The Mg-Sn alloys,with basal or prismatic Mg_(2)Sn laths,were employed to reveal the effect of precipitate orientation on twinning behavior quantitatively.The Mg-5wt.%Sn alloys with basal or prismatic Mg_(2)Sn were com...The Mg-Sn alloys,with basal or prismatic Mg_(2)Sn laths,were employed to reveal the effect of precipitate orientation on twinning behavior quantitatively.The Mg-5wt.%Sn alloys with basal or prismatic Mg_(2)Sn were compressed to study the twinning behaviors.Subsequently,an Orowan strengthening model was developed to quantitatively investigate the critical resolved shear stress(CRSS)increment of precipitates on twinning.The results revealed that the prismatic precipitates hindered the transfer and growth of tensile twins more effectively compared with the basal precipitates.The decreased proportion of tensile twins containing prismatic Mg_(2)Sn might be attributed to a larger CRSS increment for tensile twins compared with that for basal precipitates.The obvious decreased twinning transfer in the alloy with prismatic Mg_(2)Sn could be due to its higher geometrically necessary dislocation and enhanced CRSS of tensile twins.Notably,the prismatic precipitates have a better hindering effect on tensile twins during compression.展开更多
Butt welding of 0.2 mm-thick TiNi shape memory alloy sheet (SMA) was carried out using impulse laser, and tensile strength, fracture morphology, microstructure and phase change behaviour of welded joint were studied...Butt welding of 0.2 mm-thick TiNi shape memory alloy sheet (SMA) was carried out using impulse laser, and tensile strength, fracture morphology, microstructure and phase change behaviour of welded joint were studied. The results show that using impulse laser can realize good butt welding of TiNi SMA sheet, tensile strength of welded joint is 683 MPa, which achieves 97% of that of cold rolled base metal, and the fracture mode of welded joint is ductile type as well as base metal. The welded joint can be divided into four zones according to grain size and microstructure. The microstructures of welded seam center zone are fine equiaxed crystals and the microstructures of both lower surface and upper surface edge zones are columnar crystals. When welded joint is vacuum annealed after welding, the phase transformation process is basically similar to the annealed base metal.展开更多
Porous TiNiCu ternary shape memory alloys (SMAs) were successfully fabricated by powder metallurgy method. The microstructure, martensitic transformation behavior, damping performance and mechanical properties of th...Porous TiNiCu ternary shape memory alloys (SMAs) were successfully fabricated by powder metallurgy method. The microstructure, martensitic transformation behavior, damping performance and mechanical properties of the fabricated alloys were intensively studied. It is found that the apparent density of alloys decreases with increasing the Cu content, the porous Ti50Ni40Cu10 alloy exhibits wide endothermic and exothermic peaks arisen from the hysteresis of martensitic transformations, while the porous Ti50Ni30Cu20 alloy shows much stronger and narrower endothermic and exothermic peaks owing to the B2-B19 transformation taking place easily. Moreover, the porous Ti50Ni40Cu10 alloy shows a lower shape recovery rate than the porous Ti50Ni50 alloy, while the porous Ti50Ni30Cu20 alloy behaves reversely. In addition, the damping capacity (or internal friction, IF) of the porous TiNiCu alloys increases with increasing the Cu content. The porous Ti50Ni30Cu20 alloy has very high equivalent internal friction, with the maximum equivalent internal friction value five times higher than that of the porous Ti50Ni50 alloy.展开更多
Experimental investigation and theoretical analysis of the microstructure of thixomolded AZ91D were carried out to comprehensively understand the morphology transformation of solid particles and the solidification beh...Experimental investigation and theoretical analysis of the microstructure of thixomolded AZ91D were carried out to comprehensively understand the morphology transformation of solid particles and the solidification behavior. Typical microstructure of thixomolded AZ91D is composed of a-Mg and β-Mg17Al12, characterized with aun, aprim and eutectic. Four kinds of aun are classified according to the morphology and generation mechanism, such as spherical (al), irregular (a2), entrapping liquid alloy inside (a3) and entrapping pool inside (a4). Under the effect of heating, shearing, collision, agglomeration or fragmentation, a2 and a4 can be the middle states ofal and a3. Similarly, a4 and a3 can also break into a2 and become al at the end. Controlled by undercooling, aprim nucleates and spherically grows within the remaining liquid alloy of thixomolded AZ91D until instability growth. The investigated microstructure was theoretically proved according to the analysis of Mg-Al binary phase diagram.展开更多
Based on a large number of relevant literatures, the effects of environmental factors and human factors on forest soil nutrients in nature reserve were summarized, as well as the soil quality assessment and correlatio...Based on a large number of relevant literatures, the effects of environmental factors and human factors on forest soil nutrients in nature reserve were summarized, as well as the soil quality assessment and correlation of soil. nutrients, to provide references for a deep research on forest nature reserve soil and its protection. The distribution of forest soil nutrients has significant spatial heterogeneity, and its final distribution pattern is the result of joint action of environmental factors, including topography, vegetation, soil type, seasonal change as well as soil microorganism, and human factors. In natural ecosystem, environmental factors are the main factors that determine the differences of soil nutrients. Effective human management can promote the accumulation of forest soil nutrients, but improper interference will cause a significant loss of soil nutrients. Accurate soil quality evaluation can objectively clarify the impact of different soil management practices on soil, contributing to the timely adjustment of management measures. The establishment of long-term soil monitoring stations in forest nature reserves is a good way to master the influencing factors and the mechanism of forest soil nutrients, and can ultimately provide theoretical guidance for a sustainable and healthy operation of forest nature reserve.展开更多
Using an optical microscope and scanning electron microscope (SEM), the variation of eutectic Si morphology of Al-Si alloy in solution treatment was observed to study its influence on mechanical properties and fractur...Using an optical microscope and scanning electron microscope (SEM), the variation of eutectic Si morphology of Al-Si alloy in solution treatment was observed to study its influence on mechanical properties and fracture behavior. The results show that eutectic Si undergoes stubbing, necking, fragmentation, and growth in the initial stage (250 min); in the middle solution stage (250 to 400 min), the eutectic Si morphology has no significant change, only the degree of spheroidizing becomes higher; after 600 min, the growth of eutectic Si is a coarsening process controlled by diffusion and follows the Liftshitz-Slyozov-Wangner (LSW) model, and the eutectic Si morphology deteriorates due to the occurrence of facets and lap. Based on the quantitative measure and regression analysis, the eutectic Si morphology has a remarkable influence on mechanical properties and fracture behavior.展开更多
WC-6MoxC-0.47Cr3C2-0.28VC binderless carbide was prepared by hot pressing (1700 °C, 20 MPa). The sample was observed and analyzed by scanning electron microscopy, energy dispersive X–ray spectroscopy and X–ra...WC-6MoxC-0.47Cr3C2-0.28VC binderless carbide was prepared by hot pressing (1700 °C, 20 MPa). The sample was observed and analyzed by scanning electron microscopy, energy dispersive X–ray spectroscopy and X–ray diffraction. The results show that during the hot pressing process, W atoms dissolve substantially into the MoxC crystal lattices; whilst, the reverse dissolution of Mo atoms into the WC crystal lattices takes place. Consequently, the main phase and binder phase structure are formed. The phase compositions of the main phase and binder phase are a WC-based solid solution containing Mo and a Mo2C-based solid solution containing W, respectively. The isotropic dissolution and precipitation of W and Mo atoms do not result in substantial carbide coarsening. The mechanism for the densification was discussed.展开更多
The grey quasi-preferred analysis (GQPA) is one of important methods for realizing system analysis to conquer the limitations of the existing GQPA model, without any considerations to the difference of the different b...The grey quasi-preferred analysis (GQPA) is one of important methods for realizing system analysis to conquer the limitations of the existing GQPA model, without any considerations to the difference of the different behavioral factor′s importance. It could not be used to analyze the complex system with multi-hierarchy correlation factors, the weighted synthetic method for calculating abstract incidence degrees between the system beha-vioral characteristics and correlative factors in different hierarchies is given out,and the hierarchic grey quasi-preferred analysis (HGQPA) model is established. The effectiveness of the HGQPA model is tested by the scientific-technical system of Jiangsu Province. The depth and the range of the application of GQPA are developed, and the HGQPA model is regarded as a new approach to systemically analyze the complex systems with multi-hierarchy correlation factors.展开更多
The effects of copper on the ageing precipitation behavior of as-quenched and pre-aged AA6016 aluminum alloy were studied by differential scanning calorimetry (DSC), Vickers hardness measurement and transmission ele...The effects of copper on the ageing precipitation behavior of as-quenched and pre-aged AA6016 aluminum alloy were studied by differential scanning calorimetry (DSC), Vickers hardness measurement and transmission electronic microscopy (TEM). The results indicate that the addition of copper facilitates the growth of clusters (GP I) to the critical size during pre-ageing. Therefore, the addition of copper accelerates the transition from GP I (pre-β") to GP II (β") during final artificial ageing, and finally results in the favorable paint-bake response. However, the one with the copper level of 0.3% does not show significant baking hardening response as expected. Pre-aging can also reduce the detrimental effect due to natural aging of copper-containing alloys.展开更多
Distribution of TX114 between coacervate and aqueous phases in clouding of various initial TX114 concentrations was studied. Effects of temperature and salinity (Na2SO4) on the distribution of TX114 concentration we...Distribution of TX114 between coacervate and aqueous phases in clouding of various initial TX114 concentrations was studied. Effects of temperature and salinity (Na2SO4) on the distribution of TX114 concentration were also investigated. Differing from the nonionic surfactant C12E10, the distribution of TX114 is sensitive to the temperature, and it is observed that the TX114 concentration in the aqueous phase (Caq) does not depend on the initial TX114 concentration apparently at 45℃, and the Caq decreases with an increase of NazSO4 concentration. Low initial TX114 concentration in unclouded solutions, high Na2SO4 concentration, and temperature are suggested to control the surfactant loss in large-scale cloud point extraction applications.展开更多
Phase separation was studied by the optical microscopy in blends of nylon 6 (PA6) with sodium salt of ethylene/methacrylic acid copolymer (PEMA).The image collecting technology was used to keep track of the developme...Phase separation was studied by the optical microscopy in blends of nylon 6 (PA6) with sodium salt of ethylene/methacrylic acid copolymer (PEMA).The image collecting technology was used to keep track of the development of blends at a certain temperature.The fractal dimension of phase separation was calculated by the image solving technology according to the fractal theory and the self similarity behavior of the process was proved.The relationship of the fractal behavior with composition and experimental temperature was discussed.The fractal behavior of the crystallization development of the crystal phase of PA6 in blends was also discussed and the fractal behavior calculated.展开更多
The investigation on bubble behavior in electric field helps to analyze the mechanism of electric enhancement of boiling heat transfer. Experiments were performed to investigate the bubble deformation in direct curre...The investigation on bubble behavior in electric field helps to analyze the mechanism of electric enhancement of boiling heat transfer. Experiments were performed to investigate the bubble deformation in direct current (DC) electric field with bubbles attached to the orifice. The air bubbles were slowly generated in the transformer oil pool at different orifices, so that the effect of flow on bubble shape was eliminated. The results showed that the bubbles were elongated and the departure volume decreased when the electric field was intensified. The major and minor axes, aspect ratio and departure volume increased with increasing the orifice diameter. Both the electric field and orifice size have great influence on bubble behavior. The bubble deformation was also simulated to compare with the experimental results. The numerical and experimental data qualitatively agree with each other.展开更多
Experiments were carried out to investigate the influences of cation from electrolytes and acidity/alkalinity on the phase behavior of sodium dodecyl sulfate-n-butanol-organics-water (with electrolytes) microemulsio...Experiments were carried out to investigate the influences of cation from electrolytes and acidity/alkalinity on the phase behavior of sodium dodecyl sulfate-n-butanol-organics-water (with electrolytes) microemulsion sys-tem. The organics used is commercial kerosene. The volume ratio of water to organics is 1︰1. The results show that the type and valence of electrolyte cations are important factors influencing the microemulsion behavior. Biva-lent Ca2+is more effective than monovalent K+and Na+for the formation of Winsor type III and II microemulsion. For electrolytes with the same monovalent cation Na+, i.e. NaCl and Na2CO3, anions in the electrolyte have some effect. Bivalent anion 23CO - leads to a lower activity of cation Na+than monovalent anion Cl-. NaOH (or KOH) behaves similar with NaCl (or KCl). When HCl is used as electrolyte, its acidity plays an important role. Phase in-version of microemulsion from type III (or II) to type I is observed through precipitation of Ca2+using Na2CO3, neutralization of HCl by NaOH, and addition of water to the system, which releases the oil from the microemulsion.展开更多
The thorough-thickness inhomogeneity of precipitate distribution and pitting corrosion behavior of 95 mm-thick 2297 Al-Li alloy rolled plate was investigated using scanning electron microscopy, transmission electron m...The thorough-thickness inhomogeneity of precipitate distribution and pitting corrosion behavior of 95 mm-thick 2297 Al-Li alloy rolled plate was investigated using scanning electron microscopy, transmission electron microscopy and electrochemistry method. Precipitate distribution and pit size were statistically analyzed to obtain quantitative information and corresponding correlation. The population density and the size fraction of precipitate on different sections in the thick plate are ranked from high to low in the following order: quarter-section(QS) > surface section(SS) > mid-section(MS). After 300 min potentiostatic polarization, the number and the total volume of pits are ranked from high to low as QS>SS>MS, indicating a higher pitting susceptibility of the plate in QS with more precipitates. The through-thickness inhomogeneity of pitting corrosion in 2297 Al-Li alloy thick plate is mainly ascribed to inhomogeneous precipitate distribution.展开更多
基金National Natural Science Foundation of China(Nos.52004227,U22A20187,52201106)the China Postdoctoral Science Foundation(No.2020M683240)+1 种基金the Key Area Research and Development Program of Guangdong ProvinceChina(No.2020B090924002)。
文摘The Mg-Sn alloys,with basal or prismatic Mg_(2)Sn laths,were employed to reveal the effect of precipitate orientation on twinning behavior quantitatively.The Mg-5wt.%Sn alloys with basal or prismatic Mg_(2)Sn were compressed to study the twinning behaviors.Subsequently,an Orowan strengthening model was developed to quantitatively investigate the critical resolved shear stress(CRSS)increment of precipitates on twinning.The results revealed that the prismatic precipitates hindered the transfer and growth of tensile twins more effectively compared with the basal precipitates.The decreased proportion of tensile twins containing prismatic Mg_(2)Sn might be attributed to a larger CRSS increment for tensile twins compared with that for basal precipitates.The obvious decreased twinning transfer in the alloy with prismatic Mg_(2)Sn could be due to its higher geometrically necessary dislocation and enhanced CRSS of tensile twins.Notably,the prismatic precipitates have a better hindering effect on tensile twins during compression.
基金Project(200804)supported by State Key Laboratory of Advanced Welding and Joining,Harbin Institute of Technology,China
文摘Butt welding of 0.2 mm-thick TiNi shape memory alloy sheet (SMA) was carried out using impulse laser, and tensile strength, fracture morphology, microstructure and phase change behaviour of welded joint were studied. The results show that using impulse laser can realize good butt welding of TiNi SMA sheet, tensile strength of welded joint is 683 MPa, which achieves 97% of that of cold rolled base metal, and the fracture mode of welded joint is ductile type as well as base metal. The welded joint can be divided into four zones according to grain size and microstructure. The microstructures of welded seam center zone are fine equiaxed crystals and the microstructures of both lower surface and upper surface edge zones are columnar crystals. When welded joint is vacuum annealed after welding, the phase transformation process is basically similar to the annealed base metal.
基金Projects(50871039,51205135)supported by the National Natural Science Foundation of ChinaProject(S2011040001436)supported by the Guangdong Provincial Natural Science Foundation,China
文摘Porous TiNiCu ternary shape memory alloys (SMAs) were successfully fabricated by powder metallurgy method. The microstructure, martensitic transformation behavior, damping performance and mechanical properties of the fabricated alloys were intensively studied. It is found that the apparent density of alloys decreases with increasing the Cu content, the porous Ti50Ni40Cu10 alloy exhibits wide endothermic and exothermic peaks arisen from the hysteresis of martensitic transformations, while the porous Ti50Ni30Cu20 alloy shows much stronger and narrower endothermic and exothermic peaks owing to the B2-B19 transformation taking place easily. Moreover, the porous Ti50Ni40Cu10 alloy shows a lower shape recovery rate than the porous Ti50Ni50 alloy, while the porous Ti50Ni30Cu20 alloy behaves reversely. In addition, the damping capacity (or internal friction, IF) of the porous TiNiCu alloys increases with increasing the Cu content. The porous Ti50Ni30Cu20 alloy has very high equivalent internal friction, with the maximum equivalent internal friction value five times higher than that of the porous Ti50Ni50 alloy.
基金Projects (2006BA104B04-1 2006BAE04B07-3) supported by the National Science and Technology Supporting Program of China+1 种基金Project (2007KZ05) supported by the Science and Technology Supporting Project of Changchun City, ChinaProject supported by the "985 Project" of Jilin University, China
文摘Experimental investigation and theoretical analysis of the microstructure of thixomolded AZ91D were carried out to comprehensively understand the morphology transformation of solid particles and the solidification behavior. Typical microstructure of thixomolded AZ91D is composed of a-Mg and β-Mg17Al12, characterized with aun, aprim and eutectic. Four kinds of aun are classified according to the morphology and generation mechanism, such as spherical (al), irregular (a2), entrapping liquid alloy inside (a3) and entrapping pool inside (a4). Under the effect of heating, shearing, collision, agglomeration or fragmentation, a2 and a4 can be the middle states ofal and a3. Similarly, a4 and a3 can also break into a2 and become al at the end. Controlled by undercooling, aprim nucleates and spherically grows within the remaining liquid alloy of thixomolded AZ91D until instability growth. The investigated microstructure was theoretically proved according to the analysis of Mg-Al binary phase diagram.
基金Supported by the Special Fund for Biodiversity Protection of the Ministry of Environmental Protection of the People’s Republic of China(214704)the Special Fund for the Fundamentak Works of the Ministry of Science and Technology(2008FY110304)~~
文摘Based on a large number of relevant literatures, the effects of environmental factors and human factors on forest soil nutrients in nature reserve were summarized, as well as the soil quality assessment and correlation of soil. nutrients, to provide references for a deep research on forest nature reserve soil and its protection. The distribution of forest soil nutrients has significant spatial heterogeneity, and its final distribution pattern is the result of joint action of environmental factors, including topography, vegetation, soil type, seasonal change as well as soil microorganism, and human factors. In natural ecosystem, environmental factors are the main factors that determine the differences of soil nutrients. Effective human management can promote the accumulation of forest soil nutrients, but improper interference will cause a significant loss of soil nutrients. Accurate soil quality evaluation can objectively clarify the impact of different soil management practices on soil, contributing to the timely adjustment of management measures. The establishment of long-term soil monitoring stations in forest nature reserves is a good way to master the influencing factors and the mechanism of forest soil nutrients, and can ultimately provide theoretical guidance for a sustainable and healthy operation of forest nature reserve.
文摘Using an optical microscope and scanning electron microscope (SEM), the variation of eutectic Si morphology of Al-Si alloy in solution treatment was observed to study its influence on mechanical properties and fracture behavior. The results show that eutectic Si undergoes stubbing, necking, fragmentation, and growth in the initial stage (250 min); in the middle solution stage (250 to 400 min), the eutectic Si morphology has no significant change, only the degree of spheroidizing becomes higher; after 600 min, the growth of eutectic Si is a coarsening process controlled by diffusion and follows the Liftshitz-Slyozov-Wangner (LSW) model, and the eutectic Si morphology deteriorates due to the occurrence of facets and lap. Based on the quantitative measure and regression analysis, the eutectic Si morphology has a remarkable influence on mechanical properties and fracture behavior.
基金Project (51074189) supported by the National Natural Science Foundation of ChinaProject (20100162110001) supported by Research Fund for the Doctoral Program of Higher Education of ChinaProject (2011BAE09B02) supported by the National Key Technology R&D Program of China
文摘WC-6MoxC-0.47Cr3C2-0.28VC binderless carbide was prepared by hot pressing (1700 °C, 20 MPa). The sample was observed and analyzed by scanning electron microscopy, energy dispersive X–ray spectroscopy and X–ray diffraction. The results show that during the hot pressing process, W atoms dissolve substantially into the MoxC crystal lattices; whilst, the reverse dissolution of Mo atoms into the WC crystal lattices takes place. Consequently, the main phase and binder phase structure are formed. The phase compositions of the main phase and binder phase are a WC-based solid solution containing Mo and a Mo2C-based solid solution containing W, respectively. The isotropic dissolution and precipitation of W and Mo atoms do not result in substantial carbide coarsening. The mechanism for the densification was discussed.
文摘The grey quasi-preferred analysis (GQPA) is one of important methods for realizing system analysis to conquer the limitations of the existing GQPA model, without any considerations to the difference of the different behavioral factor′s importance. It could not be used to analyze the complex system with multi-hierarchy correlation factors, the weighted synthetic method for calculating abstract incidence degrees between the system beha-vioral characteristics and correlative factors in different hierarchies is given out,and the hierarchic grey quasi-preferred analysis (HGQPA) model is established. The effectiveness of the HGQPA model is tested by the scientific-technical system of Jiangsu Province. The depth and the range of the application of GQPA are developed, and the HGQPA model is regarded as a new approach to systemically analyze the complex systems with multi-hierarchy correlation factors.
基金Project(51105139)supported by the National Natural Science Foundation of ChinaProject(2010CB731706)supported by the National Basic Research Program of China
文摘The effects of copper on the ageing precipitation behavior of as-quenched and pre-aged AA6016 aluminum alloy were studied by differential scanning calorimetry (DSC), Vickers hardness measurement and transmission electronic microscopy (TEM). The results indicate that the addition of copper facilitates the growth of clusters (GP I) to the critical size during pre-ageing. Therefore, the addition of copper accelerates the transition from GP I (pre-β") to GP II (β") during final artificial ageing, and finally results in the favorable paint-bake response. However, the one with the copper level of 0.3% does not show significant baking hardening response as expected. Pre-aging can also reduce the detrimental effect due to natural aging of copper-containing alloys.
基金Supported by the National Natural Science Foundation of China (20676069).
文摘Distribution of TX114 between coacervate and aqueous phases in clouding of various initial TX114 concentrations was studied. Effects of temperature and salinity (Na2SO4) on the distribution of TX114 concentration were also investigated. Differing from the nonionic surfactant C12E10, the distribution of TX114 is sensitive to the temperature, and it is observed that the TX114 concentration in the aqueous phase (Caq) does not depend on the initial TX114 concentration apparently at 45℃, and the Caq decreases with an increase of NazSO4 concentration. Low initial TX114 concentration in unclouded solutions, high Na2SO4 concentration, and temperature are suggested to control the surfactant loss in large-scale cloud point extraction applications.
文摘Phase separation was studied by the optical microscopy in blends of nylon 6 (PA6) with sodium salt of ethylene/methacrylic acid copolymer (PEMA).The image collecting technology was used to keep track of the development of blends at a certain temperature.The fractal dimension of phase separation was calculated by the image solving technology according to the fractal theory and the self similarity behavior of the process was proved.The relationship of the fractal behavior with composition and experimental temperature was discussed.The fractal behavior of the crystallization development of the crystal phase of PA6 in blends was also discussed and the fractal behavior calculated.
基金the National Key Basic Research Program of China (G2000026301)Key Laboratory for Thermal Science and Power Engineering of Ministry of Education, Tsinghua University, China
文摘The investigation on bubble behavior in electric field helps to analyze the mechanism of electric enhancement of boiling heat transfer. Experiments were performed to investigate the bubble deformation in direct current (DC) electric field with bubbles attached to the orifice. The air bubbles were slowly generated in the transformer oil pool at different orifices, so that the effect of flow on bubble shape was eliminated. The results showed that the bubbles were elongated and the departure volume decreased when the electric field was intensified. The major and minor axes, aspect ratio and departure volume increased with increasing the orifice diameter. Both the electric field and orifice size have great influence on bubble behavior. The bubble deformation was also simulated to compare with the experimental results. The numerical and experimental data qualitatively agree with each other.
基金Supported by the National Natural Science Foundation of China(21106187)Promotive Research Funds for Excellent Young and Middle-aged Scientists of Shandong Province(BS2011NJ021)+1 种基金the Fundamental Research Funds for the Central Universities(11CX05016A)the Graduate Innovation Project of CUP 2012(CX-1214)
文摘Experiments were carried out to investigate the influences of cation from electrolytes and acidity/alkalinity on the phase behavior of sodium dodecyl sulfate-n-butanol-organics-water (with electrolytes) microemulsion sys-tem. The organics used is commercial kerosene. The volume ratio of water to organics is 1︰1. The results show that the type and valence of electrolyte cations are important factors influencing the microemulsion behavior. Biva-lent Ca2+is more effective than monovalent K+and Na+for the formation of Winsor type III and II microemulsion. For electrolytes with the same monovalent cation Na+, i.e. NaCl and Na2CO3, anions in the electrolyte have some effect. Bivalent anion 23CO - leads to a lower activity of cation Na+than monovalent anion Cl-. NaOH (or KOH) behaves similar with NaCl (or KCl). When HCl is used as electrolyte, its acidity plays an important role. Phase in-version of microemulsion from type III (or II) to type I is observed through precipitation of Ca2+using Na2CO3, neutralization of HCl by NaOH, and addition of water to the system, which releases the oil from the microemulsion.
基金Project(51671013)supported by the National Natural Science Foundation of ChinaProject(Z161100004916061)supported by the Beijing Nova Program,China
文摘The thorough-thickness inhomogeneity of precipitate distribution and pitting corrosion behavior of 95 mm-thick 2297 Al-Li alloy rolled plate was investigated using scanning electron microscopy, transmission electron microscopy and electrochemistry method. Precipitate distribution and pit size were statistically analyzed to obtain quantitative information and corresponding correlation. The population density and the size fraction of precipitate on different sections in the thick plate are ranked from high to low in the following order: quarter-section(QS) > surface section(SS) > mid-section(MS). After 300 min potentiostatic polarization, the number and the total volume of pits are ranked from high to low as QS>SS>MS, indicating a higher pitting susceptibility of the plate in QS with more precipitates. The through-thickness inhomogeneity of pitting corrosion in 2297 Al-Li alloy thick plate is mainly ascribed to inhomogeneous precipitate distribution.