几种增塑剂与PVC树脂混容性研究

本文用测清晰点的方法,测定了DBP、DOP、DOTP以及DBP+DOTP等增塑剂与不同型号PVC树脂之间相互作用参数κ值。并以此讨论了增塑剂与PVC树脂的混容性能。

A CFD Based Investigation of the Unsteady Hydrodynamic Coefficients of 3-D Fins in Viscous Flow

The motion of the fins and control surfaces of underwater vehicles in a fluid is an interesting and challenging research subject.Typically the effect of fin oscillations on the fluid flow around such a body is highly unsteady, generating vortices and requiring detailed analysis of fluid-structure interactions.An understanding of the complexities of such flows is of interest to engineers developing vehicles capable of high dynamic performance in their propulsion and maneuvering.In the present study, a CFD based RANS simulation of a 3-D fin body moving in a viscous fluid was developed.It investigated hydrodynamic performance by evaluating the hydrodynamic coefficients (lift, drag and moment) at two different oscillating frequencies.A parametric analysis of the factors that affect the hydrodynamic performance of the fin body was done, along with a comparison of results from experiments.The results of the simulation were found in close agreement with experimental results and this validated the simulation as an effective tool for evaluation of the unsteady hydrodynamic coefficients of 3-D fins.This work can be further be used for analysis of the stability and maneuverability of fin actuated underwater vehicles.

Effects of a flexible net barrier on the dynamic behaviours and interception of debris flows in mountainous areas

Flexible net barriers are a new type of effective mitigation measure against debris flows in valleys and can affect the kinematic energy and mass of debris flows. Here, ten flume tests were performed to study the dynamic behaviours of debris flows with differences in volumes, concentrations(solid volume fraction), and travel distances after interception by a uniform flexible net barrier. A high-speed camera was used to monitor the whole test process, and their dynamic behaviours were recorded. A preliminary computational framework on energy conversion is proposed according to the deposition mechanisms and outflow of debris flow under the effects of the flexible net barrier. The experimental results show that the dynamic interaction process between a debris flow and the flexible net barrier can be divided into two stages:(a) the two-phase impact of the leading edge of the debris flow with the net and(b) collision and friction between the body of the debris flow and intercepted debris material. The approach velocity of a debris flow decreases sharply(a maximum of 63%) after the interception by the net barrier, and the mass ratio of the debris material being intercepted and the kinetic energy ratio of the debris material being absorbed by the net barrier are close due to the limited interception efficiency of the flexible net barrier, which is believed to be related to the flexibility. The energy ratio of outflow is relative small despite the large permeability of the flexible net barrier.

Interaction of Counter Propagating Electromagnetic Waves with the Absorbing Plate in the Waveguide

The interaction of two coherent counter propagating TE （transverse-electric） and TM （transverse-magnetic） electromagnetic waves with different initial phases in the absorbing plate placed in the regular ideal waveguide is considered. The losses of energy of TE and TM waves in the absorbing plate are calculated. Some features of tunnel interference in the absorbing plate in the waveguide are revealed. It is shown that the losses of energy strongly depend on the various parameters describing the interaction of the counter propagating waves. Definitely choosing the parameters we can control the electromagnetic processes in this case.

Efect of Tensor Force on the Halo Structure of ^(29)Ne and ^(31)Ne

The structure of Ne isotopes has been investigated by using deformed Skyrme-Hartree-Fock （SHF） method and BCS approximation. Especially the effect of tensor force on the halo structure of 29Ne and 31Ne is discussed. To this end, the tensor contributions are considered to the energy density function and the single particle potential in SHF theory. For comparison, four Skyrme interactions are used： SLy5 and SGII without tensor force, and SLy5＋T and SGII＋ T with tensor force. The results indicate that the inclusion of tensor force shows a more pronounced halo structure for 31Ne.

Effect of Phase Shifted Frequency Modulation on Two Level Atom-Field Interaction

We have studied the effect of phase shifted frequency modulation on two level atom with field interaction using Jaynes-Cummings model.Here the frequency of the interacting field is sinusoidally varying with time with a constant phase.Due to the presence of phase in the frequency modulation,the variation of population inversion with time is different from the standard case.There are no exact collapses and revivals in the variation of population inversion but it oscillates sinusoidally with time.In coherent field atom interaction the population inversion behaves as in the case of Fock state atom interaction,when frequency modulation with a non zero phase is applied.The study done with squeezed field has shown the same behavior of the population inversion.

Rapid and accurate evaluation of the binding energies and the individual N H…O=C, N H…N, C H…O=C, and C H…N interaction energies for hydrogen-bonded peptide-base complexes

The binding energies of thirty-six hydrogen-bonded peptide-base complexes, including the peptide backbone-ase complexes and amino acid side chain-base complexes, are evaluated using the analytic potential energy function established in our lab recently and compared with those obtained from MP2, AMBER99, OPLSAA/L, and CHARMM27 calculations. The comparison indicates that the analytic potential energy function yields the binding energies for these complexes as reasonable as MP2 does, much better than the force fields do. The individual N H…O=C, N H…N, C H…O=C, and C H…N attractive interaction energies and C=O…O=C, N H…H N, C H…H N, and C H…H C repulsive interaction energies, which cannot be easily obtained from ab initio calculations, are calculated using the dipole-dipole interaction term of the analytic potential energy function. The individual N H…O=C, C H…O=C, C H…N attractive interactions are about 5.3±1.8, 1.2±0.4, and 0.8 kcal/mol, respectively, the individual N H … N could be as strong as about 8.1 kcal/mol or as weak as 1.0 kcal/mol, while the individual C=O…O=C, N H…H N, C H…H N, and C H…H C repulsive interactions are about 1.8±1.1, 1.7±0.6, 0.6±0.3, and 0.35±0.15 kcal/mol. These data are helpful for the rational design of new strategies for molecular recognition or supramolecular assemblies.

Decoherence-and Dimerization-assisted Energy Transport in Protomer of Light-Harvesting Complexes

We have investigated the dynamics of a protomer coupled to two different decoherent environments,each in a configuration called the spin star configuration.Using the quantum mechanics method,in different situations,we obtain the analytical expressions for the transition probability in the protomer system.In thermal equilibrium,there exist well-defined ranges of parameters for which decoherent interaction between the protomer and the environment assists energy transfer in the protomer system,while in pure quantum mechanics states,the decoherent interaction assists energy transfer for an eigenstate but against energy transfer for quantum mechanics averages.In particular,we also find that the dimerization of two bacteriochlorophylls in protomer can always assist energy transfer in certain parameter range,and in the appropriate spin bath energy,the efficiency of energy transport is sensitively depended on the temperature of environments.