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盐水组成对极性组分在石英表面吸附的影响 被引量:8
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作者 陈晨 董朝霞 +4 位作者 高玉莹 林梅钦 杨子浩 杨杰 高景滨 《石油学报》 EI CAS CSCD 北大核心 2017年第2期217-226,共10页
油藏按储层岩性分类主要包括:砂岩油藏、砾岩油藏、碳酸盐岩油藏等。中国砂岩油藏的储量最高,而砂岩的主要成分是石英、长石、黏土矿物等,其中石英的含量居于首位。应用岩心驱替实验、石英砂静态吸/脱附实验、模拟油接触角实验、Zeta电... 油藏按储层岩性分类主要包括:砂岩油藏、砾岩油藏、碳酸盐岩油藏等。中国砂岩油藏的储量最高,而砂岩的主要成分是石英、长石、黏土矿物等,其中石英的含量居于首位。应用岩心驱替实验、石英砂静态吸/脱附实验、模拟油接触角实验、Zeta电位实验研究了盐水的化学组成对原油中酸/碱极性组分在石英表面吸/脱附的影响。结果表明,在中性/弱碱性地层水条件下,原油中的酸性极性组分发生电离,可以通过二价阳离子架桥吸附在石英表面;碱组分不发生电离处于分子状态,且与石英表面的范德华力较弱,无法吸附在石英表面。在弱酸性条件下,酸性极性组分因电离被抑制,处于分子状态,可通过氢键吸附在石英表面;碱性组分发生电离后带正电,可通过库仑力吸附在带负电的石英表面。 展开更多
关键词 盐水组成 粒子间相互作用 原油极性组分 吸/脱附 岩心驱替实验 接触角
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Influence of Pore Size,Salinity and Gas Composition upon the Hydrate Formation Conditions 被引量:17
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作者 杨明军 宋永臣 +2 位作者 刘瑜 陈拥军 李清平 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2010年第2期292-296,共5页
An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that t... An experimental device was set up to study the hydrate formation conditions.Effects of pore size,salinity,and gas composition on the formation and dissociation of hydrates were investigated.The result indicates that the induction time for the formation of hydrates in porous media is shorter than that in pure water.The decrease in pore size,by decreasing the size of glass beads,increases the equilibrium pressure when the salinity and temperature are kept constant.In addition,higher salinity causes higher equilibrium pressure when the pore size and temperature are kept constant.It is found that the effects of pore size and salinity on the hydrate equilibrium are quite different.At lower methane concentration,the hydrate equilibrium is achieved at lower pressure and higher temperature. 展开更多
关键词 HYDRATE EQUILIBRIUM pore size SALINITY gas composition
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