Molecular dynamic simulations are performed to study the nanoscratching behavior of polymers.The effects of scratching depth,scratching velocity and indenter/polymer interaction strength are investigated.It is found t...Molecular dynamic simulations are performed to study the nanoscratching behavior of polymers.The effects of scratching depth,scratching velocity and indenter/polymer interaction strength are investigated.It is found that polymer material in the scratching zone around the indenter can be removed in a ductile manner as the local temperature in the scratching zone exceeds glass transition temperature Tg.The recovery of polymer can be more significant when the temperature approaches or exceeds Tg.The tangential force,normal force and friction coefficient increase as the scratching depth increases.A larger scratching velocity leads to more material deformation and higher pile-up.The tangential force and normal force are larger for a larger scratching velocity whereas the friction coefficient is almost independent of the scratching velocities studied.It is also found that stronger indenter/polymer interaction strength results in a larger tangential force and friction coefficient.展开更多
Stimulus-responsive energy storage devices,which can respond to external stimuli,such as heat,pH,moisture,pressure,or electric field,have recently attracted intensive attention,aiming at the ever-increasing demand for...Stimulus-responsive energy storage devices,which can respond to external stimuli,such as heat,pH,moisture,pressure,or electric field,have recently attracted intensive attention,aiming at the ever-increasing demand for safe batteries and smart electronics.The most typical stimulus-responsive materials are polymers that can change their conformation by forming and destroying secondary forces,including hydrogen bonds and electrostatic interactions in response to external stimuli,accompanied by changes in the intrinsic properties such as conductivity and hydrophobicity.Although the applications of stimulus-responsive functions in rechargeable batteries are still in the early stage because of the complexity and compatibility of battery architectures,many new concepts of regulating the polymer structures upon applications of stimuli have already been developed.In this review,we discuss the recent progress of stimulus-responsive polymers on energy storage devices featuring thermal protection and intelligent scenarios,with a focus on the detailed structural transformations of polymers under a given stimulus and the corresponding changes in battery performance.Finally,we present perspectives on the current limitations and future research directions of stimulus-responsive polymers for energy storage devices.展开更多
Up to now the chirality is seldom studied in the diluted spin glass although many investigations have been performed on the site-ordered Edwards-Anderson model. By simulation, we investigate the dynamicaJ properties o...Up to now the chirality is seldom studied in the diluted spin glass although many investigations have been performed on the site-ordered Edwards-Anderson model. By simulation, we investigate the dynamicaJ properties of both the spin-glass and the chiral-glass phases in a diluted dipolar system, which was manifested to have a spin-glass transition by recent numerical study. By scaling we find that both phases have the same aging behavior and closer aging parameterμ. Similarly, the domains grow in the same way and both phases have a closer barrier exponent g2. It means that both the spins and the chirality have the same dynamical properties and they may freeze at the same temperature.展开更多
基金supported by the National Natural Science Foundation of China (Grant No.90923038)the National Basic Research Program of China (Grant No.2011CB706703)+1 种基金"111"project (Grant No.B07014)by the State Administration of Foreign Experts Affairs and the Ministry of Education of China
文摘Molecular dynamic simulations are performed to study the nanoscratching behavior of polymers.The effects of scratching depth,scratching velocity and indenter/polymer interaction strength are investigated.It is found that polymer material in the scratching zone around the indenter can be removed in a ductile manner as the local temperature in the scratching zone exceeds glass transition temperature Tg.The recovery of polymer can be more significant when the temperature approaches or exceeds Tg.The tangential force,normal force and friction coefficient increase as the scratching depth increases.A larger scratching velocity leads to more material deformation and higher pile-up.The tangential force and normal force are larger for a larger scratching velocity whereas the friction coefficient is almost independent of the scratching velocities studied.It is also found that stronger indenter/polymer interaction strength results in a larger tangential force and friction coefficient.
基金financially supported by the National Key R&D Program of China(2017YFE0127600)the Strategic Priority Research Program of the Chinese Academy of Sciences(XDA22010600)+4 种基金the National Natural Science Foundation of China(21975271)the Key-Area Research and Development Program of Guangdong Province(2020B090919005)Shandong Natural Science Foundation(ZR2020ZD07 and ZR2021QB106)the financial support from the Youth Innovation Promotion Association of CAS(2019214)Shandong Energy Institute(SEI 1202127)。
文摘Stimulus-responsive energy storage devices,which can respond to external stimuli,such as heat,pH,moisture,pressure,or electric field,have recently attracted intensive attention,aiming at the ever-increasing demand for safe batteries and smart electronics.The most typical stimulus-responsive materials are polymers that can change their conformation by forming and destroying secondary forces,including hydrogen bonds and electrostatic interactions in response to external stimuli,accompanied by changes in the intrinsic properties such as conductivity and hydrophobicity.Although the applications of stimulus-responsive functions in rechargeable batteries are still in the early stage because of the complexity and compatibility of battery architectures,many new concepts of regulating the polymer structures upon applications of stimuli have already been developed.In this review,we discuss the recent progress of stimulus-responsive polymers on energy storage devices featuring thermal protection and intelligent scenarios,with a focus on the detailed structural transformations of polymers under a given stimulus and the corresponding changes in battery performance.Finally,we present perspectives on the current limitations and future research directions of stimulus-responsive polymers for energy storage devices.
基金Supported by National Natural Science Foundation of China under Grant Nos.11247428,61274101Natural Science Foundation of Liaoning Province under Grant No.20121078
文摘Up to now the chirality is seldom studied in the diluted spin glass although many investigations have been performed on the site-ordered Edwards-Anderson model. By simulation, we investigate the dynamicaJ properties of both the spin-glass and the chiral-glass phases in a diluted dipolar system, which was manifested to have a spin-glass transition by recent numerical study. By scaling we find that both phases have the same aging behavior and closer aging parameterμ. Similarly, the domains grow in the same way and both phases have a closer barrier exponent g2. It means that both the spins and the chirality have the same dynamical properties and they may freeze at the same temperature.
