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液/液界面生长法制备一维纳米硒 被引量:4
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作者 宋吉明 张胜义 +2 位作者 史洪伟 金葆康 沈玉华 《化学通报》 CAS CSCD 北大核心 2006年第6期434-437,共4页
采用均相反应界面生长法制备了一维结构的纳米硒。在制备过程中,初始硒纳米粒子首先在均相反应液中生成,然后加入与该反应液不互溶的溶剂,使其形成液液界面,硒纳米粒子聚集在界面上生长为一维结构。用扫描电镜、透射电镜、X射线粉末衍... 采用均相反应界面生长法制备了一维结构的纳米硒。在制备过程中,初始硒纳米粒子首先在均相反应液中生成,然后加入与该反应液不互溶的溶剂,使其形成液液界面,硒纳米粒子聚集在界面上生长为一维结构。用扫描电镜、透射电镜、X射线粉末衍射等测试技术对样品进行了表征,并讨论了界面生长的机理及其影响因素。 展开更多
关键词 界面生长法 一维结构 纳米硒
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油溶性纳米铜的制备、表征及其对SF15W/40汽油机油摩擦性能的影响 被引量:7
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作者 严冲 张锡凤 +2 位作者 程晓农 袁剑 曹志娟 《润滑与密封》 CAS CSCD 北大核心 2009年第11期27-30,共4页
采用界面生长法,以醋酸铜为母体,抗坏血酸(Vc)为还原剂,吐温-85为修饰剂,正丁醇为生长剂,合成了粒径约15.5nm的油溶性球形纳米铜粉;通过X-射线衍射(XRD)和透射电子显微镜(TEM)对纳米铜粉进行了表征;将其作为润滑油添加剂分散于SF15W/40... 采用界面生长法,以醋酸铜为母体,抗坏血酸(Vc)为还原剂,吐温-85为修饰剂,正丁醇为生长剂,合成了粒径约15.5nm的油溶性球形纳米铜粉;通过X-射线衍射(XRD)和透射电子显微镜(TEM)对纳米铜粉进行了表征;将其作为润滑油添加剂分散于SF15W/40汽油机油中制得纳米润滑油;通过高浓度激光粒度仪考察了纳米润滑油的分散稳定性;通过UMT-Ⅱ摩擦磨损实验机考察了纳米润滑油的摩擦学性能;采用扫描电子显微镜(SEM)分析了磨损表面形貌。结果表明:纳米铜粉在润滑油中具有优异的分散稳定性;纳米铜粉显著改善了SF15W/40汽油机油的润滑性能,其最佳添加量为0.8%。分析认为纳米铜在摩擦表面的划痕和犁沟处沉积并铺展成膜,从而改善了摩擦磨损性能。 展开更多
关键词 油溶性 纳米铜 界面生长法 润滑油添加剂 摩擦学性能
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镍纳米片的制备、表征及摩擦学应用 被引量:2
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作者 张锡凤 程晓农 +3 位作者 严冲 曹智娟 郝伟 刘晓光 《江苏大学学报(自然科学版)》 EI CAS 北大核心 2010年第4期417-421,共5页
采用液相化学还原结合界面生长法,以醋酸镍为母体,水合肼为还原剂,吐温-40为修饰剂,NaOH为pH调节剂,正丁醇为生长剂,制备了厚度15~27 nm、片长380~500 nm的镍纳米片.通过X射线衍射、扫描电子显微镜和激光粒度仪对镍纳米片进行了表征.将... 采用液相化学还原结合界面生长法,以醋酸镍为母体,水合肼为还原剂,吐温-40为修饰剂,NaOH为pH调节剂,正丁醇为生长剂,制备了厚度15~27 nm、片长380~500 nm的镍纳米片.通过X射线衍射、扫描电子显微镜和激光粒度仪对镍纳米片进行了表征.将镍纳米片、球形镍纳米颗粒作为基础油液体石蜡(LP)的添加剂,在UMT-Ⅱ摩擦磨损实验机上分别考察添加前、添加后LP的摩擦磨损性能.结果表明,镍纳米片的晶格参数膨胀率为0.971%,各晶面2θ相应增加;与基础油LP相比,添加纳米镍后,较大程度降低了摩擦副的摩擦因数,显著改善了LP的摩擦性能;就改善效果而言,镍纳米片优于球形镍纳米颗粒. 展开更多
关键词 镍纳米片 化学还原 界面生长法 晶格参数 摩擦学性能
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Growth interface of CdMnTe crystal by traveling heater method 被引量:1
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作者 吴文其 张继军 +5 位作者 王林军 闵嘉华 温旭亮 梁小燕 黄建 唐可 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2016年第5期1433-1438,共6页
The growth interfaces of CdMnTe(CMT) crystals grown by traveling heater method(THM) were studied. Two types of polycrystalline CMT feed ingots synthesized in a traditional rocking furnace and vertical Bridgman(VB... The growth interfaces of CdMnTe(CMT) crystals grown by traveling heater method(THM) were studied. Two types of polycrystalline CMT feed ingots synthesized in a traditional rocking furnace and vertical Bridgman(VB) furnace were adopted in THM growth, and the effects of the polycrystalline feed on the growth interface were revealed. The morphology of the growth interface of CMT crystal(CMT2) grown from the feed by vertical Bridgman was smoother with lower curvature compared with that of CMT crystal(CMT1) from the feed by rocking furnace. The radial Mn composition and Te inclusion distribution of the CMT wafers were analyzed and correlated to the growth interface. The Mn segregation along the radial direction and Te inclusion density of CMT2 were lower than those of CMT1. The VB method synthesized polycrystalline feed could improve the growth interface morphology, which is beneficial for decreasing the Te inclusions and Mn segregation in CMT wafers. 展开更多
关键词 CDMNTE traveling heater method growth interface polycrystalline feed material
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Simulation of facet dendrite growth with strong interfacial energy anisotropy by phase field method 被引量:3
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作者 袁训锋 刘宝盈 +2 位作者 李春 周春生 丁雨田 《Journal of Central South University》 SCIE EI CAS CSCD 2015年第3期855-861,共7页
Numerical simulations based on a new regularized phase-field model were presented, to simulate the solidification of hexagonal close-packed materials with strong interfacial energy anisotropies. Results show that the ... Numerical simulations based on a new regularized phase-field model were presented, to simulate the solidification of hexagonal close-packed materials with strong interfacial energy anisotropies. Results show that the crystal grows into facet dendrites,displaying six-fold symmetry. The size of initial crystals has an effect on the branching-off of the principal branch tip along the<100> direction, which is eliminated by setting the b/a(a and b are the semi-major and semi-minor sizes in the initial elliptical crystals, respectively) value to be less than or equal to 1. With an increase in the undercooling value, the equilibrium morphology of the crystal changes from a star-like shape to facet dendrites without side branches. The steady-state tip velocity increases exponentially when the dimensionless undercooling is below the critical value. With a further increase in the undercooling value, the equilibrium morphology of the crystal grows into a developed side-branch structure, and the steady-state tip velocity of the facet dendrites increases linearly. The facet dendrite growth has controlled diffusion and kinetics. 展开更多
关键词 phase field facet dendrite hcp materials interfacial energy anisotropy dimensionless undercooling
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