为了研究LDPE/Mg O纳米复合材料界面对不同三层结构空间电荷特性的影响,制备了纯LDPE薄膜以及4种不同界面的三层LDPE/MgO纳米复合薄膜。分别用电声脉冲法和光刺激放电法测试了这些薄膜的空间电荷特性和陷阱能级分布。实验结果表明,纳米Mg O颗粒的掺杂能够有效限制载流子在电介质内部的迁移,抑制空间电荷效果明显;在三明治结构复合材料的界面处存在大量的陷阱分布,这些陷阱可以捕获介质中的自由电荷,形成界面电荷层,电荷积累会削弱界面处的电场,并在界面处形成势垒,界面势垒也会抑制空间电荷的注入和迁移,降低消散速率。而且,界面相互作用对空间电荷特性的影响大于纳米颗粒掺杂。此外,界面结构的引入使薄膜中浅陷阱数量增多,深度为3. 55~5. 13 eV,空间电荷注入和消散速率降低,并且抑制了电荷的进一步注入和消散。 展开更多
关键词 空间电荷特性 陷阱能级 低密度聚乙烯 纳米掺杂 复合薄膜 界面结构
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Microstructures,mechanical and oxidation behaviors of C/C composites modified by NiAl alloy 被引量:6
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作者 方华婵 肖鹏 +1 位作者 熊翔 於广军 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第1期196-202,共7页
Carbon/carbon composites modified by NiAl alloy were prepared using vacuum reactive melt infiltration methods with NiAl and titanium mixed powders as raw materials. The microstructures were investigated by scanning el... Carbon/carbon composites modified by NiAl alloy were prepared using vacuum reactive melt infiltration methods with NiAl and titanium mixed powders as raw materials. The microstructures were investigated by scanning electron microscopy. The fracture behavior, infiltration and oxidation mechanism were further discussed. The results indicated that NiAl alloy exhibited good wettability on the C/C preform because a TiC reaction layer formed at the interface. Multi-layer(PyC/TiC/NiAl+TiC) coating evenly and compactly distributed on the surface of the carbon fiber in tubular form. The penetration depth of molten NiAl alloys depended on the reaction between the PyC and titanium. The impact fracture was inclined to along the interface between the NiAl permeability layer and C/C matrix. Al_2TiO_5 and TiO_2 formed on the surface, while the interior multi-layer tubular structure partially remained after oxidation at 1773 K for 30 min. 展开更多
关键词 carbon/carbon composites INTERFACE Ni Al multilayer structure OXIDATION
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激光功率对铝/黄铜熔钎焊接头组织和性能的影响 被引量:4
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作者 李志勇 周利 +3 位作者 何至正 宋晓国 张欣盟 冯吉才 《中国有色金属学报》 EI CAS CSCD 北大核心 2021年第3期669-681,共13页
采用激光填丝熔钎焊方法对5052铝合金和H62黄铜异种金属进行对接试验,填充材料为Zn-15%Al(质量分数)药芯焊丝,研究激光功率对接头微观组织、界面层结构和力学性能的影响。结果表明:当激光功率2100 W时,接头因热输入过低而发生断裂,激光... 采用激光填丝熔钎焊方法对5052铝合金和H62黄铜异种金属进行对接试验,填充材料为Zn-15%Al(质量分数)药芯焊丝,研究激光功率对接头微观组织、界面层结构和力学性能的影响。结果表明:当激光功率2100 W时,接头因热输入过低而发生断裂,激光功率在2400~3300 W范围时,获得了性能良好的接头。黄铜侧界面附近的过渡区有Al_(4.2)Cu_(3.2)Zn_(0.7)(T'相)和CuZn_(5)化合物生成,界面层结构可分为连续的CuZn相层和锯齿状的T'相层,且随着激光功率增大,CuZn界面层的厚度随之增大。界面层附近出现显微硬度最大值,焊缝区显微硬度大于母材。随着激光功率的增加,接头的拉伸强度先增大后减小,当激光功率为2700 W时,原始接头和磨平余高后接头的拉伸强度最大,分别为128 MPa和104 MPa。焊缝位置断口为准解理断裂,界面层位置断口为解理断裂。 展开更多
关键词 激光熔钎焊 铝/黄铜异种金属 微观组织 界面层结构 力学性能
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XPS AND UPS STUDIES OF THE INTERFACIAL INTERACTION IN Ni ZrO 2 COMPOSITE PLATING
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作者 王为 项民 +2 位作者 郭鹤桐 覃奇贤 任殿胜 《Transactions of Tianjin University》 EI CAS 1998年第1期98-101,共4页
The interfacial interaction existing in the Ni ZrO 2 composite plating has been investigated. The experimental results show that no new phases were formed in the interfacial regions between matrix Ni and ZrO 2 part... The interfacial interaction existing in the Ni ZrO 2 composite plating has been investigated. The experimental results show that no new phases were formed in the interfacial regions between matrix Ni and ZrO 2 particles, but an orbital interaction through the mutual overlap of the d orbits does exist in the interfacial regions between Ni atoms and Zr 3+ ions. 展开更多
关键词 Ni ZrO 2 composite plating interfacial structure INTERACTION
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NONLINEAR EFFECT OF LOCAL ROUGH WALL ON LARGE EDDY STRUCTURE IN BOUNDARY LAYER
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作者 陆昌根 曹卫东 张艳梅 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI 2008年第3期194-200,共7页
Based on the building of a theoretical model for the large eddy structure, the nonlinear effect of the local rough wall on the large eddy structure in the boundary layer is studied by direct numerical simulation. Nume... Based on the building of a theoretical model for the large eddy structure, the nonlinear effect of the local rough wall on the large eddy structure in the boundary layer is studied by direct numerical simulation. Numerical results show that factors of the local rough feature, the distributing structure and the intensity, etc. play an important role in the evolution of the large eddy structure in the boundary layer. 展开更多
关键词 surface roughness boundary layers large eddy structure
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Film Thickness and Surface Plasmon Tune the Contribution of SFG Signals from Buried Interface and Air Surface
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作者 Liang Zhang Junjun Tan +1 位作者 Quanbing Pei Shuji Ye 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2020年第5期532-539,I0078,共9页
Sum frequency generation vibrational spectroscopy(SFG-VS)is a powerful technique for determining molecular structures at both buried interface and air surface.Distinguishing the contribution of SFG signals from buried... Sum frequency generation vibrational spectroscopy(SFG-VS)is a powerful technique for determining molecular structures at both buried interface and air surface.Distinguishing the contribution of SFG signals from buried interface and air surface is crucial to the applications in devices such as microelectronics and bio-tips.Here we demonstrate that the SFG spectra from buried interface and air surface can be differentiated by controlling the film thickness and employment of surface-plasmon enhancement.Using substrate-supported PMMA(poly(methyl methacrylate))films as a model,we have visualized the variations in the contribution of SFG signals from buried interface and air surface.By monitoring carbonyl and C-H stretching groups,we found that SFG signals are dominated by the moieties(-CH2,-CH3,-OCH3 and C=O)segregated at the PMMA/air surface for the thin films while they are mainly contributed by the groups(-OCH3 and C=O)at the substrate/PMMA buried interface for the thick films.At the buried interface,the tilt angle of C=O decreases from65°to 43°as the film preparation concentration increases;in contrast,the angles at the air surface fall in the range from 38°to 21°.Surface plasmon generated by gold nanorods can largely enhance SFG signals,particularly the signals from the buried interface. 展开更多
关键词 Sum frequency generation Surface structure Buried interface Poly(methyl methacrylate) Surface plasmon
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Open Architecture of Single-processor Real-time Robot Control System Based on Windows NT
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作者 张广立 付莹 杨汝清 《Journal of Donghua University(English Edition)》 EI CAS 2003年第4期123-127,共5页
This paper introduces the architecture and implementation of an industrial robot control system based on Windows NT. This robot control system, which is based on a single-processor structure, can run on general indust... This paper introduces the architecture and implementation of an industrial robot control system based on Windows NT. This robot control system, which is based on a single-processor structure, can run on general industrial computers. Owing to using Windows NT's real-time extension RTX, the control system can achieve good realtime performance and friendly user interface in one general-purpose operating system. A three layer hierarchical architecture of control software is proposed to make the system more scalable and flexible. Furthermore a communication and configuration system is implemented to enable modules to communicate with each other, which make the control system scalable and flexible. 展开更多
关键词 robot controller open architecture controller real-time control
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