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尿素溶液分离体系的汽液平衡 被引量:7
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作者 魏顺安 杨楠 +2 位作者 付雪梅 董立春 张舒雯 《化学工程》 CAS CSCD 北大核心 2011年第11期83-87,共5页
以NH3,CO2为原料的合成尿素溶液中含有NH3,CO2,H2O,NH2CONH2等组分,在减压解吸、蒸发等过程中都需要NH3-CO2-H2O-NH2CONH2无尿素反应体系的汽液平衡计算。文中采用文献中NH3-CO2-H2O体系以及上述四元体系在温度为60—160℃、压力小于3.0... 以NH3,CO2为原料的合成尿素溶液中含有NH3,CO2,H2O,NH2CONH2等组分,在减压解吸、蒸发等过程中都需要NH3-CO2-H2O-NH2CONH2无尿素反应体系的汽液平衡计算。文中采用文献中NH3-CO2-H2O体系以及上述四元体系在温度为60—160℃、压力小于3.0 MPa、液相NH3摩尔分率小于0.3范围内的汽液平衡实验数据,汽液平衡计算中用SRK方程计算气相组分的逸度系数,用扩展型UNIQUAC方程计算溶液中各真实组分的活度系数,并采用单纯形法回归UNIQUAC方程中的相互作用能参数(该参数与温度相关)。模型的模拟计算结果和实验数据吻合较好。 展开更多
关键词 NH3-CO2-H2O-NH2CONH2 汽液平衡 扩展型UNIQUAC方程 二元相互作用能参数
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水-正丙醇-正丁醇三元体系汽液平衡实验数据与计算 被引量:1
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作者 张建华 魏顺安 +1 位作者 李诗纯 董立春 《高校化学工程学报》 EI CAS CSCD 北大核心 2010年第5期729-734,共6页
水-正丙醇-正丁醇三元体系常见于乙炔法生产1,4-丁二醇工艺产生的废液中,对该体系汽液平衡数据进行测定是对其进行分离回收的前提,而目前文献中,仅在极窄的温度范围内有很少的相关数据。今测定了99.2kPa时,在正丙醇与正丁醇的配料体积... 水-正丙醇-正丁醇三元体系常见于乙炔法生产1,4-丁二醇工艺产生的废液中,对该体系汽液平衡数据进行测定是对其进行分离回收的前提,而目前文献中,仅在极窄的温度范围内有很少的相关数据。今测定了99.2kPa时,在正丙醇与正丁醇的配料体积比分别为1/4、3/7、2/3、1/1和3/2,水含量直至气相出现液液分层条件下水-正丙醇-正丁醇溶液的三元汽液平衡数据,从而明显扩大了该体系的实验数据及温度适用范围;研究中还用扩展型UNIQUAC方程建立了溶液组分的活度系数模型,关联该体系的汽液平衡数据,通过单纯型法回归获得三元体系组分之间的相互作用能参数。计算结果表明,建立的模型应用相同的相互作用能参数,可以很好的关联本实验测定的数据及文献数据,一方面说明本实验数据与文献数据有很好的一致性,另一方面也表明建立的UNIQUAC模型可以可靠地预测水-正丙醇-正丁醇的汽液平衡数据。 展开更多
关键词 水-正丙醇-正丁醇体系 汽液平衡 UNIQUAC模型 相互作用能参数
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A CFD Based Investigation of the Unsteady Hydrodynamic Coefficients of 3-D Fins in Viscous Flow 被引量:3
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作者 Nazir Zulfiqar 苏玉民 王兆立 《Journal of Marine Science and Application》 2010年第3期250-255,共6页
The motion of the fins and control surfaces of underwater vehicles in a fluid is an interesting and challenging research subject.Typically the effect of fin oscillations on the fluid flow around such a body is highly ... The motion of the fins and control surfaces of underwater vehicles in a fluid is an interesting and challenging research subject.Typically the effect of fin oscillations on the fluid flow around such a body is highly unsteady, generating vortices and requiring detailed analysis of fluid-structure interactions.An understanding of the complexities of such flows is of interest to engineers developing vehicles capable of high dynamic performance in their propulsion and maneuvering.In the present study, a CFD based RANS simulation of a 3-D fin body moving in a viscous fluid was developed.It investigated hydrodynamic performance by evaluating the hydrodynamic coefficients (lift, drag and moment) at two different oscillating frequencies.A parametric analysis of the factors that affect the hydrodynamic performance of the fin body was done, along with a comparison of results from experiments.The results of the simulation were found in close agreement with experimental results and this validated the simulation as an effective tool for evaluation of the unsteady hydrodynamic coefficients of 3-D fins.This work can be further be used for analysis of the stability and maneuverability of fin actuated underwater vehicles. 展开更多
关键词 oscillating 3-D fin RANS hydrodynamic performance viscous flow
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Interaction of Counter Propagating Electromagnetic Waves with the Absorbing Plate in the Waveguide
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作者 Eduard A. Gevorkyan 《Journal of Energy and Power Engineering》 2013年第5期995-1000,共6页
The interaction of two coherent counter propagating TE (transverse-electric) and TM (transverse-magnetic) electromagnetic waves with different initial phases in the absorbing plate placed in the regular ideal wave... The interaction of two coherent counter propagating TE (transverse-electric) and TM (transverse-magnetic) electromagnetic waves with different initial phases in the absorbing plate placed in the regular ideal waveguide is considered. The losses of energy of TE and TM waves in the absorbing plate are calculated. Some features of tunnel interference in the absorbing plate in the waveguide are revealed. It is shown that the losses of energy strongly depend on the various parameters describing the interaction of the counter propagating waves. Definitely choosing the parameters we can control the electromagnetic processes in this case. 展开更多
关键词 Electromagnetic waves PROPAGATION INTERFERENCE WAVEGUIDE energy losses absorbing plate.
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Decoherence-and Dimerization-assisted Energy Transport in Protomer of Light-Harvesting Complexes
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作者 周运清 李有泉 《Communications in Theoretical Physics》 SCIE CAS CSCD 2016年第1期114-120,共7页
We have investigated the dynamics of a protomer coupled to two different decoherent environments,each in a configuration called the spin star configuration.Using the quantum mechanics method,in different situations,we... We have investigated the dynamics of a protomer coupled to two different decoherent environments,each in a configuration called the spin star configuration.Using the quantum mechanics method,in different situations,we obtain the analytical expressions for the transition probability in the protomer system.In thermal equilibrium,there exist well-defined ranges of parameters for which decoherent interaction between the protomer and the environment assists energy transfer in the protomer system,while in pure quantum mechanics states,the decoherent interaction assists energy transfer for an eigenstate but against energy transfer for quantum mechanics averages.In particular,we also find that the dimerization of two bacteriochlorophylls in protomer can always assist energy transfer in certain parameter range,and in the appropriate spin bath energy,the efficiency of energy transport is sensitively depended on the temperature of environments. 展开更多
关键词 clecoherence assisted energy transport light-harvesting complexes protomer
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