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旅游产业集群网络结构及其空间相互作用研究——以杭州国际旅游综合体为例 被引量:15
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作者 卞显红 《人文地理》 CSSCI 北大核心 2012年第4期137-142,共6页
旅游产业集群的网络构成分为核心网络与外围支持网络。旅游产业集群网络由主体、旅游资源以及旅游活动三部分组成。论文把旅游产业集群网络结构分为原子式、单核式、多核式、混合式等4种形态。论文把旅游产业集群网络结构空间相互作用... 旅游产业集群的网络构成分为核心网络与外围支持网络。旅游产业集群网络由主体、旅游资源以及旅游活动三部分组成。论文把旅游产业集群网络结构分为原子式、单核式、多核式、混合式等4种形态。论文把旅游产业集群网络结构空间相互作用分为三个层次:第一层次是核心旅游企业之间及相关旅游企业之间的竞争与合作;二是旅游企业和研究机构、地方政府、旅游中介机构及旅游投资机构之间的空间作用;三是旅游产业集群内部主体,主要是旅游企业与旅游产业集群外部成员之间的交流与互动,并以杭州国际旅游综合体为例对这三个层次的空间相互作用进行了分析。 展开更多
关键词 旅游产业集群 网络结构 空间相互作 杭州国际旅游综合体
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粘流与无粘流的相互作用计算 被引量:3
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作者 朱自强 《空气动力学学报》 CSCD 北大核心 1989年第1期12-25,共14页
本文总结了粘流/无粘流的各种计算方法和结果。重点在于介绍定常流动中的弱相互作用。首先叙述了弱相互作用的数学模型。给出了不可压流动和跨音速流动中粘流/无粘流相互作用的某些正耦合的计算结果。讨论了在分离区附近边界层正方法失... 本文总结了粘流/无粘流的各种计算方法和结果。重点在于介绍定常流动中的弱相互作用。首先叙述了弱相互作用的数学模型。给出了不可压流动和跨音速流动中粘流/无粘流相互作用的某些正耦合的计算结果。讨论了在分离区附近边界层正方法失效的原因。然后介绍了边界层反方法和适用于带分离的流动中半反方法耦合的粘流/无粘流的相互作用方法。文中也简单地总结了三维情况的应用和强相互作用。 展开更多
关键词 粘流-无粘流 相互作 跨音速流动
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Research progress on the water vapor channel within the Yarlung Zsangbo Grand Canyon, China 被引量:1
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作者 Xuelong Chen Yajing Liu +9 位作者 Yaoming Ma Xiangde Xu Xin Xu Luhan Li Dianbin Cao Qiang Zhang Gaili Wang Maoshan Li Siqiong Luo Xin Wang 《Atmospheric and Oceanic Science Letters》 CSCD 2024年第5期10-15,共6页
The Second Tibetan Plateau Scientific Expedition and Research Program tasked a research team with the“Investigation of the water vapor channel of the Yarlung Zsangbo Grand Canyon(INVC)”in the southeastern Tibetan Pl... The Second Tibetan Plateau Scientific Expedition and Research Program tasked a research team with the“Investigation of the water vapor channel of the Yarlung Zsangbo Grand Canyon(INVC)”in the southeastern Tibetan Plateau(TP).This paper summarizes the scientific achievements obtained from the data collected by the INVC observation network and highlights the progress in investigating the development of heavy rainfall events associated with water vapor changes.The rain gauge network of the INVC can represent the impacts of the Yarlung Zsangbo Grand Canyon(YGC)topography on precipitation at the hourly scale.The microphysical characteristics of the precipitation in the YGC are different than those in the lowland area.The GPM-IMERG(Integrated MultisatellitE Retrievals for Global Precipitation Measurement)satellite precipitation data for the YGC region should be calibrated before they are used.The meridional water vapor flux through the YGC is more important than the zonal flux for the precipitation over the southeastern TP.The decreased precipitation around the YGC region is partly due to the decreased meridional water vapor flux passing through the YGC.High-resolution numerical models can benefit precipitation forecasting in this region by using a combination of specific schemes that capture the valley wind and water vapor flux along the valley floor. 展开更多
关键词 Water vapor channel Land-air interaction Mountian meteorology Extreme rainfall Observation network
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Advances in the studies of the supported ruthenium catalysts for CO_(2) methanation
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作者 Chenyang Shen Menghui Liu +2 位作者 Song He Haibo Zhao Chang-jun Liu 《Chinese Journal of Catalysis》 SCIE CAS CSCD 2024年第8期1-15,共15页
CO_(2) methanation has a potential in the large-scale utilization of carbon dioxide.It has also been considered to be useful for the renewable energy storage.The commercial pipeline for natural gas transportation can ... CO_(2) methanation has a potential in the large-scale utilization of carbon dioxide.It has also been considered to be useful for the renewable energy storage.The commercial pipeline for natural gas transportation can be directly applied for the methane product of CO_(2) methanation.The supported ruthenium(Ru)catalyst has been confirmed to be active and stable for CO_(2) methanation with its high ability in the dissociation of hydrogen and the strong binding of carbon monoxide.CO_(2) methanation over the supported Ru catalyst is structure sensitive.The size of the Ru catalyst and the support have significant effects on the activity and the mechanism.A significant challenge re-mained is the structural controllable preparation of the supported Ru catalyst toward a sufficiently high low-temperature activity.In this review,the recent progresses in the investigations of the supported Ru catalysts for CO_(2) methanation are summarized.The challenges and the future devel-opments are also discussed. 展开更多
关键词 RUTHENIUM Carbon dioxide METHANATION HYDROGENATION Catalyst and metal-support interaction
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Computational Simulation of Aptamer-target Binding Mechanisms
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作者 YANG Yuan-Yuan XU Fei WU Xiu-Xiu 《中国生物化学与分子生物学报》 CAS CSCD 北大核心 2024年第11期1550-1562,共13页
Aptamers are a type of single-chain oligonucleotide that can combine with a specific target.Due to their simple preparation,easy modification,stable structure and reusability,aptamers have been widely applied as bioch... Aptamers are a type of single-chain oligonucleotide that can combine with a specific target.Due to their simple preparation,easy modification,stable structure and reusability,aptamers have been widely applied as biochemical sensors for medicine,food safety and environmental monitoring.However,there is little research on aptamer-target binding mechanisms,which limits their application and development.Computational simulation has gained much attention for revealing aptamer-target binding mechanisms at the atomic level.This work summarizes the main simulation methods used in the mechanistic analysis of aptamer-target complexes,the characteristics of binding between aptamers and different targets(metal ions,small organic molecules,biomacromolecules,cells,bacteria and viruses),the types of aptamer-target interactions and the factors influencing their strength.It provides a reference for further use of simulations in understanding aptamer-target binding mechanisms. 展开更多
关键词 computational simulation APTAMER TARGET binding mechanism intermolecular forces
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Regulating crystal phase of TiO_(2) to enhance catalytic activity of Ni/TiO_(2) for solar-driven dry reforming of methane
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作者 HE Zhanjun GONG Kun +3 位作者 DAI Yuanyuan NIU Qiang LIN Tiejun ZHONG Liangshu 《燃料化学学报(中英文)》 EI CAS CSCD 北大核心 2024年第9期1203-1213,共11页
Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by... Ni/TiO_(2) catalyst is widely employed for photo-driven DRM reaction while the influence of crystal structure of TiO_(2) remains unclear.In this work,the rutile/anatase ratio in supports was successfully controlled by varying the calcination temperature of anatase-TiO_(2).Structural characterizations revealed that a distinct TiO_(x) coating on the Ni nanoparticles(NPs)was evident for Ni/TiO_(2)-700 catalyst due to strong metal-support interaction.It is observed that the TiOx overlayer gradually disappeared as the ratio of rutile/anatase increased,thereby enhancing the exposure of Ni active sites.The exposed Ni sites enhanced visible light absorption and boosted the dissociation capability of CH4,which led to the much elevated catalytic activity for Ni/TiO_(2)-950 in which rutile dominated.Therefore,the catalytic activity of solar-driven DRM reaction was significantly influenced by the rutile/anatase ratio.Ni/TiO_(2)-950,characterized by a predominant rutile phase,exhibited the highest DRM reactivity,with remarkable H_(2) and CO production rates reaching as high as 87.4 and 220.2 mmol/(g·h),respectively.These rates were approximately 257 and 130 times higher,respectively,compared to those obtained on Ni/TiO_(2)-700 with anatase.This study suggests that the optimization of crystal structure of TiO_(2) support can effectively enhance the performance of photothermal DRM reaction. 展开更多
关键词 dry reforming of methane photothermal catalysis crystal phase TiO_(2) metal-support interaction
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Effect of Apis mellifera on community composition of local pollinator bees and their pollination network in Qinling Mountains and surrounding areas
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作者 Cheng'en ZHONG Qingle XIE +1 位作者 Yaoyao SI Yalin ZHANG 《Entomotaxonomia》 CSCD 2024年第3期167-205,共39页
The Qinling Mountains, known for their rich vegetation and diverse pollinating insects, have seen a significant decline in bee species richness and abundance over recent decades, largely due to the introduction and sp... The Qinling Mountains, known for their rich vegetation and diverse pollinating insects, have seen a significant decline in bee species richness and abundance over recent decades, largely due to the introduction and spread of Apis mellifera. This decline has caused cascading effects on the region's community structure and ecosystem stability. To improve the protection of native bees in the natural and agricultural landscape of the Qinling Mountains and its surrounding areas, we investigated 33 sampling sites within three habitats: forest, forest-agriculture ecotones, and farmland. Using a generalized linear mixing model, t-test, and other data analysis methods, we explored the impact of Apis mellifera on local pollinator bee richness, abundance, and the pollination network in different habitats in these regional areas. The results show that(1)Apis mellifera significantly negatively affects the abundance and richness of wild pollinator bees,while Apis cerana abundance is also affected by beekeeping conditions.(2)There are significant negative effects of Apis mellifera on the community structure of pollinator bees in the Qinling Mountains and its surrounding areas: the Shannon-Wiener diversity index, Pielou evenness index, and Margalef richness index of bee communities at sites with Apis mellifera influence were significantly lower than those at sites without Apis mellifera influence.(3)The underlying driver of this effect is the monopolization of flowering resources by Apis mellifera. This species tends to visit flowering plants with large nectar sources, which constitute a significant portion of the local plant community. By maintaining a dominant role in the bee-plant pollination network, Apis mellifera competitively displaces native pollinator bees, reducing their access to floral resources. This ultimately leads to a reduction in local bee-plant interactions, decreasing the complexity and stability of the pollination network. These findings highlight the need for targeted conservation efforts to protect native pollinator species and maintain the ecological balance in the Qinling Mountains. 展开更多
关键词 Apis mellifera Pollinator bees Species richness ABUNDANCE Interaction networks
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Zonal Coupling Analysis Method of Seismic Response of Offshore Monopile Wind Turbine
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作者 XU Xiaofeng CHEN Shaolin SUN Jie 《Transactions of Nanjing University of Aeronautics and Astronautics》 EI CSCD 2024年第S01期103-110,共8页
The seismic safety of offshore wind turbines is an important issue that needs to be solved urgently.Based on a unified computing framework,this paper develops a set of seawater-seabed-wind turbine zoning coupling anal... The seismic safety of offshore wind turbines is an important issue that needs to be solved urgently.Based on a unified computing framework,this paper develops a set of seawater-seabed-wind turbine zoning coupling analysis methods.A 5 MW wind turbine and a site analysis model are established,and a seismic wave is selected to analyze the changes in the seismic response of offshore monopile wind turbines under the change of seawater depth,seabed wave velocity and seismic wave incidence angle.The analysis results show that when the seawater increases to a certain depth,the seismic response of the wind turbine increases.The shear wave velocity of the seabed affects the bending moment and displacement at the bottom of the tower.When the angle of incidence increases,the vertical displacement and the acceleration of the top of the tower increase in varying degrees. 展开更多
关键词 offshore monopile wind turbine seismic response analysis soil-junction interactions fluid-structure inter-action
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A novel refined dynamic model of high-speed maglev train-bridge coupled system for random vibration and running safety assessment
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作者 MAO Jian-feng LI Dao-hang +3 位作者 YU Zhi-wu CAI Wen-feng GUO Wei ZHANG Guang-wen 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第7期2532-2544,共13页
Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can b... Running safety assessment and tracking irregularity parametric sensitivity analysis of high-speed maglev train-bridge system are of great concern,especially need perfect refinement models in which all properties can be well characterized based on various stochastic excitations.A three-dimensional refined spatial random vibration analysis model of high-speed maglev train-bridge coupled system is established in this paper,in which multi-source uncertainty excitation can be considered simultaneously,and the probability density evolution method(PDEM)is adopted to reveal the system-specific uncertainty dynamic characteristic.The motion equation of the maglev vehicle model is composed of multi-rigid bodies with a total 210-degrees of freedom for each vehicle,and a refined electromagnetic force-air gap model is used to account for the interaction and coupling effect between the moving train and track beam bridges,which are directly established by using finite element method.The model is proven to be applicable by comparing with Monte Carlo simulation.By applying the proposed stochastic framework to the high maglev line,the random dynamic responses of maglev vehicles running on the bridges are studied for running safety and stability assessment.Moreover,the effects of track irregularity wavelength range under different amplitude and running speeds on the coupled system are investigated.The results show that the augmentation of train speed will move backward the sensitive wavelength interval,and track irregularity amplitude influences the response remarkably in the sensitive interval. 展开更多
关键词 maglev train-bridge interaction electromagnetic force-air gap model stochastic dynamic analysis running safety assessment probability density evolution method
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协作学习的实践研究报告——以内蒙古师范大学日语系实践为例
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作者 其力格尔 《语文学刊》 2016年第7期168-170,共3页
本文主要论述关于在中国内蒙古地区日语协作学习教育的可能性问题。通过对内蒙古师范大学日语专业三年级学生的日语协作学习实践调查,分析出他们对日语协作学习的态度及意识变化,并结合语言生态学、支援学、相互学习理论来论述其可行性... 本文主要论述关于在中国内蒙古地区日语协作学习教育的可能性问题。通过对内蒙古师范大学日语专业三年级学生的日语协作学习实践调查,分析出他们对日语协作学习的态度及意识变化,并结合语言生态学、支援学、相互学习理论来论述其可行性。实践调查结果显示,学生们对日语视听说课堂上的互动及相互学习效果持肯定的态度,学生总体上期待协作学习在其他专业课程上也运用这种学习方法。并得出协作学习在中国内蒙古地区少数民族日语教育上的可能性的结论。 展开更多
关键词 学习 实践调查 相互作 内蒙古地区 学习兴致
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Dynamics of Nonlinear Waves in(2+1)-Dimensional Extended Boiti-Leon-Manna-Pempinelli Equation
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作者 SUN Junxiu WANG Yunhu 《应用数学》 北大核心 2024年第4期1103-1113,共11页
Based on the Hirota bilinear method,this study derived N-soliton solutions,breather solutions,lump solutions and interaction solutions for the(2+1)-dimensional extended Boiti-Leon-Manna-Pempinelli equation.The dynamic... Based on the Hirota bilinear method,this study derived N-soliton solutions,breather solutions,lump solutions and interaction solutions for the(2+1)-dimensional extended Boiti-Leon-Manna-Pempinelli equation.The dynamical characteristics of these solutions were displayed through graphical,particularly revealing fusion and ssion phenomena in the interaction of lump and the one-stripe soliton. 展开更多
关键词 Hirota bilinear method N-soliton solutions Breather solutions Lump solutions Interaction solutions (2+1)-dimensional extended Boiti-Leon-Manna-Pempinelli equation
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Local existence and uniqueness of the incompressible Navier-Stokes-Landau-Lifshitz equations with the Dzyaloshinskii-Moriya interaction and V-flow term
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作者 HUANG Gui-huo WANG Guang-wu +1 位作者 YE Ting-ting QIU Zhen 《广州大学学报(自然科学版)》 CAS 2024年第3期44-57,共14页
In this paper,we prove that there exists a unique local solution for the Cauchy problem of a system of the incompressible Navier-Stokes-Landau-Lifshitz equations with the Dzyaloshinskii-Moriya interaction and V-flow t... In this paper,we prove that there exists a unique local solution for the Cauchy problem of a system of the incompressible Navier-Stokes-Landau-Lifshitz equations with the Dzyaloshinskii-Moriya interaction and V-flow term inR^(2) and R^(3).Our methods rely upon approximating the system with a perturbed parabolic system and parallel transport. 展开更多
关键词 incompressible Navier-Stokes-Landau-Lifshitz equations Dzyaloshinskii-Moriya interac-tion local solution
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己酸菌的筛选及其在浓香型白酒生产中应用的研究进展 被引量:3
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作者 殷想想 王欣蕊 +6 位作者 冯文聪 李良 陈晖 董孝元 常煦 方尚玲 陈茂彬 《中国酿造》 CAS 北大核心 2023年第9期14-18,共5页
浓香型白酒主体香风味物质己酸乙酯的前体物质是己酸,己酸菌是生成己酸的主体微生物,所以己酸菌在中国浓香型白酒中起着举足轻重的地位。该文对己酸菌的筛选与产酸途径进行了简单介绍,重点论述了己酸菌与其他微生物间的相互作用及其在... 浓香型白酒主体香风味物质己酸乙酯的前体物质是己酸,己酸菌是生成己酸的主体微生物,所以己酸菌在中国浓香型白酒中起着举足轻重的地位。该文对己酸菌的筛选与产酸途径进行了简单介绍,重点论述了己酸菌与其他微生物间的相互作用及其在浓香型白酒中的应用现状,为提高己酸菌的产量、探究微生物之间的关系以及将己酸菌通过不同方式应用于浓香型白酒中提供一定的理论基础和参考。 展开更多
关键词 己酸菌 筛选 代谢途径 相互 应用
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轨检车测取的轨道谱精度分析 被引量:5
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作者 张格明 罗林 《铁道学报》 EI CAS CSCD 北大核心 1999年第3期67-71,共5页
从理论解析、模型仿真分析及实测对比三方面,研究分析了轨检车移动负荷轮在不同速度时通过平顺轨道和不平顺轨道区段的动态轨迹变化。分析表明,在移动负荷轮作用下,轨道不平顺引起的轨道附加变形在不同速度时的量值很小,可忽略不计... 从理论解析、模型仿真分析及实测对比三方面,研究分析了轨检车移动负荷轮在不同速度时通过平顺轨道和不平顺轨道区段的动态轨迹变化。分析表明,在移动负荷轮作用下,轨道不平顺引起的轨道附加变形在不同速度时的量值很小,可忽略不计,基于负荷车轮进行轨道不平顺动态检测可如实反映实际轨道不平顺特征和幅值大小,用轨检车测取的轨道不平顺样本进行轨道谱分析不会影响轨道谱精度,澄清了轨检车的检测数据可能包含较大响应成分的疑虑。 展开更多
关键词 轨道不平顺 轨道检查车 功率谱 轮轨相互作
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Collision and attachment behavior between fine cassiterite particles and H_2 bubbles 被引量:15
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作者 任浏祎 张一敏 +2 位作者 覃文庆 包申旭 王军 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第2期520-527,共8页
Particle-bubble interaction during electro-flotation of cassiterite was investigated by determining the recovery of cassiterite and the collision mechanism of cassiterite particle and H2 bubble. Flotation tests at dif... Particle-bubble interaction during electro-flotation of cassiterite was investigated by determining the recovery of cassiterite and the collision mechanism of cassiterite particle and H2 bubble. Flotation tests at different conditions were conducted in a single bubble flotation cell. The recovery of cassiterite was found to be affected by cassiterite particle and bubble size. A matching range, in which the best recovery can be obtained, was found between particle and bubble size. Collision, attachment, and detachment of the particle-bubble were observed and captured by a high-speed camera. Particle-bubble collision and attachment were analyzed with the use of particle-bubble interaction theory to obtain the experimental results. An attachment model was introduced and verified through the photos captured by the high-speed camera. A bridge role was observed between the bubbles and particles. Particle-bubble interaction was found to be affected by bubble size and particle size, which significantly influenced not only the collision and attachment behavior of the particles and bubbles but also the flotation recovery of fine cassiterite particles. 展开更多
关键词 CASSITERITE fine particle flotation particle-bubble interaction collision and attachment
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Preparation, characterization, and catalytic performance of high efficient CeO_2-MnO_x-Al_2O_3 catalysts for NO elimination 被引量:8
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作者 姚小江 李露露 +5 位作者 邹伟欣 虞硕涵 安继斌 李红丽 杨复沫 董林 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第8期1369-1380,共12页
A series of CeO2‐MnOx‐Al2O3 mixed oxide catalysts (Ce:Mn:Al mole ratio=6:4:x, x=0.25, 0.5, 1, 2) were prepared by a simple one‐step inverse co‐precipitation method to investigate the influence of the incorpo... A series of CeO2‐MnOx‐Al2O3 mixed oxide catalysts (Ce:Mn:Al mole ratio=6:4:x, x=0.25, 0.5, 1, 2) were prepared by a simple one‐step inverse co‐precipitation method to investigate the influence of the incorporation of Al3+ into CeO2‐MnOx mixed oxides. CeO2‐MnOx, CeO2‐Al2O3, and MnOx‐Al2O3 mixed oxides, and CeO2 were prepared by the same method for comparison. The samples were characterized by XRD, Raman, N2 physisorption, H2‐TPR, XPS, and in situ DRIFTS. The catalytic re‐duction of NO by CO was chosen as a model reaction to evaluate the catalytic performance. The incorporation of a small amount of Al3+into CeO2‐MnOx mixed oxides resulted in a decrease of crys‐tallite size, with the increase of the BET specific surface area and pore volume, as well as the in‐crease of Ce3+and Mn4+. The former benefits good contact between catalyst and reactants, and the latter promotes the adsorption of CO and the desorption, conversion and dissociation of adsorbed NO. All these enhanced the catalytic performance for the NO+CO model reaction. A reaction mecha‐nism was proposed to explain the excellent catalytic performance of CeO2‐MnOx‐Al2O3 catalysts for NO reduction by CO. 展开更多
关键词 Ceria-based mixed oxide Incorporation Electron interaction Adsorption property NO elimination
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Electro-flotation and collision-attachment mechanism of fine cassiterite 被引量:8
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作者 覃文庆 任浏祎 +2 位作者 王佩佩 杨聪仁 张雁生 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2012年第4期917-924,共8页
In order to discuss the particle-bubble interaction during the electro-flotation of cassiterite,the recovery of cassiterite with different particle sizes was investigated,and the collision mechanism between the cassit... In order to discuss the particle-bubble interaction during the electro-flotation of cassiterite,the recovery of cassiterite with different particle sizes was investigated,and the collision mechanism between the cassiterite particles and H2 bubbles was explored.The flotation tests were carried out in a single bubble flotation cell.The results show that cassiterite particles 10 μm,10-20 μm,20?38 μm and 38-74 μm match with bubbles with size of 50-150 μm,about 250 μm,74 μm and 74 μm,respectively,and a better recovery can be obtained.It is demonstrated that the recovery of cassiterite is influenced by the size of cassiterite particles and bubbles.Furthermore,the probabilities of collision,adhesion,detachment and collection were calculated using the collision,attachment and collection models.Theoretical calculation results show that the collision probability decreases sharply with decreasing particle size and increasing bubble size(below 150 μm).The attachment probability would increase from the effective collision,leading to the increase of recovery. 展开更多
关键词 CASSITERITE particle-bubble interaction fine particle flotation ELECTRO-FLOTATION collision-attachment probability
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Application of molecular interaction volume model in separation of Pb-Sn-Sb ternary alloy by vacuum distillation 被引量:3
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作者 孔令鑫 杨斌 +4 位作者 徐宝强 李一夫 李亮 刘大春 戴永年 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2013年第8期2408-2415,共8页
Based on the molecular interaction volume model (MIVM), the activities of components of Pb Sn Sb ternary alloy were predicted. The vapo^liquid phase equilibrium of Pb-Sn-Sb alloy system was calculated using the acti... Based on the molecular interaction volume model (MIVM), the activities of components of Pb Sn Sb ternary alloy were predicted. The vapo^liquid phase equilibrium of Pb-Sn-Sb alloy system was calculated using the activity coefficients of Pb Sn-Sb alloy system in the process of vacuum distillation. The calculated results show that the content of Sn in vapor phase increases with the increasing distillation temperature and content of Sn in liquid phase. However, the content of Sn in vapor phase is only 0.45% (mass fraction) while 97% in liquid phase at 1100 ℃, which shows that the separating effect is very well. Experimental investigations on the separation of Pb-Sn-Sb ternary alloy were carried out in the distillation temperature range of 1100-1300 ℃ under vacuum condition. It is found that the Sn content in vapor phase is 0.54% while 97% in liquid phase at 1100 ℃. Finally, the predicted data were compared with the experimental results showing good agreement with each other. 展开更多
关键词 molecular interaction volume model vacuum distillation Pb-Sn-Sb alloy phase equilibrium
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Framework-solvent interactional mechanism and effect of NMP/DMF on solvothermal synthesis of [Zn_4O(BDC)_3]_8 被引量:3
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作者 吴争平 王明雪 +4 位作者 周丽姣 尹周澜 谈进 张锦玲 陈启元 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2014年第11期3722-3731,共10页
In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) o... In order to explore the effect mechanism of solvent on the synthesis of the metal organic framework materials, the microscopic interaction between solvent and framework and the effects of N,N-dimethyl-formamide(DMF) or N-methyl- 2-pyrrolidone(NMP) on solvothermal synthesis of [Zn4O(BDC)3]8 were investigated through a combined DFT and experimental study. XRD and SEM showed that the absorbability of NMP in the pore of [Zn4O(BDC)3]8 was weaker than that of DMF. The thermal decomposition temperature of [Zn4O(BDC)3]8 synthesized in DMF was higher than that in NMP according to TG and FT-IR. In addition, the nitrogen sorption isotherms indicated that NMP improved gas sorption property of [Zn4O(BDC)3]8. The COSMO optimized calculations indicated that the total energy of Zn4O(BDC)3 in NMP was higher than that in DMF, and compared with non-solvent system, the charge of zinc atoms decreased and the charge value was the smallest in NMP. Furthermore, the interaction of DMF, NMP or DEF in [Zn4O(BDC)3]8 crystal model was calculated by DFT method. The results suggested that NMP should be easier to be removed from pore of materials than DMF from the point of view of energy state. It can be concluded that NMP was a favorable solvent to synthesize [Zn4O(BDC)3]8 and the microscopic mechanism was that the binding force between Zn4O(BDC)3 and NMP molecule was weaker than DMF. 展开更多
关键词 solvothermal synthesis [Zn4O(BDC)3]8 N-METHYL-2-PYRROLIDONE interactional mechanism COSMO solvation model density functional method
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Effect of NH_4^+ exchange on CuY catalyst for oxidative carbonylation of methanol 被引量:4
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作者 王玉春 郑华艳 李忠 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2016年第8期1403-1412,共10页
NaY and ion exchanged NaNH4Y zeolite with NH4NO3 were used as the support to prepare CuY cata‐lysts by a high temperature anhydrous interaction between the support and copper (II) acety‐lacetonate Cu(acac)2. The... NaY and ion exchanged NaNH4Y zeolite with NH4NO3 were used as the support to prepare CuY cata‐lysts by a high temperature anhydrous interaction between the support and copper (II) acety‐lacetonate Cu(acac)2. The catalysts were used for the oxidative carbonylation of methanol to dime‐thyl carbonate (DMC) at atmospheric pressure. The textural and acidic properties of NaNH4Y zeolite and the CuY catalysts were investigated by X‐ray diffraction, scanning electron microscopy, N2 ad‐sorption‐desorption, temperature programmed reduction of H2, X‐ray photoelectron spectroscopy and temperature programmed desorption of NH3. With increasing NH4NO3 concentration, the NH4+exchange degree increased while the crystallinity of the zeolite remained intact. Crystalline CuO was formed when the NH4+exchange degree of NaNH4Y was low, and the corresponding CuY catalyst showed low catalytic activity. With increasing of the NH4+exchange degree of NaNH4Y, the content of surface bound Cu+active centers increased and the catalytic activity of the corresponding CuY catalyst also increased. The surface bound Cu+content reached its maximum when the NH4+ex‐change degree of NaNH4Y reached towards saturation. The CuY exhibited optimal catalytic activity with 267.3 mg/(g·h) space time yield of DMC, 6.9%conversion of methanol, 68.5%selectivity of DMC. 展开更多
关键词 High temperature anhydrous interaction NH4+exchange degree CuY catalyst Oxidative carbonylation Dimethyl carbonate
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