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干湿循环作用下风积沙混凝土的抗硫酸盐侵蚀机理 被引量:13
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作者 董瑞鑫 申向东 +1 位作者 薛慧君 刘倩 《材料导报》 EI CAS CSCD 北大核心 2020年第24期24040-24044,共5页
选取内蒙古自治区乌兰布和沙漠的风积沙作为细骨料,用40%的风积沙替代部分河砂,采用核磁共振技术对风积沙混凝土的孔隙结构特征进行测试分析,利用扫描电子显微镜观察风积沙混凝土的微观形貌,并用X射线衍射技术分析混凝土的物相成分。研... 选取内蒙古自治区乌兰布和沙漠的风积沙作为细骨料,用40%的风积沙替代部分河砂,采用核磁共振技术对风积沙混凝土的孔隙结构特征进行测试分析,利用扫描电子显微镜观察风积沙混凝土的微观形貌,并用X射线衍射技术分析混凝土的物相成分。研究表明:质量损失率在干湿循环60次时出现“拐点”,风积沙混凝土和普通混凝土的抗压耐蚀系数分别降低到84%、87%;风积沙组谱面积是普通组的1.59~2.76倍,风积沙混凝土最大孔隙减小了34.1%,普通组最大孔隙减小了29.3%;风积沙混凝土和普通混凝土中无害孔的占比均不超过10%,孔隙度都与自由流体饱和度的变化成正比,混凝土内部存在着小孔隙向大孔隙演变的特性;风积沙混凝土和普通混凝土干湿循环120次对比干湿循环0次均出现了较多的CaSO 4·2H 2O衍射峰,腐蚀结晶物多为硫酸盐和碳酸盐;风积沙组的水泥浆体出现18~36μm的细长裂缝,普通组出现大量AFt。研究成果可为混凝土耐久性和盐侵环境下的工程建筑提供理论参考。 展开更多
关键词 风积沙混凝土 硫酸干湿循环 孔隙特征 盐蚀产物 机理
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Hot corrosion of modified Ti_3Al-based alloy coated with thin Na_2SO_4 film at 910 and 950℃ in air 被引量:2
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作者 Yu-hai QIAN Xi-chao LI +2 位作者 Mei-shuan LI Jing-jun XU Bin LU 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2017年第4期954-961,共8页
The hot corrosion behaviour of a modified Ti3Al-based alloy under thin Na2SO4deposit film was investigated at910and950°C in air.The corrosion product was identified by XRD and its morphologies on the surface and ... The hot corrosion behaviour of a modified Ti3Al-based alloy under thin Na2SO4deposit film was investigated at910and950°C in air.The corrosion product was identified by XRD and its morphologies on the surface and cross-section were observed bySEM.The alloy suffered from considerable hot corrosion attack.The mass gain versus time curves obtained by TGA exhibited tworegions of different kinetics.The whole corroded layer consisted of loose and porous mixture oxides of TiO2,Nb2O5and Al2O3.Numerous small nodules of corrosion product were observed.An illustrative schematic was established to describe the formationprocess of such nodules.It seemed that the refractory oxides played a significantly important role in determining the development ofhot corrosion attack. 展开更多
关键词 modified Ti3Al-based intermetallics hot corrosion corrosion product nodule Na2SO4 melt
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