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原位探测防污高分子材料与液体界面的分子结构 被引量:1
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作者 Chengcheng Zhang Ralph Crisci Zhan Chen 《物理化学学报》 SCIE CAS CSCD 北大核心 2020年第10期45-57,共13页
海洋生物附着在船体表面会导致严重的燃油消耗的增加,防污高分子材料的研究因此成为对海洋船只运行极其重要的课题。这些高分子可以被用作船只的表面涂层,从而保护船只不受到海洋生物的吸附和生长的影响。两性离子高分子近年来已经逐渐... 海洋生物附着在船体表面会导致严重的燃油消耗的增加,防污高分子材料的研究因此成为对海洋船只运行极其重要的课题。这些高分子可以被用作船只的表面涂层,从而保护船只不受到海洋生物的吸附和生长的影响。两性离子高分子近年来已经逐渐成为潜力巨大的防污材料。研究表明,这些两性离子高分子的表面在水中的强水化作用对于其防污性能有至关重要的影响。在本篇综述中,我们总结了最近通过使用和频(SFG)振动光谱技术来实现的对防污材料的界面分析工作。SFG是一种表面敏感的技术,可以在原位并实时检测界面高分子和水分子的分子结构。我们总结的防污材料包括两性离子高分子,混合电荷式高分子以及两性的拟肽高分子材料。这些材料的界面水研究,以及盐离子对界面水分子作用会被详细讨论。我们也将介绍这些防污材料与蛋白质及海藻之间的作用。以上这些研究清楚地表明了高分子界面强水化与防污性能之间的关联,也显示了SFG是对高分子材料防污机理探索的一个强有力的分析技术。 展开更多
关键词 防污材料 和频共振光谱 界面水 两性离子高分子 盐离子效应 蛋白质作用
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Salting-out effect of ionic liquids on isobaric vapor-liquid equilibrium of acetonitrile-water system
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作者 方静 赵蕊 +2 位作者 王辉 李春利 刘婧 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2015年第8期1369-1373,共5页
This paper presents the vapor–liquid equilibrium(VLE) data of acetonitrile–water system containing ionic liquids(ILs) at atmospheric pressure(101.3 k Pa). Since ionic liquids dissociate into anions and cations, the ... This paper presents the vapor–liquid equilibrium(VLE) data of acetonitrile–water system containing ionic liquids(ILs) at atmospheric pressure(101.3 k Pa). Since ionic liquids dissociate into anions and cations, the VLE data for the acetonitrile + water + ILs systems are correlated by salt effect models, Furter model and improved Furter model. The overall average relative deviation of Furter model and improved Furter model is 5.43% and 4.68%, respectively. Thus the salt effect models are applicable for the correlation of IL containing systems. The salting-out effect theory can be used to explain the change of relative volatility of acetonitrile–water system. 展开更多
关键词 Salting-out effect Vapor–liquid equilibrium Separation Ionic liquid Acetonitrile
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Coastal afforestation effects on soil properties at Hatiya in Bangladesh
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作者 K.M.Shaifullah S.M.Sirajul Haque +1 位作者 M.Sujauddin Shyamal Karmakar 《Journal of Forestry Research》 SCIE CAS CSCD 2009年第A3期243-248,287,共7页
An exploratory study was conducted in the coastal plantation (12-and 17-year-old Sonneratia apetala) of Char Alim and Char Piya and on their adjacent barren lands at Char Rehania and Char Nurul Islam in Hatiya of Noak... An exploratory study was conducted in the coastal plantation (12-and 17-year-old Sonneratia apetala) of Char Alim and Char Piya and on their adjacent barren lands at Char Rehania and Char Nurul Islam in Hatiya of Noakhali district, in Bangladesh to determine afforestation effects on soil properties. At soil depths of 0-10, 10-30 and 30-40 cm across three different land strips viz. inland, middle and sea side in 12-and 17-year-old keora (Sonneratia apetala) plantations, soil moisture, particle density, organic matter and C, total N, pH, available P, K, Na, Ca and Mg were significantly (p≤0.05, p≤0.01, p≤0.001) higher, and soil salinity significantly (p≤0.001) lower than that in their adjacent barren lands. Soil moisture, particle density, organic matter and C, total N, pH, soil salinity, available P, K, Na, Ca and Mg of surface soil in Char Alim plantation at inland were 31.09%, 2.24 g·cm-3, 2.41%, 4.14%, 0.58%, 7.07, 0.09 dS·cm-1, 28.06 mg·L-1, 0.50 mg·L-1 11.5 mg·L-1, 3.30 mg·L-1 and 2.7 mmol·kg-1, respectively. Their corresponding values for the same depth and land position at adjacent Char Rehania barren land were 16.69%, 1.25g·cm-3, 0.43%, 0.74%, 0.25%, 6.57, 0.13 dS·cm-1, 13.07mg·L-1, 0.30 mg·L-1, 1.4 mg·L-1, 0.30 mmol·kg-1 and 0.50 mg·L-1, respectively. Soil moisture, particle density, organic matter and C, total N, pH, available P, K and Ca decreased, and soil salinity, available Na and Mg increased from inland towards sea side in the plantations. Although soil texture did not differ in most soil depths between plantation and adjacent barren land, proportion of sand particle was significantly (p≤0.01) lower and silt particle significantly (p≤0.001) in the plantations higher than that in their adjacent barren lands. In the study, evaluation of all the parameters was also done for the other pair of lands. 展开更多
关键词 coastal afforestation keora plantation soil physicochemical properties afforestation effect soil texture soil base cations Sonneratia apetala BANGLADESH
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