柴达木盆地三湖地区盐岩区表层调查方法研究

针对三湖地区盐岩区近地表结晶互层多而厚等难点,通过表层精细调查在结晶互层区优选最佳激发井深是提高地震采集资料品质的关键所在。首先定量分析了该区近地表介质的Q值特征;建立了工区实际近地表模型,对结晶互层进行激发模拟。接着介绍了用于该区近地表调查的微测井面积调查方法;研究提出了结合微测井初至时间、波形、能量以及Q值变化进行表层结构精细解释的三步分层法。最后,基于精细近地表分层和正演模拟结果,制定了盐岩区地震采集新的激发井深设计原则。盐岩区表层调查方法和激发井深设计优化技术研究成果在实际资料采集中取得了很好的应用效果,成功解决了复杂盐岩区的激发难题。

Effects of carbon anhydrase on utilization of bicarbonate in microalgae:a case study in Lake Hongfeng

A bidirectional labeling method was established to distinguish the proportions of HCO3- and CO2 utiliza- tion pathways of microalgae in Lake Hongfeng. The method was based on microalgae cultured in a medium by adding equal concentrations of NaH13CO3 with different 613C values simultaneously. The inorganic carbon sources were quantified according to the stable carbon isotope composition in the treated microalgae. The effects of extracellular carbonic anhydrase （CAex） on the HCO3 and CO2 utilization pathways were distinguished using acetazolamide, a potent membrane-impermeable carbonic anhydrase inhibitor. The results show utilization of the added HCO3- was only 8% of the total carbon sources in karst lake. The proportion of the HCO3- utilization path- way was 52% of total inorganic carbon assimilation. Therefore, in the natural water of the karst area, the microalgae used less bicarbonate that preexisted in the aqueous medium than CO2 derived from the atmosphere. CAex increased the utilization of inorganic carbon from the atmosphere. The microalgae with CAex had greater carbon sequestration capacity in this karst area.

Sequestration of carbon as carbonate in the critical zone：insights from the Himalayas and Tibetan Plateau

The carbon pool stored in soil carbonate is comparable to the soil organic carbon.Therefore,secondary calcite precipitation in supersaturated catchment could be an important,yet poorly constrained,carbon sink within the modern global carbon cycle.The chemical analysis of some dissolved species transported by rivers,such as elevated Sr/Ca and Mg/Ca ratios but also heavy stable Ca isotopic compositions,witness the formation of secondary calcite in rivers draining arid regions.However,in areas affected by active tectonics and rapid physical erosion,co-variations in the fluvial Sr/Ca and Mg/Ca ratios could also be related to incongruent carbonate weathering processes.Here,we present a model to assess the roles played by incongruent carbonate dissolution and secondary calcite precipitation in modern weathering processes.We tested and applied the model to rivers draining the Himalayan–Tibetan region.The results suggest that regional aridity in the drainage basin promotes carbon sequestration as secondary carbonate but that for a given runoff,incongruent dissolution of carbonate possibly related to rapid physical erosion amplifies such sequestration.The isotopic compositions(^(13)C/^(12)C and^(18)O/^(16)O)of detrital carbonate transported by the main rivers in South and South-East Tibet imply that around 1%of the suspended material transported by those rivers corresponds to secondary carbonate and can represent between 5%and 15%of the alkalinity flux.Most of these alkalinity transported as particulate material is,nevertheless related to the weathering of carbonate lithologies and is also subjected to dissolution prior its final storage in sedimentary basins.However,on glacial-interglacial timescale this will amplify the significant role of mountain weathering on climatic variations.

Agronomic Potential of Partially Acidnlated Rock Phos－phates in Acid Soils of Subtropical China

A glasshouse experiment was conducted to evaluate the agronomic potential of four partially acidulatedrock phosphates (PARP) in three representative soils sampled from subtropical China. The PARPs weremanufactured by attacking a moderately reactive phosphate rock either with sulfuric acid alone or withcombination of sulfuric and phosphoric acids at 30 or 60 percent of acidulation. Shoot dry weight and Paccumulation of six successive cuttings of ryegrass were used to compare the agronomic potential of thesefertilizers with that of the raw rock phosphate (RP) and monocalcium phosphate (MCP). Results indicatedthat the effectiveness of various phosphates was determined both by the solubility of the phosphates andby the acidity and P-fixing capacity of the soils. The higher the watersoluble P contained, the better theeffectiveness of the fertilizer was. Although plant P accumulation of PARP treatments was constantly lowerthan that of MCP treatment, some PARPs could still get a dry matter production similar to that of MCPtreatment. PARP SP60, which was acidulated with a mixture of sulfuric acid and phosphoric acid at 60percent of acidulation and contained the highest soluble P, was as effective as MCP in terms of dry matterproduction on all the soils. 560 and C1, which were both acidulated with sulfuric acid with the formerat 60 percent of acidulation and the latter at 30 percent but with a further addition of monoarninoniumphosphate, were more than 80 percent as effective as MCP. Raw RP also showed a reasonable effectivenesswhich increased with soil acidity. It was suggested from the study that some of these PARPs could beexpected to have a comparable field performance as soluble P fertilizers in the acid soil regions.

Distinct sedimentary environments and their influences on carbonate reservoir evolution of the Lianglitag Formation in the Tarim Basin,Northwest China

The Upper Ordovician Lianglitag Formation carbonate rocks are important oil and gas reservoirs in the Tarim Basin, Northwest China, with obviously distinct reservoir properties among different oilfields. As a case area of the above carbonate reser- voirs correlation, Tahe and Tazhong oilfields are chosen for the study through an integrated analysis of biostratigraphic isoch- ronous framework, cores, thin sections, logs, and strontium isotopes. The research shows that the two areas were respectively attributed to different carbonate platforms during the Lianglitag Formation depositional phase. For the Lianglitag Formation, five fourth-order sequences may be divided in Tazhong, whereas only four fourth-order sequences are preserved in Tahe that correspond to the lower ones observed in Tazhong. The Lianglitag Formation carbonate platform in Tahe was characterized by ramp and/or weak rimmed types, with low depositional rates （37 ktm/a）, higher whole-rock clastic contents, and higher 878r/86Sr isotope ratios of carbonate matrix, showing relatively deep-water environment and evident terrigenous input for car- bonate deposition. However, a strongly rimmed carbonate platform was developed in Tazhong, with high depositional rates of 250 p.m/a and less whole-rock clastic contents, indicating a high-energy depositional environment. Because of the sedimentary environment differences mentioned above, less high-energy facies but relatively intense syndepositional （early diagenetic） sea-water cementation of carbonates were developed in Tahe, and ubiquitous high-energy reef and shoal facies, with a frequent exposure to subaerial, and weak syndepositional sea-water cementation of carbonates in Tazhong. Therefore, fewer primary pores occurred in the Lianglitag Formation carbonate rocks of Tahe, whereas more primary pores were preserved in the same lithostratigraphic unit of the Tazhong （No. 1 fault zone）. Available high-energy reef-shoal facies and early diagenesis, with more primary pores preserved, provided a key material basis for the Lianglitag Formation carbonate reservoirs that largely oc- curred in Tazhong.

Hydrocarbon charging of the Ordovician reservoirs in Tahe-Lunnan area, China

The Tahe-Lunnan hydrocarbon province is China's largest region with oil-and-gas-producing marine carbonate rocks. However, in terms of multi-source hydrocarbon generation, multi-episode reservoir adjustment and reconstruction, it remains unsettled how to determine the geological period of primary hydrocarbon filling of the Ordovician reservoir in this region. Based on the analysis of distribution and properties of reservoir, hydrocarbon filling of the Cambrian source rocks in the Late Caledon stage has largely been destroyed. However, hydrocarbon filling of the Middle Ordovician source rocks in the Early Carboniferous resulted in the major body of crude oil. During the charging process, the hydrocarbons were oxidatively degraded to heavy oil due to the poor closure conditions, which is corroborated by homogenization temperature of inclusions. Moreover, the capturing of hydrocarbon inclusions with high-temperature does not represent the filling of mature petroleum in the later period, but represents the result of the natural gas containing light fraction. Therefore, the Tahe-Lunnan area underwent two hydrocarbon filling processes, and the invasion of excessive dry gas led to a gas-washing fractionation upon the original Ordovician reservoirs.