Exploring the vertical variation in volatile organic compounds(VOCs)in background regions can provide infor-mation on the spatial distribution of pollutants,providing a scientific basis for atmospheric pollution preve...Exploring the vertical variation in volatile organic compounds(VOCs)in background regions can provide infor-mation on the spatial distribution of pollutants,providing a scientific basis for atmospheric pollution prevention and control strategies.From 15 August to 5 September 2023,at the Southeast Tibet Mountain Comprehensive Environmental Observation Station(SETS),a tethered balloon was used to sample VOCs every 100 m from the ground to 1000 m.A total of 403 air bag samples were collected,and 39 vertical profiles of VOCs were obtained.Ninety-two VOC species were detected.The VOC concentration at the SETS did not change significantly verti-cally,and the average VOC concentration was 11.1±2.4 ppbv.The main components were alkanes(51.4%),alkenes(18.7%),and halohydrocarbons(18.1%).There was no obvious diurnal change in VOCs and no signif-icant difference between the different layers.When the surface VOC concentration was less than 10 ppbv,the concentrations,components,and sources of VOCs were evenly distributed vertically,and the main sources of VOCs at different heights were vehicle exhaust and background.When the surface VOC concentration exceeded 10 ppbv,the VOC concentration gradually decreased with height.The proportion of alkanes in surface VOCs in-creased,and the source was mainly vehicle exhaust.This study confirmed that VOCs are vertically homogeneous in the background of the Tibetan Plateau,emphasizing the importance of vehicle emissions as a potential source of VOCs.展开更多
Background,aim,and scope Soil saturated hydraulic conductivity(K_(s))is a key parameter in the hydrological cycle of soil;however,we have very limited understanding of K_(s) characteristics and the factors that inf lu...Background,aim,and scope Soil saturated hydraulic conductivity(K_(s))is a key parameter in the hydrological cycle of soil;however,we have very limited understanding of K_(s) characteristics and the factors that inf luence this key parameter in the Mu Us sandy land(MUSL).Quantifying the impact of changes in land use in the Mu Us sandy land on K_(s) will provide a key foundation for understanding the regional water cycle,but will also provide a scientific basis for the governance of the MUSL.Materials and methods In this study,we determined K_(s) and the basic physical and chemical properties of soil(i.e.,organic matter,bulk density,and soil particle composition)within the first 100 cm layer of four different land use patterns(farmland,tree,shrub,and grassland)in the MUSL.The vertical variation of K_(s) and the factors that influence this key parameter were analyzed and a transfer function for estimating K_(s) was established based on a multiple stepwise regression model.Results The K_(s) of farmland,tree,and shrub increased gradually with soil depth while that of grassland remained unchanged.The K_(s) of the four patterns of land use were moderately variable;mean K_(s)values were ranked as follows:grassland(1.38 mm·min^(-1))<tree(1.76 mm·min^(-1))<farmland(1.82 mm·min^(-1))<shrub(3.30 mm·min^(-1)).The correlation between K_(s) and organic matter,bulk density,and soil particle composition,varied across different land use patterns.A multiple stepwise regression model showed that silt,coarse sand,bulk density,and organic matter,were key predictive factors for the K_(s) of farmland,tree,shrub,and grassland,in the MUSL.Discussion The vertical distribution trend for K_(s) in farmland is known to be predominantly influenced by cultivation,fertilization,and other factors.The general aim is to improve the water-holding capacity of shallow soil on farmland(0-30 cm in depth)to conserve water and nutrients;research has shown that the K_(s) of farmland increases with soil depth.The root growth of tree and shrub in sandy land exerts mechanical force on the soil due to biophysical processes involving rhizospheres,thus leading to a significant change in K_(s).We found that shallow high-density fine roots increased the volume of soil pores and eliminated large pores,thus resulting in a reduction in shallow K_(s).Therefore,the K_(s) of tree and shrub increased with soil depth.Analysis also showed that the K_(s) of grassland did not change significantly and exhibited the lowest mean value when compared to other land use patterns.This finding was predominantly due to the shallow root system of grasslands and because this land use pattern is not subject to human activities such as cultivation and fertilization;consequently,there was no significant change in K_(s) with depth;grassland also had the lowest mean K_(s).We also established a transfer function for K_(s) for different land use patterns in the MUSL.However,the predictive factors for K_(s) in different land use patterns are known to be affected by soil cultivation methods,vegetation restoration modes,the distribution of soil moisture,and other factors,thus resulting in key differences.Therefore,when using the transfer function to predict K_(s) in other areas,it will be necessary to perform parameter calibration and further verification.Conclusions In the MUSL,the K_(s) of farmland,tree,and shrub gradually increased with soil depth;however,the K_(s) of grassland showed no significant variation in terms of vertical distribution.The mean K_(s) values of different land use patterns were ranked as follows:shrub>farmland>tree>grassland;all land use patterns showed moderate levels of variability.The K_(s) for different land use patterns exhibited differing degrees of correlation with soil physical and chemical properties;of these,clay,silt,sand,bulk density,and organic matter,were identified as important variables for predicting K_(s) in farmland,tree,shrub,and grassland,respectively.Recommendations and perspectives In this study,we used a stepwise multiple regression model to establish a transfer function prediction model for K_(s) for different land use patterns;this model possessed high estimation accuracy.The ability to predict K_(s) in the MUSL is very important in terms of the conservation of water and nutrients.展开更多
One new species Bryophaenocladius alpinus Deng&Zhang sp.nov.is described and illustrated based on adult males collected from China.The adult males can be distinguished by the third palpomere with a digitiform proj...One new species Bryophaenocladius alpinus Deng&Zhang sp.nov.is described and illustrated based on adult males collected from China.The adult males can be distinguished by the third palpomere with a digitiform projection but without sensilla clavata,anal point broad triangular,inferior volsella sub-rectangular-shaped and covered with setae,gonostylus broad triangular,and crista dorsalis welldeveloped.展开更多
The seasonal and interannual variations of the vertical distribution of the Kuroshio velocity and its formative mechanism were studied by analyzing the Global Ocean Reanalysis Simulation 2 （GLORYS2） dataset in the P...The seasonal and interannual variations of the vertical distribution of the Kuroshio velocity and its formative mechanism were studied by analyzing the Global Ocean Reanalysis Simulation 2 （GLORYS2） dataset in the Pollution Nagasaki （PN） section （126.0°E-128.2°, at depths less than 1000 m）. The results indicated that： 1） the maximum transport in the PN section occurs in summer, followed by spring, and the minimum transport occurs in fall and winter; the maximum velocities are located at the subsurface in both winter and summer and velocities are relatively larger and at a shallower depth in summer; and the velocity core is located at the surface in spring and fall. The isopycnic line has a clear depression around the Kuroshio axis in winter. The depth of maximum velocity and the zero horizontal density gradients both exhibit substantial seasonal and interannual variations, and the interannual variations are larger. 2） The distributions of velocity and density are in accordance with the therma~ wind relation. Although Kuroshio transport is determined by the large-scale wind field and mesoscale motion in the Pacific Ocean; local heat flux and thermohaline circulation influence the density field, modify the vertical structure of the Kuroshio velocity, and adjust the allocation of water fluxes and nutrients transport. 3） Shelf-water offshore transport into the Kuroshio upper layer induced by southwest monsoons might contribute to the maximum velocity up to the surface in summer. Nonlinear and nongeostrophic processes are not considered in the present study, and the thermal wind relation accounts for part of the vertical structure of the Kuroshio velocity.展开更多
Aim Researching the optimal thieshold of image segmentation. M^ethods An adaptiveimages segmentation method based on the entropy of histogram of gray-level picture and genetic. algorithm (GA) was presental. Results ...Aim Researching the optimal thieshold of image segmentation. M^ethods An adaptiveimages segmentation method based on the entropy of histogram of gray-level picture and genetic. algorithm (GA) was presental. Results In our approach, the segmentation problem was formulated as an optimization problem and the fitness of GA which can efficiently search the segmentation parameter space was regarded as the quality criterion. Conclusion The methodcan be adapted for optimal behold segmentation.展开更多
We previously functionally characterized a novel marine microbial GDSL lipase MT6 and identified that the stereo-selectivity of MT6 was opposite to that of other common lipases in trans-esterification reactions.Herein...We previously functionally characterized a novel marine microbial GDSL lipase MT6 and identified that the stereo-selectivity of MT6 was opposite to that of other common lipases in trans-esterification reactions.Herein,we have investigated the use of MT6 in stereo-selective biocatalysis through direct hydrolysis reactions.Notably,the stereo-selectivity of MT6 was also demonstrated to be opposite to that of other common lipases in hydrolysis reactions.Parameters,including temperature,organic co-solvents,pH,ionic strength,catalyst loading,substrate concentration,and reaction time,affecting the enzymatic resolution of racemic 1-phenylethyl acetate were further investigated,with the e.e.of the final（S）-l-Phenylethanol product and the conversion being 97%and 28.5%,respectively,after process optimization.The lengths of side chains of 1-phenylethyl esters greatly affected the stereo-selectivity and conversion during kinetic resolutions.MT6 is a novel marine microbial GDSL lipase exhibiting opposite stereo-selectivities than other common lipases in both trans-esterification reactions and hydrolysis reactions.展开更多
基金supported by the second Tibetan Plateau Scientific Expedition and Research Program[No.2019QZKK0604]the National Natural Science Foundation of China[Nos.42177081 and 42171450]the Youth Cross Team Scientific Research Project of the Chinese Academy of Sciences[No.JCTD-2021–10]。
文摘Exploring the vertical variation in volatile organic compounds(VOCs)in background regions can provide infor-mation on the spatial distribution of pollutants,providing a scientific basis for atmospheric pollution prevention and control strategies.From 15 August to 5 September 2023,at the Southeast Tibet Mountain Comprehensive Environmental Observation Station(SETS),a tethered balloon was used to sample VOCs every 100 m from the ground to 1000 m.A total of 403 air bag samples were collected,and 39 vertical profiles of VOCs were obtained.Ninety-two VOC species were detected.The VOC concentration at the SETS did not change significantly verti-cally,and the average VOC concentration was 11.1±2.4 ppbv.The main components were alkanes(51.4%),alkenes(18.7%),and halohydrocarbons(18.1%).There was no obvious diurnal change in VOCs and no signif-icant difference between the different layers.When the surface VOC concentration was less than 10 ppbv,the concentrations,components,and sources of VOCs were evenly distributed vertically,and the main sources of VOCs at different heights were vehicle exhaust and background.When the surface VOC concentration exceeded 10 ppbv,the VOC concentration gradually decreased with height.The proportion of alkanes in surface VOCs in-creased,and the source was mainly vehicle exhaust.This study confirmed that VOCs are vertically homogeneous in the background of the Tibetan Plateau,emphasizing the importance of vehicle emissions as a potential source of VOCs.
文摘Background,aim,and scope Soil saturated hydraulic conductivity(K_(s))is a key parameter in the hydrological cycle of soil;however,we have very limited understanding of K_(s) characteristics and the factors that inf luence this key parameter in the Mu Us sandy land(MUSL).Quantifying the impact of changes in land use in the Mu Us sandy land on K_(s) will provide a key foundation for understanding the regional water cycle,but will also provide a scientific basis for the governance of the MUSL.Materials and methods In this study,we determined K_(s) and the basic physical and chemical properties of soil(i.e.,organic matter,bulk density,and soil particle composition)within the first 100 cm layer of four different land use patterns(farmland,tree,shrub,and grassland)in the MUSL.The vertical variation of K_(s) and the factors that influence this key parameter were analyzed and a transfer function for estimating K_(s) was established based on a multiple stepwise regression model.Results The K_(s) of farmland,tree,and shrub increased gradually with soil depth while that of grassland remained unchanged.The K_(s) of the four patterns of land use were moderately variable;mean K_(s)values were ranked as follows:grassland(1.38 mm·min^(-1))<tree(1.76 mm·min^(-1))<farmland(1.82 mm·min^(-1))<shrub(3.30 mm·min^(-1)).The correlation between K_(s) and organic matter,bulk density,and soil particle composition,varied across different land use patterns.A multiple stepwise regression model showed that silt,coarse sand,bulk density,and organic matter,were key predictive factors for the K_(s) of farmland,tree,shrub,and grassland,in the MUSL.Discussion The vertical distribution trend for K_(s) in farmland is known to be predominantly influenced by cultivation,fertilization,and other factors.The general aim is to improve the water-holding capacity of shallow soil on farmland(0-30 cm in depth)to conserve water and nutrients;research has shown that the K_(s) of farmland increases with soil depth.The root growth of tree and shrub in sandy land exerts mechanical force on the soil due to biophysical processes involving rhizospheres,thus leading to a significant change in K_(s).We found that shallow high-density fine roots increased the volume of soil pores and eliminated large pores,thus resulting in a reduction in shallow K_(s).Therefore,the K_(s) of tree and shrub increased with soil depth.Analysis also showed that the K_(s) of grassland did not change significantly and exhibited the lowest mean value when compared to other land use patterns.This finding was predominantly due to the shallow root system of grasslands and because this land use pattern is not subject to human activities such as cultivation and fertilization;consequently,there was no significant change in K_(s) with depth;grassland also had the lowest mean K_(s).We also established a transfer function for K_(s) for different land use patterns in the MUSL.However,the predictive factors for K_(s) in different land use patterns are known to be affected by soil cultivation methods,vegetation restoration modes,the distribution of soil moisture,and other factors,thus resulting in key differences.Therefore,when using the transfer function to predict K_(s) in other areas,it will be necessary to perform parameter calibration and further verification.Conclusions In the MUSL,the K_(s) of farmland,tree,and shrub gradually increased with soil depth;however,the K_(s) of grassland showed no significant variation in terms of vertical distribution.The mean K_(s) values of different land use patterns were ranked as follows:shrub>farmland>tree>grassland;all land use patterns showed moderate levels of variability.The K_(s) for different land use patterns exhibited differing degrees of correlation with soil physical and chemical properties;of these,clay,silt,sand,bulk density,and organic matter,were identified as important variables for predicting K_(s) in farmland,tree,shrub,and grassland,respectively.Recommendations and perspectives In this study,we used a stepwise multiple regression model to establish a transfer function prediction model for K_(s) for different land use patterns;this model possessed high estimation accuracy.The ability to predict K_(s) in the MUSL is very important in terms of the conservation of water and nutrients.
基金the financial support from Science and Technology Commission of Shanghai Municipality(1905050190019DZ1204504)。
文摘One new species Bryophaenocladius alpinus Deng&Zhang sp.nov.is described and illustrated based on adult males collected from China.The adult males can be distinguished by the third palpomere with a digitiform projection but without sensilla clavata,anal point broad triangular,inferior volsella sub-rectangular-shaped and covered with setae,gonostylus broad triangular,and crista dorsalis welldeveloped.
文摘The seasonal and interannual variations of the vertical distribution of the Kuroshio velocity and its formative mechanism were studied by analyzing the Global Ocean Reanalysis Simulation 2 （GLORYS2） dataset in the Pollution Nagasaki （PN） section （126.0°E-128.2°, at depths less than 1000 m）. The results indicated that： 1） the maximum transport in the PN section occurs in summer, followed by spring, and the minimum transport occurs in fall and winter; the maximum velocities are located at the subsurface in both winter and summer and velocities are relatively larger and at a shallower depth in summer; and the velocity core is located at the surface in spring and fall. The isopycnic line has a clear depression around the Kuroshio axis in winter. The depth of maximum velocity and the zero horizontal density gradients both exhibit substantial seasonal and interannual variations, and the interannual variations are larger. 2） The distributions of velocity and density are in accordance with the therma~ wind relation. Although Kuroshio transport is determined by the large-scale wind field and mesoscale motion in the Pacific Ocean; local heat flux and thermohaline circulation influence the density field, modify the vertical structure of the Kuroshio velocity, and adjust the allocation of water fluxes and nutrients transport. 3） Shelf-water offshore transport into the Kuroshio upper layer induced by southwest monsoons might contribute to the maximum velocity up to the surface in summer. Nonlinear and nongeostrophic processes are not considered in the present study, and the thermal wind relation accounts for part of the vertical structure of the Kuroshio velocity.
文摘Aim Researching the optimal thieshold of image segmentation. M^ethods An adaptiveimages segmentation method based on the entropy of histogram of gray-level picture and genetic. algorithm (GA) was presental. Results In our approach, the segmentation problem was formulated as an optimization problem and the fitness of GA which can efficiently search the segmentation parameter space was regarded as the quality criterion. Conclusion The methodcan be adapted for optimal behold segmentation.
基金supported by the Strategic Priority Research Program of Chinese Academy of Sciences(XDA11030404),the Key Project from Chinese Academy of Sciences(KGZD-EW-606)the National Natural Science Foundation of China(21302199)Guangzhou Science and Technology Plan Projects(201510010012)
文摘We previously functionally characterized a novel marine microbial GDSL lipase MT6 and identified that the stereo-selectivity of MT6 was opposite to that of other common lipases in trans-esterification reactions.Herein,we have investigated the use of MT6 in stereo-selective biocatalysis through direct hydrolysis reactions.Notably,the stereo-selectivity of MT6 was also demonstrated to be opposite to that of other common lipases in hydrolysis reactions.Parameters,including temperature,organic co-solvents,pH,ionic strength,catalyst loading,substrate concentration,and reaction time,affecting the enzymatic resolution of racemic 1-phenylethyl acetate were further investigated,with the e.e.of the final（S）-l-Phenylethanol product and the conversion being 97%and 28.5%,respectively,after process optimization.The lengths of side chains of 1-phenylethyl esters greatly affected the stereo-selectivity and conversion during kinetic resolutions.MT6 is a novel marine microbial GDSL lipase exhibiting opposite stereo-selectivities than other common lipases in both trans-esterification reactions and hydrolysis reactions.
