水洗加工方法对东天山地球化学勘查样品测试结果的影响研究

水洗样品加工方法使用在东天山地区1∶25万化探中,产生了良好的找矿效果,为了了解水与样品的相互作用会不会影响测试结果,在东戈壁钼矿选区,通过对加工用水、测试结果和地球化学图对比研究,发现这种方法是把双刃剑,水洗样品加工会使测试结果更清楚地显示其原岩的原生晕地球化学规律,但是也屏蔽了其次生晕产生的化探异常。在实际异常查证工作中针对地表与浅部矿床产生的原生晕异常比上升水异常更加容易利用。在区域地球化学勘查找矿中该方法产生了一定的积极影响。

Electrochemical behaviors of Mg^(2+) and B^(3+) deposition in fluoride molten salts

By using cyclic and linear sweep voltammetry,the electrochemical deposition behaviors of Mg^2＋ and B^3＋ in fluorides molten salts of KF-MgF2 and KF-KBF4 at 880℃ were investigated,respectively.The results show that the electrochemical reduction of Mg^2＋ is a one-step reaction as Mg^2＋＋2e-→Mg in KF-1%MgF2 molten salt,and the electrochemical reduction of B^3＋ is also a one-step reaction as B^3＋＋3e-→B in KF-KBF4 （1%,2% KBF4） molten salts.Both the cathodic reduction reactions of Mg^2＋ and B^3＋ are controlled by diffusion process.The diffusion coefficients of Mg^2＋ in KF-MgF2 molten salts and B^3＋ in KF-KBF4 molten salts are 6.8×10^-7 cm^2/s and 7.85×10^-7 cm^2/s,respectively.Moreover,the electrochemical synthesis of MgB2 by co-deposition of Mg and B was carried out in the KF-MgF2-KBF4 （molar ratio of 6：1：2） molten salt at 750℃.The X-ray diffraction analysis indicates that MgB2 can be deposited on graphite cathode in the KF-MgF2-KBF4 molten salt at 750℃.

Nitrate Accumulation in Soil Profile of Dry Land Farming in Northwest China

A long-term fertilizer experiment on dry land of the Loess Plateau, northwestChina, has been conducted since 1984 to study the distribution and accumulation of NO_3-N down to adepth of 400 cm in the profile of a coarse-textured dark loessial soilafter continuous winter wheatcropping. Thirteen fertilizer treatments consisted of four levels of N and P applied alone or incombination. Annual N and P (P_2O_5) rates were 0, 45, 90, 135 and 180 kg ha^(-1). After 15successive cropping cycles, the soil samples were taken from each treatment for analysis of NO_3-Nconcentration. The results showed that NO_3-N distribution in the soil profile was quite differentamong the treatments. The application of fertilizer N alone resulted in higher NO_3-N concentrationin the soil profile than the combined application of N and P, showing that application of P couldgreatly reduce the NO_3-N accumulation. With an annual application of 180 kg N ha^(-1) alone, a peakin NO_3-N accumulation occurred at 140 cm soildepth, and the maximum NO_3-N concentration in thesoils was 67.92 mg kg^(-1). The amount of NO_3-N accumulated in the soil profile decreased as thecumulative N uptake by the winter wheat increased. Application of a large amount of N resulted inlowerN recoveries in winter wheat and greater NO_3-N accumulation in soil profile. KO_3-N did notenter underground water in the study region; therefore, there is no danger of underground waterpollution. Amount of NO_3-N accumulation can be predicted by an equation according to annual N and Prates based on the results of this experiment.

Biogenic silicate accumulation in sediments, Jiaozhou Bay

It has been widely recognized that low silicate content in seawater is a major limiting factor to phytoplankton primary production in Jiaozhou Bay. However the reason of Si-limitation remains poorly understood. In the present study we measured the biogenic silicate content and discussed the ac- cumulation of silicate in Jiaozhou Bay sediment. The results show that the biogenic silica content in the sediment of the Jiaozhou Bay is obviously much higher than those in the Yellow Sea and the Bohai Sea. The BSi:TN ratios and BSi:16P ratios in the sediment are > 1 and the OC:BSi ratio in sediment is lower than these of Redfield ratio (106:16), indicating that the decomposition rate of OC is much higher than that for BSi in similar conditions. Therefore, the majority of the biogenic silicate was buried and thus did not participate in silicate recycling. Silicate accumulation in sediment may explain why Si limits the phytoplankton growth in the Jiaozhou Bay. Comparing the flux of biogenic silicate from sediments with primary production rate, it can be concluded that only 15.5% of biogenic silicate is hydrolyzed during the journey from surface to bottom in seawater, thus approximate 84.5% of biogenic silicate could reach the bottom. The silicate releasing rate from the sediment to seawater is considerably lower than that of sedi- mentation of biogenic silicate, indicating silicate accumulation in sediment too. In a word, the silicate ac- cumulation in sediment is the key reason of silicate limiting to phytoplankton growth in Jiaozhou Bay.

Molecular Survey of Sulphate-Reducing Bacteria in the Deep-Sea Sediments of the West Pacific Warm Pool

The sulfate-reducing bacteria(SRB) community in the deep-sea sediments of the west Pacific Warm Pool(WP) was surveyed by molecular phylogenetic analyses using primers targeting the 16S rRNA gene fragments of SRB. Specific 16S rRNA gene libraries from five sediment layers(1-cm,3-cm,6-cm,10-cm and 12-cm layer) of the 12-cm core of WP-0 were constructed. The clones in the five libraries were differentiated by restriction fragment length polymorphism(RFLP) and representative clones were selected to sequence. It was found that the clones fell into four groups,which were closest related to Desulfotomaculum,Desul-facinum,Desulfomonile and Desulfanuticus. Desulfacinum-like clones were only detected in the upper layers of the sediment core,whereas Desulfomonile-like clones were only present in the deeper layers. Fluorescence in situ hybridization(FISH) was further carried out to visualize and count the SRB and bacteria in the five sediment layers. It was found that SRB constituted only a small proportion of the bacteria community(0.34%-1.95%) ,it had the highest content in the 3-cm layer(1.95%) and had a depth-related decreasing tendency along the 12-cm core.

On the Unusual Holocene Carbonate Sediment in Lake Nam Co,Central Tibet

In lacustrine sediments,aragonite is a widespread mineral,whereas monohydrocalcite is a rare carbonate mineral. In the cold and high-attitude Xizang (Tibetan) Plateau,where aragonite has been commonly found in lacustrine sediments,there is no aragonite,but low-Mg calcite,monohydrocalcite and trace dolomite. The lake receives solutes primarily from surface runoffs and remains fairly constant water chemistry for a long time. The total CaCO3 percentage in sediments could be controlled by evaporation and inflow of detrital materials. The absence of aragonite is unusual when compared to other lacustrine sediments from the Tibetan Plateau. This could be due to low Ca/Mg ratio,low salinity,low Mg and Ca concentration. Monohydrocalcite might precipitate from the lake water mediated by biological activities. Low-Mg calcite originated from minor ostracoda shell and the precipitation of lake water with biological activities.

Effects of clam size, food type, sediment characteristic, and seawater carbonate chemistry on grazing capacity of Venus clam Cyclina sinensis (Gmelin, 1791)

Aquaculture in saline-alkaline water has a major problem： microalgal blooming causes the pH of water to increase dramatically, thereby causing damage to the reared organisms. To solve this problem, we set out to find a candidate filter-feeding bivalve species suitable for saline-alkaline water to graze on microalgae and to control the pH. In the current study, we investigated the effect of carbonate alkalinity （CA, 2.5, 10.0, and 20.0 meq/L） and pH （8.0, 8.5, and 9.0） on the grazing capacity （GC） of the clam Cyclina sinensis. Additionally, the effect of clam size （small, medium, and large） and microalgae species （Nannochloropsis oculata, Chaetoceros miielleri, and lsochrysis galbana）, and the effect of bottom sediment characteristic （mud, sandy mud, and muddy sand） and thickness （3 and 6 cm） were analyzed as well. The results show that the GC on L galbana was the highest and small size had the maximum GC/W （W： wet weight including body and shells）. No significant differences were observed between sediment type and thickness. Regarding CA and pH, a significant decrease in GC by the pH or by their interaction was found. The GC ofC. sinensis was not greatly reduced in the treatments ofpH≤8.5 and CA≤20.0, and also not affected by bottom sediment type, indicating that this clam is capable to manage microalgal concentrations and might be a candidate species for pH reduction in saline-alkaline water ponds.

Response of Microbial Community to Petroleum Stress and Phosphate Dosage in Sediments of Jiaozhou Bay, China

The dynamic microcosms were used to evaluate the effect of oil spills on microbial ecological system in marine sediment and the enhancement of nutrient on the oil removal. The function and structure of microbial community caused by the oil pollution and phosphate dosage were simultaneously monitored by dehydrogenase activity assay and PCR-denaturing gradient gel electrophoresis(DGGE) techniques. The results indicated that the amount of total bacteria in all dynamic microcosms declined rapidly with incubation time. The number of petroleum-degrading bacteria and the activity of sediment dehydrogenase were gradually enhanced by petroleum in the oil-treated microcosms, while they both showed no obvious response to phosphate dosage. In comparison, phosphate spiked heterotrophic bacteria and they showed a significant increase in amount. DGGE profiles indicated that petroleum dosage greatly changed community structure, and the bacteria belonged to class Deltaproteobacteria, and phyla Bacteroidetes and Chlorobi were enriched. This study demonstrated that petroleum input greatly impacted the microbial community structure and consequently the marine sediment petroleum-degrading activity was enhanced. Phosphate dosage would multiply heterotrophic bacteria but not significantly enhance the petroleum degradation.

Denitrification and Nitrate Reduction to Ammoniumin Taihu Lake and Yellow Sea Inter-Tidal MarineSediments

Denitrification and nitrate reduction to ammonium in Taihu Lake and Yellow Sea inter-tidal marinesediments were studied. The sediment samples were made into slurry containing 150 g dry matter per liter.Various amounts of glucose and 5 mmol L-1 of potassium nitrate were added in order to achieve differentratios of glucose-C to nitrate-N. Acetylene inhibition technique was applied to measure denitrification in theslumes. All samples were incubated anaerobically under argon atmosphere. Data showed that Taihu Lakesediment produced more N2O than marine sediment. Denitrification potential was higher in Taihu Lakesediment than in marne one. Glucose added increased denitrification activity but not the denitrification po-tential of the sediments. Dissimilatory nitrate reduction to ammonium seemed to occur in marine sediment,but not in freshwater one. When the marine sediment was treated with 25 mmol L-1 glucose, its denitrification poteatial, as indicated by maximum N2O production by acetylene blockage, was lower than that treatedwith no or 2.5 mmol L-l glucose. Acetylene was suspected to have inhibitory effect on dissimilatory nitratereduction to ammonium.

Geological features and genesis of Gaotaigou borate deposit, Jilin, China

Gaotaigou borate deposit in Ji'an area, southeastern Jilin, is located in the easten end of Liaoning-Jilin (Liaoji)Proterozoic paleo-rift, which is a medium-sized deposit and makes up 67% of the total borate reserves in Jilin Province.The original borate ore bodies were formed by sedimentary exhalative process in Paleoproterozoic, but were activated and enriched by later metamorphism. In late stage of metamorphism, hydrothermal fluid of metamorphic origin made wallrocks be altered and the borate ore bodies be reformed. Ore bodies are strictly controlled by strata and their lithologies. In addition, the shape and spatial distribution of ore bodies are also defined by the Gaotaigou syncline. Combined with the ore-controlling factors and mineralizing features, it has been proposed that Gaotaigou borate deposit is a metamorphosed and hydrothermally altered sedimentary exhalative deposit.

Diagenetic control of magnetic susceptibility variation in Core MD98-2172 from the Eastern Timor Sea

Detailed mineral magnetic measurements, integrated with grain-size distribution and X-ray diffraction （XRD） analyses, were made on the marine sediments of Core MD98-2172, retrieved from the Eastern Timor Sea. Values of magnetic susceptibility in this core drop sharply down-core from -3.85 m deep below sediment/water interface and are very low at -5.35 m. However, both XRD and grain-size distribution results show no sudden change in terrigenous input during sedimentation. Mineral magnetic results indicate that the depth of -3.85 m may be an oxic/anoxic boundary. Therefore, the sediments below -3.85 m have been subjected to intense reductive diagenesis, whereas the sediments above -3.85 m are seldom affected. The magnetic properties of the sediments shallower than 3.85 m are dominated by pseudo-single domain （PSD） magnetite, with little down-core variation in its content and grain size. Below -3.85 m, the magnetic mineral assemblages that have survived in the sediments may record different stages of the reductive diagenesis： （1） the sediments from the 3.85-5.35 m interval are at the stage of iron oxide reduction; t＇SD magnetite is the major magnetic contributor, but it becomes less abundant and coarser down-core; （2） the sediments below -5.35 m are at the stage of sulphate reduction; ferrimagnetie minerals almost vanish and paramagnetic minerals contribute to down-core susceptibility variations, including pyrite as evidenced by high-temperature magnetic susceptibility measurements. However, the susceptibility variations below -5.35 m of Core MD98-2172 show obvious periodicity, despite the intense effect of reduetive diagenesis. Furthermore, the down-core susceptibility variations are coincident with fluctuations in the quantity of fine detrital particles （〈8 μm）, which may come mainly from the advection of the Indonesia Throughflow （ITF） and/or river input from Timor. Therefore, for Core MD98-2172, susceptibility variation below -5.35 m, which potentially correspond to fluctuations in the quantity of fine particles, may record the histories of the development of the ITF and precipitation on Timor.

Micromorphology and texture of niobium coating electrodeposited in NaCl−KCl−CsCl molten salt system

A low-toxicity and environment-friendly NaCl−KCl−CsCl−K_(2)NbF_(7) system was used to prepare Nb coatings on Mo substrates.The effects of temperature,current density and electrodeposition time on the micromorphologies and textures of the electrodeposited Nb coatings were studied.The results showed that Nb coatings obtained at 30−70 mA/cm^(2) in the temperature range of 700−750℃ were continuous and compact,with a hardness range of 2.16−2.45 GPa.As the columnar crystals grew with time,the preferential growth orientations of the Nb coatings changed from<200>to<211>and then became disordered.With increasing polarization,the morphologies of the Nb coatings changed from hexagonal star-like surface to conical or pyramid-like surface.

Molecular Characterization of Sulfate-Reducing Bacteria Community in Surface Sediments from the Adjacent Area of Changjiang Estuary

Sulfate-reducing bacteria(SRB),which obtain energy from dissimilatory sulfate reduction,play a vital role in the carbon and sulfur cycles.The dissimilatory sulfite reductase(Dsr),catalyzing the last step in the sulfate reduction pathway,has been found in all known SRB that have been tested so far.In this study,the diversity of SRB was investigated in the surface sediments from the adjacent area of Changjiang Estuary by PCR amplification,cloning and sequencing of the dissimilatory sulfite reductase beta subunit gene(dsr B).Based on dsr B clone libraries constructed in this study,diversified SRB were found,represented by 173 unique OTUs.Certain cloned sequences were associated with Desulfobacteraceae,Desulfobulbaceae,and a large fraction(60%) of novel sequences that have deeply branched groups in the dsr B tree,indicating that novel SRB inhabit the surface sediments.In addition,correlations of the SRB assemblages with environmental factors were analyzed by the linear model-based redundancy analysis(RDA).The result revealed that temperature,salinity and the content of TOC were most closely correlated with the SRB communities.More information on SRB community was obtained by applying the utility of Uni Frac to published dsr B gene sequences from this study and other 9 different kinds of marine environments.The results demonstrated that there were highly similar SRB genotypes in the marine and estuarine sediments,and that geographic positions and environmental factors influenced the SRB community distribution.

The Burial of Biogenic Silica, Organic Carbon and Organic Nitrogen in the Sediments of the East China Sea

We sampled the sediments of the East China Sea during 2005 and 2006, and analysed the contents of the biogenic matters: biogenic silica, organic carbon, and organic nitrogen. From the surface distribution we found the contents of these substances to be in the ranges of 0.72%-1.64%, 0.043%-0.82%, and 0.006%-0.11%, respectively. Their distributions were similar to each other, being high inside the Hangzhou Bay and low outside the bay. The vertical variations of the contents were also similar. In order to discuss the relation between them we analysed the variations of content with depth. They increased in the first 7 cm and then decreased with depth. The peaks were found at depths between 20 to 25 cm. The distribution of carbonate showed an opposite trend to that of biogenic matters. The content of total carbon was relatively stable with respect to depth, and the ratio of high organic carbon to carbonate showed a low burial efficiency of carbonate, which means that the main burial of carbon is organic carbon. In order to discuss the source of organic matters, the ratio of organic carbon to organic nitrogen was calculated, which was 8.01 to 9.65, indicating that the organic matter in the sediments was derived mainly from phytoplankton in the seawater.

Seasonal Dynamics of Turbidity Maximum in the Muthupet Estuary, India

Results are presented of the longitudinal and vertical profiling of salinity and suspended particulate matter(SPM) at the Muthupet estuary, India, during a one year period under widely varying freshwater flow conditions. Freshwater flow was available during post-monsoon and monsoon. An up-estuary shift in the location of estuarine turbidity maxima(ETM) was observed during the transition from post-monsoon to pre-monsoon and further it shifted downstream during the transition from pre-monsoon to monsoon, thereby exhibiting a pronounced seasonal cycle. The salinity intrusion was dependent on the freshwater discharge and was expressed as a power function of freshwater flow, explaining 97% of the variance. The formation of a salt plug in Muthupet estuary and its seasonal dynamics were observed, which is not an identified feature of any of the Indian estuaries studied so far. The geographical positions of salt plug and ETM core were more or less the same during their formation. The occurrence of two ETM during the LW of post-monsoon and the absence of ETM during monsoon explains the strong seasonal variation in the formation of ETM. The primary factor affecting the formation of ETM was identified as the freshwater flow over an annual cycle; the resuspension of sediments by tidal current affecting the formation on a flood/ebb cycle was secondary. The extent of shift of ETM was found to be an inverse logarithmic function of the freshwater discharge. The separation between ETM intrusion and salinity intrusion increased two fold with the increase in ETM intrusion.

Boron isotope geochemistry of Zigetang Co saline lake sediments,Tibetan Plateau

The origin of boron in boron-rich salt lakes in the Tibetan Plateau is highly controversial.In this study,we carried out a detailed study on boron geochemistry and isotope composition of lake sediments collected in Zigetang Co,central Tibet.Evaporites had high boron concentrations of 172.3–418.6 lg/g and δ^(11)B values of-8.2%to-3.3%,suggesting a non-marine origin for the saline lake.The boron isotopic fractionation factor,a,between evaporite and brackish water(a_(evaporite–brackish))decreased systematically with depth,from 0.9942 at the top of the drill core to 0.9893 at the bottom;the linear variation between α_(evaporite–brackish)and depth reflects boron isotopic fractionation associated with progressive crystallization.The positive correlation between δ^(11)B versus[B]and δ^(11)B versus depth in the evaporite phase reflects pH and boron speciation in the solution control on the adsorption of boron,and B(OH)_3 species incorporated preferentially into Mg(OH)_2 precipitation at high pH.

Influences of hydrological regime on heavy metal and salt ion concentrations in intertidal sediment from Chongming Dongtan, Changjiang River estuary, China

The tidal flat along the Changjiang(Yangtze) River estuary has long been reclaimed for the agricultural purposes, with the prevailing hydrological conditions during such pedogenic transformations being of great importance to their successful development. In this study, samples of surface sediment from Chongming Dongtan, situated at the mouth of the Changjiang River estuary, were collected and analyzed in order to understand how hydrological management can influence the concentrations of heavy metals and salt ions in pore water, and chemical fractionation of heavy metals during the reclamation process. We performed a series of experiments that simulated three dif ferent hydrological regimes: permanent flooding(R1), alternative five-day periods of wetting and drying(R2), continuous field capacity(R3). Our results exhibited good Pearson correlations coefficients between heavy metals and salt ions in the pore water for both R1 and R2. In particular, the concentrations of salt ions in the pore water decreased in all three regimes, but showed the biggest decline in R2. With this R2 experiment, the periodic concentration patterns in the pore water varied for Fe and Mn, but not for Cr, Cu, Pb and Zn. Neither the fractionation of Ni nor the residual fractions of any metals changed significantly in any regime. In R1, the reducible fractions of heavy metals(Cr, Cu, Zn and Pb) in the sediment decreased, while the acid extractable fractions increased. In R2, the acid extractable and the reducible fractions of Cr, Cu, Zn and Pb both decreased, as did the oxidizable fraction of Cu. These data suggest that an alternating hydrological regime can reduce both salinity and the availability of heavy metals in sediments.

Removal of K^+,Na^+,Ca^(2+),and Mg^(2+) from saline-alkaline water using the microalga Scenedesmus obliquus

The capability ofScenedesmus obliquus to remove cations （K^＋, Na^＋, Ca^2＋, Mg^2＋） from saline- alkaline water was investigated at different salinities （0, 5, 10, 15, 20, 25） and carbonate alkalinities （0, 5, 10, 15, 20, 25, 30, 35 mmol/L）. K^＋, Na^＋, Ca^2＋, and Mg^2＋ in saline-alkaline water were efficiently removed by S. obliquus. The maximum removal of the cations （29.37 mg for K^＋, 185.85 mg for Na^＋, 23.07 mg for Ca^2＋, 66.14 mg for Mg^2＋） occurred at salinity 25. The maximum removal of K^＋ （2.28 mg）, Na＋ （6.62 mg）, Ca^2＋ （1.01 mg）, and Mg2＋ （0.62 mg） occurred at carbonate alkalinities of 25 mmol/L for K＊, 35 mmol/L for Na＋, 20 mmol/L for Ca2＋, and 25 mmol/L for Mf＋, respectively. Under a salinity stress, the concentration of Na＇ in S. obliquus increased significantly, while that of K~ decreased significantly. The concentrations of Ca^2＋ and Mg2＋ decreased as well. The ratios of K＋/Na~, Ca2＋/Na^＋, and Mg^2＋/Na^＋ were significantly lower in all salinity treatments than those of the control. Under alkaline stress, the concentrations of Nan and K＋ in S. obliquus decreased significantly and the ratios of K^＋/Na^＋, Ca2＋/Na^＋, and Mg^2＋/Na^＋ were significantly higher in all treatments than in the control. Moreover, the concentrations of Ca2＋ and Mg2＋ in S. obliquus at alkalinities of 5-10 mmol/L were significantly higher than those of the other treatments. The removal of Na＋ by S. obliquus mainly occurs through biosorption, and Mg^2＋ and Ca^2 ＋ were removed through both biosorption and bioaccumulation.

System： Pattern of Phosphorus Sequestration in Different Depths of Sediment

The present study investigated potential effectiveness of certain chemical candidates for controlling internal phosphorus loading, and for delineating inactivation pattern in sediment depths of an eutrophic pond under simulated mesocosm condition. Chemical administration （@ 30 mg/dm3） resulted in phosphate precipitation from water column concomitant with inactivation in sediments, under specific pH range and/or redox regime. The alum-lime combination dosing wrought the maximum reduction in orthophosphate （65.6%） and soluble reactive phosphate （71.9%） in water plus the utmost increment in sediment-P （0.257 ppm）. The inactivated P forms typically exhibited a downhill concentration gradient with highest sequestration in the uppermost sediment stratum. Ironbound P displayed the highest mobility while calcium- and aluminum- bound P behaved almost immune to internal feedback dynamics. The combo-treatment was established as the most effective phosphate scavenging and confiscating agent, to be adopted as chemical remediation regime for de-eutrophication, restoration and rehabilitation of the water body.

Formation and influencing factors of carbonate source rock of the Lower Permian Chihsia Formation in Chaohu region, Anhui Province

Highly-mature carbonate source rock is essential to the exploration of oil and gas in southern China. In this study, the carbonate strata in the relatively well-developed Lower Permian Chihsia Formation (located in Chaohu, Lower Yangtze) were targeted, and the formation and influencing factors of source rock were discussed based on paleoenvironment reconstruction using comprehensive sedimentology, palynofacies, and organic geochemistry data. The results demonstrate that the Chihsia Formation is oxygen-deficient biogenic carbonate sediments, with marked variations in the organic and inorganic components, formed during a period of Permian transgression. The formation of source rock is the combined result of high bioproductivity and oxygen-deficient environment generated by transgression and oxygenation events which frequently occurred during transgression periods. Source rock was affected by self-dilution effects and diagenesis, causing its heterogeneous distribution in many intervals. Source rock is over 40 m thick, and can be identified based on its different organic, biological, and mineral composition characteristics. The carbonate rock appears to require no specific clay content in order to become a source rock. The combination of sedimentology, palynofacies, and organic geochemistry has provided an effective means for evaluating and predicting high-maturity carbonate source rock in the region.