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无相互作用的相互稳定自治系统动力学的一个评注(英文)
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作者 杨晓松 《应用数学》 CSCD 北大核心 2002年第2期5-8,共4页
本文证明了无相互作用的相互渐近稳定的自治系统的动力学非常简单 ,因此人们应该研究具有相互作用的或耦合的系统的相互稳定性 .
关键词 相互作用 相互稳定 自治系统 动力系统 常微分方程
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空间飞行器尾部区域内等离子体与场的非稳态相互作用 被引量:1
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作者 马善钧 《江西师范大学学报(自然科学版)》 CAS 2001年第3期251-255,共5页
该文利用数值计算的方法 ,研究了运动飞行器与周围等离子体非稳态非线性相互作用问题 .通过求解非稳态非线性相互作用耦合方程 ,得到了在飞行器远尾区 ,场和密度扰动的分布 .计算结果显示 ,在飞行器的尾区 ,飞行器上的天线系统可以作为... 该文利用数值计算的方法 ,研究了运动飞行器与周围等离子体非稳态非线性相互作用问题 .通过求解非稳态非线性相互作用耦合方程 ,得到了在飞行器远尾区 ,场和密度扰动的分布 .计算结果显示 ,在飞行器的尾区 ,飞行器上的天线系统可以作为调制不稳定性的激发源 ,激发出可探测的密度空洞和电磁孤波 .通过对这种密度空洞和电磁孤波的探测 ,可以跟踪探测隐身飞行器的轨迹 . 展开更多
关键词 飞行器 尾区 孤波 密度空洞 等离子体 稳定相互作用
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Stability analysis method of geogrid reinforced expansive soil slopes and its engineering application 被引量:27
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作者 ZHANG Rui LONG Ming-xu +2 位作者 LAN Tian ZHENG Jian-long GEOFF Chao 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第7期1965-1980,共16页
The traditional stability analysis method of geogrid reinforced slopes does not consider the effect of lateral swelling,so it is not applicable to reinforced expansive soil slopes.This paper reports a new stability an... The traditional stability analysis method of geogrid reinforced slopes does not consider the effect of lateral swelling,so it is not applicable to reinforced expansive soil slopes.This paper reports a new stability analysis method for geogrid reinforced expansive soil slopes.The additional pullout force of the free zone due to the lateral swelling and the anti-pullout safety factor of each geogrid layer were obtained by ensuring the overall stability of the reinforced slope.The optimum design was carried out to treat an expansive soil cut slope in Hubei Province,China,by changing the spacing and length of geogrid reinforcement.Calculation results show that the additional pullout force caused by lateral swelling has a great influence on the anti-pullout stability of geogrids,and the local stability of the reinforced slope will be overestimated if the swelling effect of soil in the free zone is not considered. 展开更多
关键词 expansive soil lateral swelling pressure geogrid-soil interaction stability analysis engineering application
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Computation of Ship Hydrodynamic Interaction Forces in Restricted Waters using Potential Theory 被引量:8
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作者 Xueqian Zhou Serge Sutulo C. Guedes Soares 《Journal of Marine Science and Application》 2012年第3期265-275,共11页
A computer code based on the double-body potential flow model and the classic source panel method has been developed to study various problems of hydrodynamic interaction between ships and other objects with solid bou... A computer code based on the double-body potential flow model and the classic source panel method has been developed to study various problems of hydrodynamic interaction between ships and other objects with solid boundaries including the seabed. A peculiarity of the proposed implementation is the application of the so-called "moving-patch" method for simulating steady boundaries of large extensions. The method is based on an assumption that at any moment just the part of the boundary ("moving patch") which lies close to the interacting ship is significant for the near-field interaction. For a specific case of the fiat bottom, comparative computations were performed to determine optimal dimensions of the patch and of the constituting panels based on the trade-off between acceptable accuracy and reasonable efficiency. The method was applied to estimate the sway force on a ship hull moving obliquely across a dredged channel. The method was validated for a case of ship-to-ship interaction when tank data were available. This study also contains a description of a newly developed spline approximation algorithm necessary for creating consistent discretizations of ship hulls with various degrees of refinement. 展开更多
关键词 ship hydrodynamic interaction restricted waters moving panelled patch method potential theory
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An assessment of coal pillar system stability criteria based on a mechanistic evaluation of the interaction between coal pillars and the overburden 被引量:21
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作者 Reed Guy Mctyer Kent Frith Russell 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2017年第1期9-15,共7页
Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assi... Coal pillar design has historically assigned a factor of safety(Fo S) or stability factor(SF) according to their estimated strength and the assumed overburden load acting on them. Acceptable Fo S values have been assigned based on past mining experience or a statistical link between Fo S and probability of failure(Po F). Pillar width-to-height(w/h) ratio has long been established as having a material influence on both pillar strength and its potential failure mode. However, there has been significant disagreement on using both factor of safety(Fo S) and w/h as part of pillar system stability criterion, as compared to using Fo S in isolation. This paper will argue that there are valid technical reasons to bring w/h ratio into system stability criteria(other than its influence on pillar strength), as it is related to the post-failure stiffness of the pillar, as measured in situ, and its interaction with overburden stiffness. When overburden stiffness is also brought into pillar system stability considerations, two issues emerge. The first is the width-todepth(W/D) ratio of the panel and whether it is sub-critical or super-critical from a surface subsidence perspective. The second relates to a re-evaluation of pillar Fo S based on whether the pillar is in an elastic or non-elastic(i.e., post-yield) state in its as-designed condition, as this is relevant to maintaining overburden stiffness at the highest possible level. The significance of the model is the potential to maximise both reserve recovery and mining efficiencies without any discernible increase in geotechnical risk, particularly in thick seams and higher depth of cover mining situations. At a time when mining economics are, at best, marginal, removing potentially unnecessary design conservatism is of interest to all mine operators and is an important topic for discussion amongst the geotechnical community. 展开更多
关键词 Coa] pillars Stability OVERBURDEN Post-failure behaviour Stability criteria
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Research on the influence of action between fin and anti-rolling tank on the integrated stabilization effect 被引量:2
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作者 YU Li-jun JIN Hong-zhang WANG Hui YANG Sheng 《Journal of Marine Science and Application》 2007年第1期9-14,共6页
Through analyzing the roll model of the integrated system of fin and anti-rolling tank, this paper uses binomial equation to simplify the module and check how the approximate parameters simulate the original function.... Through analyzing the roll model of the integrated system of fin and anti-rolling tank, this paper uses binomial equation to simplify the module and check how the approximate parameters simulate the original function. Based on the simplified module, the influence of fin and anti-rolling tank on the coefficient items of the roll module is discussed, and the influencing factors between fin and anti-rolling tank are analysed. And through simulation, the influence of action between fin and anti-rolling tank on the static characteristics, and the integrated stabilization effect, are analyzed. 展开更多
关键词 fin stabilizer anti-rolling tank integrated stabilization action each other INFLUENCE
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Application of atomic layer deposition in fabricating high-efficiency electrocatalysts 被引量:11
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作者 Huimin Yang Yao Chen Yong Qin 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 北大核心 2020年第2期227-241,共15页
Electrocatalysis is a promising approach to clean energy conversion due to its high efficiency and low environmental pollution. Noble metal materials have been studied to show high activity toward electrocatalyltic re... Electrocatalysis is a promising approach to clean energy conversion due to its high efficiency and low environmental pollution. Noble metal materials have been studied to show high activity toward electrocatalyltic reactions, although such applications remain restricted by the high cost and poor durability of the noble metals. By precisely adjusting the catalyst composition, size, and structure, electrocatalysts with excellent performance can be obtained. Atomic layer deposition(ALD) is a technique used to produce ultrathin films and ultrafine nanoparticles at the atomic level. It possesses unique advantages for the controllable design and synthesis of electrocatalysts. Furthermore, the homogenous composition and structure of the electrocatalysts prepared by ALD favor the exploration of structure-reactivity relationships and catalytic mechanisms. In this review, the mechanism, characteristics, and advantages of ALD in fabricating nanostructures are introduced first. Subsequently, the problems associated with existing electrocatalysts and a series of recently developed ALD strategies to enhance the activity and durability of electrocatalysts are presented. For example, the deposition of ultrafine Pt nanoparticles to increase the utilization and activity of Pt, fabrication of core–shell, overcoat, nanotrap, and other novel structures to protect the noble-metal nanoparticles and enhance the catalyst stability. In addition, ALD developments in synthesizing non-noble metallic electrocatalysts are summarized and discussed. Finally, based on the current studies, an outlook for the ALD application in the design and synthesis of electrocatalysts is presented. 展开更多
关键词 Atomic layer deposition ELECTROCATALYSIS PT Catalyst stability Metal-support interaction
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THE ROLE OF MERIDIONAL WIND STRESS IN THE TROPICAL UNSTABLE AIR-SEA INTERACTION
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作者 房佳蓓 杨修群 《Journal of Tropical Meteorology》 SCIE 2003年第1期95-104,共10页
With a simple tropical coupled ocean-atmosphere model, this paper presents an analysis aiming to understand the relative role of the meridional and zonal wind stresses in the tropical unstable air-sea interaction. The... With a simple tropical coupled ocean-atmosphere model, this paper presents an analysis aiming to understand the relative role of the meridional and zonal wind stresses in the tropical unstable air-sea interaction. The roles of the zonal wind stress, the meridional wind stress and the both are considered respectively into the coupled system. It is demonstrated that the meridional component of the wind stress does not lead to any instability under the local thermal balance assumption, but it does lead to a weak instability under the sea surface temperature advection assumption. Unstable air-sea interaction is dominated by the zonal component of the wind stress, suggesting that ignoring the meridional wind stress is approximately feasible in studying the tropical unstable air-sea interaction. 展开更多
关键词 wind stress air-sea interactions INSTABILITY
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Citrate-stabilized CdSe/CdS quantum dots as fluorescence probe for protein determination 被引量:3
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作者 傅昕 黄可龙 刘素琴 《Journal of Central South University》 SCIE EI CAS 2010年第4期720-725,共6页
A rapid, ultrasensitive and convenient fluorescence measurement technology based on the enhancement of the fluorescence intensity resulting from the interaction of functionalized CdSe/CdS quantum dots (QDs) with bov... A rapid, ultrasensitive and convenient fluorescence measurement technology based on the enhancement of the fluorescence intensity resulting from the interaction of functionalized CdSe/CdS quantum dots (QDs) with bov/ne serum albumin (BSA) was proposed. The citrate-stabilized CdSe/CdS (QDs) were synthesized by using Se powder and Na2S as precursors instead of any pyrophoric organometallic precursors. The modified CdSe/CdS QDs are brighter and more stable against photobleaching in comparison with organic fluorophores. At pH 7.0, the fluorescence signal of CdSe/CdS is enhanced by increasing the concentration of BSA in the range of 0.1-10 μg/mL, and the low detection limit is 0.06 μg/mL. A linear relationship between the enhanced fluorescence peak intensity (△F) and BSA concentration (c) is established using equation △F=50.7c+16.4 (R=0.996 36). Results of determination for BSA in three synthetic samples are identical with the true values, and the recovery (98.9%-102.4%) and relative standard deviation (RSD, 1.8%-2.5%) are satisfactory. 展开更多
关键词 CdSe/CdS quantum dots bovine serum albumin PROTEIN fluorescence measurement
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Influence of Integral Instability of Kramers-Kronig Transformation on Photoabsorption Cross Sections 被引量:1
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作者 MA Xiao-Guang GONG Yu-Bing QU Zhao-Jun 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第8期369-376,共8页
The photoabsorption cross sections of condensed atoms and molecules have proven to be dependent not only on the imaginary parts but also on the real parts of the polarizabilities due to the strong interatomie interact... The photoabsorption cross sections of condensed atoms and molecules have proven to be dependent not only on the imaginary parts but also on the real parts of the polarizabilities due to the strong interatomie interactions in condensed environment. The real parts of the polarizabilities calculated usually by using the famous Kramers-Kronig transformation (KKT) from the photoabsorption cross sections of the isolated atoms are very sensitive to the accuracy of the implementation method of the infinite integral in the KKT. The influence of the integral instability of the KKT and the real part of the polarizability on the variation of the photoabsorption cross sections with the number density and the structure of the condensed matter has been studied in the present work for the first time. The conclusion is that the integration method with interpolation has given more reasonable results than the direct truncation method if some appropriate interpolation functions have been used. Some notes and conclusions have also been given for the applications of the alternative coupled expressions of photoabsorption cross sections. 展开更多
关键词 condensed-phase photoabsorption Kramers-Kronig transformation dynamic polarizability
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Coalescence Behaviors of Drop Swarms on Liquid-Liquid Interface 被引量:4
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作者 唐洪涛 陈建平 崔世海 《Transactions of Tianjin University》 EI CAS 2011年第2期96-102,共7页
The trajectory model of dispersed phase drops and distribution model of drop diameters were derived.By numerical simulation,the analytical results indicate that a large number of dispersed phase drops accumulate on th... The trajectory model of dispersed phase drops and distribution model of drop diameters were derived.By numerical simulation,the analytical results indicate that a large number of dispersed phase drops accumulate on the upper plate in different directions and form a hydrodynamic area with the stream-wise location in the range of 0—0.4m,where the flow of trickling film obtains kinetic drive from flowing field.The flowing field of trickling film exhibits an unstable state if the stream-wise location is less than 0.02m,and a stable state otherwise.Moreover,different velocity vectors of drops in the x-y plane result in different interactions between the trickling film and drops.For the non-uniform distribution of drop diameters,there is a stronger interaction between the trickling film and drop if the stream-wise location is less than 0.02m,because the amplitudes of velocity vectors are higher than those in the range of 0.02—1.0m.The result reveals a complexity and diversity of stratified two-phase flowing field.On the other hand,both the basic flowing field and distributions of drop diameters have a great influence on the distributions of comparable kinetic energy of drops.The complicated motions of larger drops are helpful to coalescence because they will consume much more kinetic energy on the trickling film than those of smaller drops.The change of comparable kinetic energy of smaller drops is continuous and steady.The smaller drops are easily entrained by the liquid-liquid flowing field. 展开更多
关键词 TRAJECTORY COALESCENCE DROP DIAMETER distribution
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Theoretical Investigation on Interaction between Guanine and Luteolin
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作者 Lai-cai Li Kun-kun Bai Wan-fei Cai 《Chinese Journal of Chemical Physics》 SCIE CAS CSCD 2013年第5期533-540,I0003,共9页
The interacting patterns of the luteolin and guanine have been investigated by using the density functional theory B3LYP method with 6-31+G* basis set. Eighteen stable structures for the luteolin-guanine complexes h... The interacting patterns of the luteolin and guanine have been investigated by using the density functional theory B3LYP method with 6-31+G* basis set. Eighteen stable structures for the luteolin-guanine complexes have been found respectively. The results indicate that the complexes are mainly stabilized by the hydrogen bonding interactions. Meanwhile, both the number and strength of hydrogen bond play important roles in determining the stability of the complexes which can form two or more hydrogen bonds. Theories of atoms in molecules and natural bond orbital have also been utilized to investigate the hydrogen bonds involved in all the systems. The interaction energies of all the complexes which were corrected by basis set superposition error are 6.04-56.94 kJ/mol. The calculation results indicate that there are strong hydrogen bonding interactions in the luteolin-guanine complexes. We compared the interaction between luteolin and four bases of DNA, and found luteolin-thymine was the strongest and luteolin-adenine was the weakest. The interaction between luteolin and DNA bases are all stronger than luteolin-water. 展开更多
关键词 Density functional theory LUTEOLIN GUANINE Hydrogen bond Atoms inmolecules Natural bond orbital
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Research on key technologies in design of middle pylon of Taizhou Bridge 被引量:1
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作者 Ji Lin 《Engineering Sciences》 EI 2012年第3期2-7,共6页
At the middle pylon of a three-pylon two-span suspension bridge, the effect of unbalanced loads on the adjacent spans may result in a series of technical bottlenecks in design, such as stability and anti-slippage betw... At the middle pylon of a three-pylon two-span suspension bridge, the effect of unbalanced loads on the adjacent spans may result in a series of technical bottlenecks in design, such as stability and anti-slippage between saddles and main cables. This article presents the researches conducted on structure selection and behavior characteristics of middle pylon, interaction mechanism between main cables and saddles and their anti-slippage safety performance, elastic and plastic stability analysis and safety assessment of steel middle pylon, and fatigue design load and method for steel pylon of Taizhou Bridge. According to the research results, a longitudinal inverted Y shape steel middle pylon is used in design, effectively solving many technical difficulties, and this type of pylon has become a suitable middle pylon structural form for many three-ovlon two-soan susoension bridges. 展开更多
关键词 three-pylon two-span suspension bridge structural behavior and selection elastic and plastic stability main cable and saddle anti-slippage
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Risk Premiums and Financial Stability
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作者 Bogdan Moinescu 《Journal of Modern Accounting and Auditing》 2011年第8期792-798,共7页
The collective revelation of credit institutions as regards the imminence of specific risks materialising, which often follows long periods of underestimating probable losses, can trigger a broad-based financial delev... The collective revelation of credit institutions as regards the imminence of specific risks materialising, which often follows long periods of underestimating probable losses, can trigger a broad-based financial deleveraging via an overly high upsurge in banks' risk premiums vis-a-vis the dynamics of fundamentals underlying loan repayment capability. In this context, this paper seeks to investigate the banking sector's internal mechanisms that might bring about a negative spiral of credit risk by building a model for the interaction between the increase of the risk premium and that of net interest income and provisioning rate. Statistical results confirm that a higher risk premium is one of the major determinants of credit default in Romania and its excessive widening could affect financial stability in Romania. 展开更多
关键词 risk premium financial stability negative spirals of credit risk financial deleveraging CDS (credit default swap) spread
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Magnetoelastic Instability in Ring-Shaped Molecule Magnets with Next-Nearest Neighbor Coupling
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作者 LI Peng-Fei CHEN Yu-Guang 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第12期1125-1128,共4页
In considering next-nearest neighbor (NNN) coupling, we numerically investigate the magnetoelastic instability in ring-shaped mesoscopic antiferromagnetic Heisenberg spin 1/2 systems with spin-phonon interaction. Th... In considering next-nearest neighbor (NNN) coupling, we numerically investigate the magnetoelastic instability in ring-shaped mesoscopic antiferromagnetic Heisenberg spin 1/2 systems with spin-phonon interaction. The results indicate that, for antiferromagnetic NNN coupling J2, there may be a critical value J2^c, at which the ground state is dimerized for arbitrary lattice spring constant and beyond and below which the magnetoelastic instability behavior is different from each other. The values of J2^c are irrelevant to the system size. For ferromagnetic NNN coupling, only continuous transition is present from dimerized phase to uniform phase as lattice spring constant is increased. 展开更多
关键词 single molecule magnets magnetoelastic instability spin-phonon interaction
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The Stabilizing Role of Material Structure in Scientific Practice
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作者 Anna Estany 《Journal of Philosophy Study》 2012年第6期398-410,共13页
Knowledge of the environment is essential for the survival of organisms; but those organisms have to have the capacity to stabilize such knowledge. The aim of this article is to analyze the various strategies for stab... Knowledge of the environment is essential for the survival of organisms; but those organisms have to have the capacity to stabilize such knowledge. The aim of this article is to analyze the various strategies for stabilizing human knowledge, with a special focus on its material anchors and their interactions with other stabilization means. In particular, I consider how such stabilization is reflected in scientific activity and practice, and what its repercussions are for the models of science that have dominated the philosophical landscape of the 20th century. My starting hypothesis will be that the role of material anchors in stabilizing conceptual blends is analogous to that of technology in grounding scientific knowledge. The framework I adopt with regard to conceptualization is that of Fauconnier and Turner (2002) on conceptual blends. Just as technology intervenes in scientific practice in conjunction with conceptual elements, so do material anchors, which conjoin other non-material strategies of knowledge stabilization. Endowing knowledge with a material basis may be understood firstly as an element (sometimes a key element) for representing knowledge and offering an explanation, and secondly as a way of providing a scientific hypothesis with empirical grounding. It is this second sense that connects with scientific experimentation and the use of instruments and technology. 展开更多
关键词 conceptual blends material anchors naturalized philosophy of science social distributed cognition CONCEPTUAL social and material strategies of stabilization the role of technology in scientific experimentation
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Stability and Collective Excitation of Two-Dimensional BECs with Two-and Three-Body Interactions in an Anharmonic Trap
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作者 YONG Wen-Mei WEI Xiu-Fang +1 位作者 ZHOU Xiao-Yan XUE Ju-Kui 《Communications in Theoretical Physics》 SCIE CAS CSCD 2009年第3期433-440,共8页
The stability and collective excitation of Bose-Einstein condensates with both two- and three-body interactions in a two-dimensional anhaxmonic trap (i.e., harmonic plus quartic trap) are investigated. By using the ... The stability and collective excitation of Bose-Einstein condensates with both two- and three-body interactions in a two-dimensional anhaxmonic trap (i.e., harmonic plus quartic trap) are investigated. By using the variational method, the influence of the three-body interaction and the anharmonicity on the stability axe discussed in detail. It is found that the anhaxmonicity of the trap and the three-body interaction have significant effect on the stability and collective excitations of the system. 展开更多
关键词 Bose Einstein condensates STABILITY ANHARMONICITY three-body interaction
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A Proof of Lyapunov Stability of a Nonlinear Observer for the Mechanical States of Turbogenerator Systems
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作者 A. Alwadie A. M. Abdel-Hamid 《Journal of Energy and Power Engineering》 2013年第6期1206-1213,共8页
The dynamics of a turbogenerator are characterized by a nonlinearly interacting electrical and mechanical subsystems. Accurate and robust state reconstruction by an observer should be based on its nonlinear dynamic be... The dynamics of a turbogenerator are characterized by a nonlinearly interacting electrical and mechanical subsystems. Accurate and robust state reconstruction by an observer should be based on its nonlinear dynamic behavior. Linear and reduced order observers are undesired since intolerable error of state reconstruction may be expected especially if the operating conditions and/or the external disturbances are, as usual in modern power systems, extremely changed. The 2nd authors of this paper had published a methodical design of a full order nonlinear observer for turbogenerator systems and conducted its experimental validation on a 120 MVA and 1,000 MVA synchronous generators at Gud-Power Station in south Munich (Germany) and the Nuclear Power Station of Goesgen (Switzerland). In this paper, the Lyapunov's stability is applied to the mechanical slow motion of nonlinear observer. A second order Lyapunov function is introduced. Based on the energy interpretations of its terms, the necessary and sufficient conditions for the asymptotic stability of this nonlinear observer are derived. 展开更多
关键词 TURBOGENERATORS Lyapunov stability function nonlinear observer synchronous generator nonlinear feedback.
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Promoted porous Co_3O_4-Al_2O_3 catalysts for ammonia decomposition 被引量:2
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作者 Zhe-Shan Zhang Xin-Pu Fu +3 位作者 Wei-Wei Wang Zhao Jin Qi-Sheng Song Chun-Jiang Jia 《Science China Chemistry》 SCIE EI CAS CSCD 2018年第11期1389-1398,共10页
Transition metal catalysts have been considerably used for NH3 decomposition because of the potential application in COx-free H2 generation for fuel cells. However, most transition metal catalysts prepared via traditi... Transition metal catalysts have been considerably used for NH3 decomposition because of the potential application in COx-free H2 generation for fuel cells. However, most transition metal catalysts prepared via traditional synthetic approaches performed the inferior stability due to the agglomeration of active components. Here, we adopted an efficient method, aerosol-assisted self- assembly approach (AASA), to prepare the optimized cobalt-alumina (C0304-A1203) catalysts. The C0304-A1203 catalysts exhibited excellent catalytic performance in the NH3 decomposition reaction, which can reach 100% conversion at 600 ℃and maintain stable for 72 h at a gaseous hourly space velocity (GHSV) of 18000 cm3 gcat-1 h-1. The catalysts were characterized by various techniques including transmission electron microscope (TEM), scanning electron microscope (SEM), nitrogen sorption, temperature-programmed reduction by hydrogen (H2-TPR), ex-situ/in-situ Raman and ex-situ/in-situ X-ray diffraction (XRD) to obtain the information about the structure and property of the catalysts. H2-TPR and in-situ XRD results show that there is strong interaction between the cobalt and alumina species, which influences the redox properties of the catalysts. It is found that even a low content of alumina (10 at%) is able to stabilize the catalysts due to the adequate dispersion and rational interaction between different components, which ensures the high activity and superior stability of the cobalt-alumina catalysts. 展开更多
关键词 cobalt-alumina catalyst aerosol-assisted self-assembly approach ammonia decomposition anti-sintering redox prop-erties
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Solvating power regulation enabled low concentration electrolyte for lithium batteries 被引量:3
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作者 Linshan Peng Xiangkun Wu +6 位作者 Mengmin Jia Weiwei Qian Xiaoyan Zhang Na Zhou Lan Zhang Cuiying Jian Suojiang Zhang 《Science Bulletin》 SCIE EI CAS CSCD 2022年第21期2235-2244,共10页
Li^(+) solvation structures have a decisive influence on the electrode/electrolyte interfacial properties and battery performances.Reduced salt concentration may result in an organic rich solid electrolyte interface(S... Li^(+) solvation structures have a decisive influence on the electrode/electrolyte interfacial properties and battery performances.Reduced salt concentration may result in an organic rich solid electrolyte interface(SEI)and catastrophic cycle stability,which makes low concentration electrolytes(LCEs)rather challenging.Solvents with low solvating power bring in new chances to LCEs due to the weak salt-solvent interactions.Herein,an LCE with only 0.25 mol L^(-1) salt is prepared with fluoroethylene carbonate(FEC)and 1,1,2,2-tetrafluoroethyl-2,2,3,3-tetrafluoropropylether(D_(2)).Molecular dynamics simulations and experiments prove that the low solvating power solvent FEC not only renders reduced desolvation energy to Li^(+) and improves the battery kinetics,but also promotes the formation of a LiF-rich SEI that hinders the electrolyte consumption.Li||Cu cell using the LCE shows a high coulombic efficiency of 99.20%,and LiNi_(0.6)Co_(0.2)Mn_(0.2)O_(2)||Li cell also exhibits satisfying capacity retention of 89.93%in 200 cycles,which demonstrates the great potential of solvating power regulation in LCEs development. 展开更多
关键词 Lithium metal batteries Solvating power Low concentration electrolytes Desolvation energy FEC
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