In order to improve leaching efficiency of vanadium from stone coal,the combination of blank roasting and bioleaching using Bacillus mucilaginosus(B.mucilaginosus)mutants was evaluated.The atmospheric and room tempera...In order to improve leaching efficiency of vanadium from stone coal,the combination of blank roasting and bioleaching using Bacillus mucilaginosus(B.mucilaginosus)mutants was evaluated.The atmospheric and room temperature plasma(ARTP)technique was used to generate B.mucilaginosus mutants.The results showed that a mutant B.mucilaginosus BM-50,after ARTP irradiation for 50 s,had the highest acid production.The total content of the organic acid produced by B.mucilaginosus BM-50 was nearly doubled compared with the wild strain after 2 days.After 20 days,vanadium leaching rate with B.mucilaginosus BM-50 reached 18.2%,which was improved compared with the original bacteria(15.3%).A pretreatment via blank roasting for stone coal further improved the vanadium dissolution by bioleaching,namely,68.3%vanadium was extracted,which was much higher than that without blank roasting.It is shown that bioleaching by bacterial mutants by ARTP irradiation combined with blank roasting has great potential for improving vanadium recovery from low-grade vanadium bearing stone coal.展开更多
The present study aims at the recovery of potassium from muscovite mica(which contains K_(2)O;~10 wt%)using NaCl-roasting coupled with H_(2)SO_(4)-leaching process.The preliminary acid leaching studies applying differ...The present study aims at the recovery of potassium from muscovite mica(which contains K_(2)O;~10 wt%)using NaCl-roasting coupled with H_(2)SO_(4)-leaching process.The preliminary acid leaching studies applying different mineral acids resulted in a potassium recovery of 8%−18%.The optimum leaching conditions for the maximum recovery were 4 mol/L H_(2)SO_(4),60 min leaching time and liquid-solid ratio 4 mL/g at 90℃.However,the roasting of muscovite with additive NaCl(muscovite:NaCl mass ratio of 1:1.00,900℃,45 min)followed by H_(2)SO_(4)-leaching(95℃,60 min)extracted potassium to the tune of 98%.Under similar roasting conditions,the H_(2)O-leaching process extracted only 60%of potassium.The effects of various roasting and leaching parameters such as temperature,time,NaCl concentration,acid concentration,liquid-solid ratio on potassium extraction were evaluated.The appearance of the sylvite(KCl)mineral phase in the NaCl-roasted muscovite and its disappearance in the acid/water leached residue confirmed the physical and chemical distortions of the muscovite crystal structure.The possible mechanism of potassium release from the complex muscovite structure was elucidated based on available literature substantiated by characterizations using X-ray diffraction(XRD)and scanning electron microscopy with energy dispersive X-rays spectroscopy(SEM-EDX).展开更多
In this paper,sulfidation mechanism of cerussite in the presence of sulphur at high temperatures was investigated based on micro-flotation,X-ray powder diffractometry(XRD),electron probe microanalysis(EPMA)and X-ray p...In this paper,sulfidation mechanism of cerussite in the presence of sulphur at high temperatures was investigated based on micro-flotation,X-ray powder diffractometry(XRD),electron probe microanalysis(EPMA)and X-ray photoelectron spectroscopy(XPS).The micro-flotation test results showed that flotation recovery of the treated cerussite increased to above 80%under a suitable flotation condition.It was found that the S/PbCO3 mole ratio and pH obviously affected flotation recovery.XRD analysis results confirmed that the cerussite was decomposed into massicot and then was transformed into mainly PbS and PbO·PbSO4 after sulfidation roasting.EPMA analysis results demonstrated that surface of the obtained massicot was smooth,but surface of the artificial galena was rough and even porous.Content of oxygen decreased,whereas content of sulphur increased with an increase in the S/PbCO3 mole ratio.XPS analysis results revealed that various lead-bearing species,including mainly PbS,PbSO4 and PbO·PbSO4,were generated at the surface.Formation of PbS was advantageous to flotation of the treated cerussite.Based on these results,a reaction model of the cerussite sulfurized with sulphur was proposed.展开更多
β-Sialon/ZrN bonded corundum composites were synthesized using fused white corundum,alumina micro powder,zircon and carbon black by nitridation reaction sintering process. Phase composition and microstructure of the ...β-Sialon/ZrN bonded corundum composites were synthesized using fused white corundum,alumina micro powder,zircon and carbon black by nitridation reaction sintering process. Phase composition and microstructure of the synthesized composites were investigated by X-ray powder diffraction and scanning electronic microscope,and the formation process of the composites was discussed. The results show that the composites with different compositions can be obtained by controlling the heating temperature and contents of zircon and carbon black. The proper temperature to synthesize the composites is 1773 K.展开更多
基金Project(2015ZX07205003)supported by Major Science and Technology Program for Water Pollution Control and Treatment of China
文摘In order to improve leaching efficiency of vanadium from stone coal,the combination of blank roasting and bioleaching using Bacillus mucilaginosus(B.mucilaginosus)mutants was evaluated.The atmospheric and room temperature plasma(ARTP)technique was used to generate B.mucilaginosus mutants.The results showed that a mutant B.mucilaginosus BM-50,after ARTP irradiation for 50 s,had the highest acid production.The total content of the organic acid produced by B.mucilaginosus BM-50 was nearly doubled compared with the wild strain after 2 days.After 20 days,vanadium leaching rate with B.mucilaginosus BM-50 reached 18.2%,which was improved compared with the original bacteria(15.3%).A pretreatment via blank roasting for stone coal further improved the vanadium dissolution by bioleaching,namely,68.3%vanadium was extracted,which was much higher than that without blank roasting.It is shown that bioleaching by bacterial mutants by ARTP irradiation combined with blank roasting has great potential for improving vanadium recovery from low-grade vanadium bearing stone coal.
文摘The present study aims at the recovery of potassium from muscovite mica(which contains K_(2)O;~10 wt%)using NaCl-roasting coupled with H_(2)SO_(4)-leaching process.The preliminary acid leaching studies applying different mineral acids resulted in a potassium recovery of 8%−18%.The optimum leaching conditions for the maximum recovery were 4 mol/L H_(2)SO_(4),60 min leaching time and liquid-solid ratio 4 mL/g at 90℃.However,the roasting of muscovite with additive NaCl(muscovite:NaCl mass ratio of 1:1.00,900℃,45 min)followed by H_(2)SO_(4)-leaching(95℃,60 min)extracted potassium to the tune of 98%.Under similar roasting conditions,the H_(2)O-leaching process extracted only 60%of potassium.The effects of various roasting and leaching parameters such as temperature,time,NaCl concentration,acid concentration,liquid-solid ratio on potassium extraction were evaluated.The appearance of the sylvite(KCl)mineral phase in the NaCl-roasted muscovite and its disappearance in the acid/water leached residue confirmed the physical and chemical distortions of the muscovite crystal structure.The possible mechanism of potassium release from the complex muscovite structure was elucidated based on available literature substantiated by characterizations using X-ray diffraction(XRD)and scanning electron microscopy with energy dispersive X-rays spectroscopy(SEM-EDX).
基金Project(51964027)supported by the National Natural Science Foundation of ChinaProject(2017FB084)supported by the Yunnan Province Applied Basic Research Project,ChinaProject(2019J0037)supported by the Education Department of Yunnan Province,China。
文摘In this paper,sulfidation mechanism of cerussite in the presence of sulphur at high temperatures was investigated based on micro-flotation,X-ray powder diffractometry(XRD),electron probe microanalysis(EPMA)and X-ray photoelectron spectroscopy(XPS).The micro-flotation test results showed that flotation recovery of the treated cerussite increased to above 80%under a suitable flotation condition.It was found that the S/PbCO3 mole ratio and pH obviously affected flotation recovery.XRD analysis results confirmed that the cerussite was decomposed into massicot and then was transformed into mainly PbS and PbO·PbSO4 after sulfidation roasting.EPMA analysis results demonstrated that surface of the obtained massicot was smooth,but surface of the artificial galena was rough and even porous.Content of oxygen decreased,whereas content of sulphur increased with an increase in the S/PbCO3 mole ratio.XPS analysis results revealed that various lead-bearing species,including mainly PbS,PbSO4 and PbO·PbSO4,were generated at the surface.Formation of PbS was advantageous to flotation of the treated cerussite.Based on these results,a reaction model of the cerussite sulfurized with sulphur was proposed.
基金Project(50274021) supported by the National Natural Science Foundation of China and Baoshan Iron and Steel Co., Ltd.
文摘β-Sialon/ZrN bonded corundum composites were synthesized using fused white corundum,alumina micro powder,zircon and carbon black by nitridation reaction sintering process. Phase composition and microstructure of the synthesized composites were investigated by X-ray powder diffraction and scanning electronic microscope,and the formation process of the composites was discussed. The results show that the composites with different compositions can be obtained by controlling the heating temperature and contents of zircon and carbon black. The proper temperature to synthesize the composites is 1773 K.