The presence of salt has a profound effect on the size,shape and structure of sodium dodecyl sulfate(SDS)micelles.There have been a great number of experiments on SDS micelles in the presence and absence of salt to st...The presence of salt has a profound effect on the size,shape and structure of sodium dodecyl sulfate(SDS)micelles.There have been a great number of experiments on SDS micelles in the presence and absence of salt to study this complex problem.Unfortunately,it is not clear yet how electrolyte ions influence the structure of micelles.By describing the compromise between dominant mechanisms,a simplified atomic model of SDS in presence of salt has been developed and the molecular dynamics(MD)simulations of two series of systems with different concentrations of salt and charges of ion have been performed.Polydispersity of micelle size is founded at relatively high concentration of SDS and low charge of cation.Although the counter-ion pairs with head groups are formed,the transition of micelle shape is not observed because the charge of cation is not enough to neutralize the polar of micelle surface.展开更多
We established a novel droplet model (with-gravity model) to show the gravity effect of the droplet in the contact angle experiment.By using with-gravity model, we obtained a three-dimensional topography of the drople...We established a novel droplet model (with-gravity model) to show the gravity effect of the droplet in the contact angle experiment.By using with-gravity model, we obtained a three-dimensional topography of the droplet including the height of the droplet, the shape of the baseline and the circumference of the baseline.Comparing the with-gravity model with the ideal spherical model, our model considered the measurement error caused by gravity effect in the contact angle experiment which is a key point to influence the three-dimension topography of the droplet.From the calculation of our model, we found that there were two important points to enhance the measurement error: the size of the droplet and the contact angle.With the droplet and the contact angle became larger, measurement error was obviously increased.展开更多
基金supported by the National Natural Science Foundation of China(21202133)Specialized Research Fund for the Doctoral Program of Higher Education(20050736001)Young Teacher Research Foundation of Northwest Normal University(NWNU-LKQN-08-8,NWNU-kjcxgc-03-73)~~
基金Supported by the Outstanding Overseas Research Team Project of the Chinese Academy of Sciences, the National Natural Science Foundation of China （20221603）, and the Research Fund of Key Lab for Nanomaterials, Ministry of Education, China （2006-1）.
文摘The presence of salt has a profound effect on the size,shape and structure of sodium dodecyl sulfate(SDS)micelles.There have been a great number of experiments on SDS micelles in the presence and absence of salt to study this complex problem.Unfortunately,it is not clear yet how electrolyte ions influence the structure of micelles.By describing the compromise between dominant mechanisms,a simplified atomic model of SDS in presence of salt has been developed and the molecular dynamics(MD)simulations of two series of systems with different concentrations of salt and charges of ion have been performed.Polydispersity of micelle size is founded at relatively high concentration of SDS and low charge of cation.Although the counter-ion pairs with head groups are formed,the transition of micelle shape is not observed because the charge of cation is not enough to neutralize the polar of micelle surface.
基金Funded by Beijing Natural Science Foundation (No. 2062004)National Natural Science Foundation of China (No. 50502001 and No. 60576012)+1 种基金the Fundamental Research Funds for the Central UniversitiesNorth China Institute of Science and Technology (No. 2011B24)
文摘We established a novel droplet model (with-gravity model) to show the gravity effect of the droplet in the contact angle experiment.By using with-gravity model, we obtained a three-dimensional topography of the droplet including the height of the droplet, the shape of the baseline and the circumference of the baseline.Comparing the with-gravity model with the ideal spherical model, our model considered the measurement error caused by gravity effect in the contact angle experiment which is a key point to influence the three-dimension topography of the droplet.From the calculation of our model, we found that there were two important points to enhance the measurement error: the size of the droplet and the contact angle.With the droplet and the contact angle became larger, measurement error was obviously increased.
