The properties of styrene-butadiene rubber (SBR) reinforced by modified silica was investigated according to national standards. Silica was modified by silane coupling agents KH-570, KH-590, and KH-792. The optimized ...The properties of styrene-butadiene rubber (SBR) reinforced by modified silica was investigated according to national standards. Silica was modified by silane coupling agents KH-570, KH-590, and KH-792. The optimized geome-tries of molecular modified silica reinforced SBR were obtained by using B3LYP calculation of density functional theory with the 6-31+G basis sets. The natural bond orbital analyses were carried out. The Si—O bond length of silica modified by KH-792 was the shortest and the electronegative of O was the highest. It indicated that the connection between silica and KH-792 was the tightest. Higher tensile strength and elongation of reinforced SBR was obtained by silica modified with the KH-792. It was caused by large delocalization of lone pair electrons of the two N atoms in KH-792. The S—C bond length in silica modified by KH-590 was longer than the ordinary S—C bond length. Then the sulfur free radical (·S·) was produced more easily in vulcanization. The degree of crosslink was increased by the cross-linkage of the rubber molecule and the sulfur free radical. That was why the highest stress and tear strength of reinforced SBR was produced when silane coupling agent KH-590 was used. The calculation results was in accord with experimental data.展开更多
Chinese cabbage was cultivated in upland soil with the addition of biochar in order to investigate the potential for reduction of greenhouse gas emissions. Barley straw biochar(BSB) was introduced in a Wagner pot(1/50...Chinese cabbage was cultivated in upland soil with the addition of biochar in order to investigate the potential for reduction of greenhouse gas emissions. Barley straw biochar(BSB) was introduced in a Wagner pot(1/5000a) in amounts of 0(BSB0, control), 100(BSB100), 300(BSB300), and 500(BSB500) kg 10a^(-1). After the addition of BSB into the upland soil, carbon dioxide(CO_2) emission increased while methane(CH_4) and nitrous oxide(N_2O) emissions decreased. The highest CO2 flux was measured for the BSB500 sample,(84.6 g m^(-2)) followed by BSB300, BSB100, and BSB0 in decreasing order. Relative to those of control, the total CH_4 flux and N_2O flux for the BSB500 treatment were lower by 31.6% and 26.1%, respectively. The global warming potential(GWP) of the treatment without biochar was 281.4 g CO_2 m-2 and those for treatments with biochar were in the range from 194.1 to 224.9 g CO_2 m^(-2). Therefore, introducing BSB into upland soil to cultivate Chinese cabbages can reduce the global warming potential.展开更多
The grain-size distribution characteristics and grain-size parameters of sediment in two vertical sections of Daniugou peatland in the Changbai Mountains were systematically investigated.A comparative analysis of the ...The grain-size distribution characteristics and grain-size parameters of sediment in two vertical sections of Daniugou peatland in the Changbai Mountains were systematically investigated.A comparative analysis of the sediment granularity using a discriminative function with Hongyuan peat,red clay,loess-paleosol,fluvial deposit as well as lacustrine deposit was also conducted.It turns out that the vertical section of Daniugou peat ash is primarily constituted by clay and silt particles,and the content of sand is relatively small.Grain-size frequency curves generally show a single-peak modality while a bimodal pattern is detected in the upper layer.The grain-size component and peak pattern of grain-size frequency curves also illustrate that peat ash materials were transported to the peatland by long-range aeolian dust during the deposition process,while there existed short-distance dust influence in peat deposition of the upper layer.Comparisons of grain-size parameters and the discriminative Y-value of Daniugou peat ash with those of typical aeolian sediments show close similarities,suggesting the possibility that atmospheric dust transport processes were involved in the accumulation of peat again.Moreover,the variations of grain-size distribution suggest the local environmental deterioration which is just the driving force of local dust elevation.Grain-size analysis of peatland sediment is demonstrated to be one effective method to extract information about regional and global environmental evolution,and more attention should be paid to current local ecological environment and to seeking a balance between economic development and environmental protection in Northeast China.展开更多
Bleaching with oxygen-containing agents and recirculation of process streams in the pulp and paper industry has increased the accumulation of oxalic acid and danger for precipitation of calcium oxalate encrusts, scali...Bleaching with oxygen-containing agents and recirculation of process streams in the pulp and paper industry has increased the accumulation of oxalic acid and danger for precipitation of calcium oxalate encrusts, scaling. Analysis and control of oxalic acid in bleaching filtrates is therefore becoming increasingly important in the pulp and paper industry. Chromatographic methods, such as IC and HPLC, are generally more time-consuming but are valuable as standard methods for determination of oxalic acid. However, the instrumentation needed is expensive and stationary. In this study, an enzymatic method based on oxalate oxidase and peroxidase was developed to determine oxalic acid in authentic bleaching filtrates using a spectrophotometer. The results showed that bleaching filtrates contain some compounds interfering with the enzymatic method. Pretreatment of the samples with activated charcoal was a successful approach for decreasing problems with interference. By using dilution followed by charcoal treatment, the results obtained from five bleaching filtrates with the colorimetric method correlated very well with those obtained using IC. This study offers a selective, fast and mobile analysis method to determine oxalic acid in bleaching fiRrates from the pulp and paper industry, The convenient enzyme-based method improves the possibilities for control of critical oxalic acid concentrations in closed-loop bleaching streams.展开更多
文摘The properties of styrene-butadiene rubber (SBR) reinforced by modified silica was investigated according to national standards. Silica was modified by silane coupling agents KH-570, KH-590, and KH-792. The optimized geome-tries of molecular modified silica reinforced SBR were obtained by using B3LYP calculation of density functional theory with the 6-31+G basis sets. The natural bond orbital analyses were carried out. The Si—O bond length of silica modified by KH-792 was the shortest and the electronegative of O was the highest. It indicated that the connection between silica and KH-792 was the tightest. Higher tensile strength and elongation of reinforced SBR was obtained by silica modified with the KH-792. It was caused by large delocalization of lone pair electrons of the two N atoms in KH-792. The S—C bond length in silica modified by KH-590 was longer than the ordinary S—C bond length. Then the sulfur free radical (·S·) was produced more easily in vulcanization. The degree of crosslink was increased by the cross-linkage of the rubber molecule and the sulfur free radical. That was why the highest stress and tear strength of reinforced SBR was produced when silane coupling agent KH-590 was used. The calculation results was in accord with experimental data.
基金supported by the Basic Science Research Program through the National Research Foundation of Korea (NRF)funded by the Ministry of Education,Science and Technology (2012R1A2A2A01015706)the support of "Cooperative Research Program for Agriculture Science & Technology Development (Project No. PJ011227042016)" Rural Development Administration, Republic of Korea
文摘Chinese cabbage was cultivated in upland soil with the addition of biochar in order to investigate the potential for reduction of greenhouse gas emissions. Barley straw biochar(BSB) was introduced in a Wagner pot(1/5000a) in amounts of 0(BSB0, control), 100(BSB100), 300(BSB300), and 500(BSB500) kg 10a^(-1). After the addition of BSB into the upland soil, carbon dioxide(CO_2) emission increased while methane(CH_4) and nitrous oxide(N_2O) emissions decreased. The highest CO2 flux was measured for the BSB500 sample,(84.6 g m^(-2)) followed by BSB300, BSB100, and BSB0 in decreasing order. Relative to those of control, the total CH_4 flux and N_2O flux for the BSB500 treatment were lower by 31.6% and 26.1%, respectively. The global warming potential(GWP) of the treatment without biochar was 281.4 g CO_2 m-2 and those for treatments with biochar were in the range from 194.1 to 224.9 g CO_2 m^(-2). Therefore, introducing BSB into upland soil to cultivate Chinese cabbages can reduce the global warming potential.
基金Under the auspices of National Natural Science Foundation of China (No 40871089, 40830535)State Key Laboratory of Loess and Quaternary Geology,Institute of Earth Environment, Chinese Academy of Sciences (No SKLLQG0910)
文摘The grain-size distribution characteristics and grain-size parameters of sediment in two vertical sections of Daniugou peatland in the Changbai Mountains were systematically investigated.A comparative analysis of the sediment granularity using a discriminative function with Hongyuan peat,red clay,loess-paleosol,fluvial deposit as well as lacustrine deposit was also conducted.It turns out that the vertical section of Daniugou peat ash is primarily constituted by clay and silt particles,and the content of sand is relatively small.Grain-size frequency curves generally show a single-peak modality while a bimodal pattern is detected in the upper layer.The grain-size component and peak pattern of grain-size frequency curves also illustrate that peat ash materials were transported to the peatland by long-range aeolian dust during the deposition process,while there existed short-distance dust influence in peat deposition of the upper layer.Comparisons of grain-size parameters and the discriminative Y-value of Daniugou peat ash with those of typical aeolian sediments show close similarities,suggesting the possibility that atmospheric dust transport processes were involved in the accumulation of peat again.Moreover,the variations of grain-size distribution suggest the local environmental deterioration which is just the driving force of local dust elevation.Grain-size analysis of peatland sediment is demonstrated to be one effective method to extract information about regional and global environmental evolution,and more attention should be paid to current local ecological environment and to seeking a balance between economic development and environmental protection in Northeast China.
基金This work was supported by Vinnova and the Knowledge Foundation in Sweden.
文摘Bleaching with oxygen-containing agents and recirculation of process streams in the pulp and paper industry has increased the accumulation of oxalic acid and danger for precipitation of calcium oxalate encrusts, scaling. Analysis and control of oxalic acid in bleaching filtrates is therefore becoming increasingly important in the pulp and paper industry. Chromatographic methods, such as IC and HPLC, are generally more time-consuming but are valuable as standard methods for determination of oxalic acid. However, the instrumentation needed is expensive and stationary. In this study, an enzymatic method based on oxalate oxidase and peroxidase was developed to determine oxalic acid in authentic bleaching filtrates using a spectrophotometer. The results showed that bleaching filtrates contain some compounds interfering with the enzymatic method. Pretreatment of the samples with activated charcoal was a successful approach for decreasing problems with interference. By using dilution followed by charcoal treatment, the results obtained from five bleaching filtrates with the colorimetric method correlated very well with those obtained using IC. This study offers a selective, fast and mobile analysis method to determine oxalic acid in bleaching fiRrates from the pulp and paper industry, The convenient enzyme-based method improves the possibilities for control of critical oxalic acid concentrations in closed-loop bleaching streams.
