Photodetachment of H- irradiated by linearly polarized few-cycle laser field is investigated by time-dependent SchrSdinger equation numerically. The photo-electron left-right asymmetry parameter as a function of carri...Photodetachment of H- irradiated by linearly polarized few-cycle laser field is investigated by time-dependent SchrSdinger equation numerically. The photo-electron left-right asymmetry parameter as a function of carrier-envelop (CE) phase of few-cycle pulses is attained. We confirm the asymmetry of photoelectron distribution in H- photodetachment and find that the maximal asymmetry parameter of H- is equal to that of H atom under the same conditions but the corresponding CE phases are quite different. Thus a CE phase shift appears. Compared to that of H atom and field free electron, the zero asymmetry CE phase shift is sensitively affected by Coulomb field. The Coulomb effect on the asymmetry of H- photodetachment mainly behaves in the CE phase shift of H- instead of the amplitude of asymmetry parameter curve.展开更多
Objective:To evaluate the correlation of the quantifiable parameters of blood flow pattern derived with dynamic CT in solitary bronchogenic adenocarcinoma(SBA).Methods:46 patients with solitary bronchogenic adenocarci...Objective:To evaluate the correlation of the quantifiable parameters of blood flow pattern derived with dynamic CT in solitary bronchogenic adenocarcinoma(SBA).Methods:46 patients with solitary bronchogenic adenocarcinomas (SBA)(diameter≤4 cm)underwent multi-location dynamic contrast material-enhanced(nonionic contrast material was administrated via the antecubital vein at a rate of 4 mL/s by using an autoinjector 90 mL,4×5 mm or 4×2.5 mm scanning mode with stable table were performed)serial CT.Precontrast and postcontrast attenuation on every scan was recorded.Perfusion (PBA),peak height(PHBA),ratio of peak height of the SPN to that of the aorta(BA-to-A ratio)and mean transit time(MTT)were calculated.The correlation between peak height of the aorta(PHA)and parameters of the SBA(PHBA,BA-to-A ratio,PBA,and MTT)and those among parameters of the SBA were assessed by means of linear regression analysis.Regression equation among parameters of the SBA were obtain by means of stepwise regression.Results:The correlation between the SBA peak height(PHBA,36.78 HU±12.02)and the aortic peak height(PHA)was significant(r=0.506,P<0.0001).No significant cor- relation was found between the BA-to-Apeak height ratio(15.33%±4.55)and the aortic peak height(r=0.130,P=0.388> 0.05)as it was between the SBA perfusion(PBA,31.86 mL/min/100 g±9.74)and the aortic peak height(r=0.049,P=0.749 >0.05).The SBA perfusion correlated with the PHBA and the BA-to-A peak height ratio(r=0.394,P=0.007<0.05;r=0.407, P=0.005<0.05).The PHBA correlated positively with the BA-to-A peak height ratio(r=0.781,P<0.0001).Mean transit time was 14.84 s±5.52.PBA=18.500+0.872×BA-to-A ratio.BA-to-A ratio=4.467+0.295×PHBA.Conclusion:The linear correlation between the SBA perfusion and BA-to-Aratio and that between BA-to-Aratio and PHBA can be expressed by equation. It is possible to design a simpler scanning procedure of investigation of bronchogenic adenocarcinoma angiogenesis.展开更多
In this paper, Cramer-Rao Bound (CRB) is derived from phase-coding signal with additive white noise, where three important parameters are focused on: carrier frequency, chip width and amplitude. Simplified and close f...In this paper, Cramer-Rao Bound (CRB) is derived from phase-coding signal with additive white noise, where three important parameters are focused on: carrier frequency, chip width and amplitude. Simplified and close form expressions of CRB are obtained through complicated derivation, and then are applied to evaluate the performance of the cyclic estimator.The results are accurate enough and serve well as benchmark for evaluating the performance of parameter estimation method. Numerical simulations illustrate the accuracy and applicability of the derived CRB.展开更多
Accurate measurement of flow parameters is important in gas-solid two-phase flow,and such flow has to be dealt with in many processes involving bulk solids handling and transportation.The circular electrostatic sensor...Accurate measurement of flow parameters is important in gas-solid two-phase flow,and such flow has to be dealt with in many processes involving bulk solids handling and transportation.The circular electrostatic sensor is one of those used for gas-solid flow measurement.In this paper,the finite element method(FEM)is used to establish the mathematical model of the sensor,the spatial sensitivity characteristics of the sensors is analyzed,and the analytic model is improved by the nonlinear least square method and the iterative method.Finally,the correlation coefficients between the experimental results and the improved processing are compared and analyzed,and the mathematical expression of the model is improved.The feasibility and practicability of the improved model are verified.展开更多
In order to optimize the crashworthy characteristic of energy-absorbing structures, the surrogate models of specific energy absorption (SEA) and ratio of SEA to initial peak force (REAF) with respect to the design...In order to optimize the crashworthy characteristic of energy-absorbing structures, the surrogate models of specific energy absorption (SEA) and ratio of SEA to initial peak force (REAF) with respect to the design parameters were respectively constructed based on surrogate model optimization methods (polynomial response surface method (PRSM) and Kriging method (KM)). Firstly, the sample data were prepared through the design of experiment (DOE). Then, the test data models were set up based on the theory of surrogate model, and the data samples were trained to obtain the response relationship between the SEA &amp; REAF and design parameters. At last, the structure optimal parameters were obtained by visual analysis and genetic algorithm (GA). The results indicate that the KM, where the local interpolation method is used in Gauss correlation function, has the highest fitting accuracy and the structure optimal parameters are obtained as: the SEA of 29.8558 kJ/kg (corresponding toa=70 mm andt= 3.5 mm) and REAF of 0.2896 (corresponding toa=70 mm andt=1.9615 mm). The basis function of the quartic PRSM with higher order than that of the quadratic PRSM, and the mutual influence of the design variables are considered, so the fitting accuracy of the quartic PRSM is higher than that of the quadratic PRSM.展开更多
As one of the most important geometric parameters for a PC-type fiber connector end face, apex offset can contribute to high insertion loss and high back-reflection reading. A novel measurement method for the paramete...As one of the most important geometric parameters for a PC-type fiber connector end face, apex offset can contribute to high insertion loss and high back-reflection reading. A novel measurement method for the parameter, connector rotating-π method, is proposed. With the method, the apex offset of a common connector end face is measured. The result is compared with that measured by a Norland 3000 fiber connector end face interferometer. It is found that the difference between two results is 1.8μm. Meantime, the influences of relevant error resources on apex offset measurement under rotating-π method and apex-core method are respectively analyzed, and two error equations are derived. The analytical result shows that, compared with apex-core method, if two additional sub-tilts of axis within and in the direction perpendicular to principal plane caused by its rotation are not bigger than the original axis tilt angle, the max. measurement error will then be reduced by at least 22.5% with rotating-π method. The practicability of the method is confirmed by the experiments.展开更多
By virtue of the properties of bipartite entangled state representation we derive the common eigenvector of the parametric Hamiltonian and the two-mode number-difference operator. This eigenvector is superposition of ...By virtue of the properties of bipartite entangled state representation we derive the common eigenvector of the parametric Hamiltonian and the two-mode number-difference operator. This eigenvector is superposition of some definite two-mode Foek states with the coefficients being proportional to hypergeometric functions. The Gauss contiguous relation of hypergeometrie functions is used to confirm the formal solution.展开更多
The thermal quantum discord (QD) is studied in a two-qubit Heisenberg XXZ system with DzyaloshinskiiMoriya (DM) interaction. We compare the thermal QD with thermal entanglement in this system and find remarkable d...The thermal quantum discord (QD) is studied in a two-qubit Heisenberg XXZ system with DzyaloshinskiiMoriya (DM) interaction. We compare the thermal QD with thermal entanglement in this system and find remarkable differences between them. For instance, we show situations where QD decreases asymptotically to zero with temperature T while entanglement decreases to zero at the point of critical temperature, situations where QD decreases with certain tunable parameters such as Dx and Dx when entanglement increases. We find that the characteristic of QD is exotic in this system and this possibly offers a potential solution to enhance entanglement of a system. We also show that tunable parameter Dx is more efficient than parameter Dz in most regions for controlling the QD.展开更多
For the diagnosis of glaucoma,optical coherence tomography(OCT)is a noninvasive imaging technique for the assessment of retinal layers.To accurately segment intraretinal layers in an optic nerve head(ONH)region,we pro...For the diagnosis of glaucoma,optical coherence tomography(OCT)is a noninvasive imaging technique for the assessment of retinal layers.To accurately segment intraretinal layers in an optic nerve head(ONH)region,we proposed an automatic method for the segmentation of three intraretinal layers in eye OCT scans centered on ONH.The internal limiting membrane,inner segment and outer segment,Bruch’s membrane surfaces under vascular shadows,and interaction of multiple high-reflectivity regions in the OCT image can be accurately segmented through this method.Then,we constructed a novel spatial-gradient continuity constraint,termed spatial-gradient continuity constraint,for the correction of discontinuity between adjacent image segmentation results.In our experiment,we randomly selected 20 B-scans,each annotated three retinal layers by experts.Signed distance errors of?0.80μm obtained through this method are lower than those obtained through the state-of-art method(?1.43μm).Meanwhile,the segmentation results can be used as bases for the diagnosis of glaucoma.展开更多
The simplified incidence function model which is driven by the colored correlated noises is employed to investigate the extinction time of a metapopulation perturbed by environments. The approximate Fokker-Planck Equa...The simplified incidence function model which is driven by the colored correlated noises is employed to investigate the extinction time of a metapopulation perturbed by environments. The approximate Fokker-Planck Equation and the mean first passage time which denotes the extinction time (Tex) are obtained by virtue of the Novikov theorem and the Fox approach. After introducing a noise intensity ratio and a dimensionless parameter R = D /α (D and a are the multiplicative and additive colored noise intensities respectively), and then performing numerical computations, the results indicate that: (i) The absolute value of correlation strength A and its correlation time τ3 play opposite roles on the Tex; (ii) For the case of 0 〈λ〈 1,α and its correlation time τ2 play opposite roles on the Tex in which R〉 1 is the best condition, and there is one-peak structure on the Tex - D plot; (iii) For the case of-1 〈 λ≤ 0, D and its correlation time τ1 play opposite roles on the Tex in which R 〈 1 is the best condition and there is one-peak structure on the Tex - τ2 plot.展开更多
A quantum secure direct intercommunication scheme is proposed to exchange directly the communicators' secret messages by making ase of swapping entanglement of Bell states. It has great capacity to distribute the sec...A quantum secure direct intercommunication scheme is proposed to exchange directly the communicators' secret messages by making ase of swapping entanglement of Bell states. It has great capacity to distribute the secret messages since these messages have been imposed on high-dimensional Bell states via the local unitary operations with superdense coding. The security is ensured by the secure transmission of the travel sequences and the application of entanglement swapping.展开更多
The effect of stochastic dephasing on the dynamics of entanglement of qutrit-qutrit states is investigated by using negativity and bound entanglement defined with realignment criterion, From the analysis, we, find tha...The effect of stochastic dephasing on the dynamics of entanglement of qutrit-qutrit states is investigated by using negativity and bound entanglement defined with realignment criterion, From the analysis, we, find that the time evolution of quantum free entanglement and bound entanglement depends on the fluctuations of the stochastic variables and the parameters of the particular initial states of concern. Our results imply that some qutrits states display both distillability sudden death and entanglement sudden death, while some states do not display distillability sudden death but only entanglement sudden death.展开更多
The Berry phase in a composite system induced by the time-dependent interaction is discussed. We choose two coupled spin-1/2 systems as the composite system: one of the subsystems is subjected to a static magnetic fi...The Berry phase in a composite system induced by the time-dependent interaction is discussed. We choose two coupled spin-1/2 systems as the composite system: one of the subsystems is subjected to a static magnetic field, and the coupling parameters between two spins are controllable in time. We show that the time-dependent interaction can induce the Berry phase in a similar way as that a spin-1/2 system (qubit) is driven by an effective time-dependent magnetic field. Furthermore, using two consecutive cycles with opposite directions of both the static magnetic field as well as opposite signs of the coupling parameters, a nontrivial two-qubit unitary transformation purely based on Berry phases can be constructed.展开更多
Zinc oxide (ZnO) has been used as heterogeneous catalyst for the degradation of Acid Alizarin Black S dye (AAB) in aqueous solutions using UV light irradiation. Experiments were conducted at various operating para...Zinc oxide (ZnO) has been used as heterogeneous catalyst for the degradation of Acid Alizarin Black S dye (AAB) in aqueous solutions using UV light irradiation. Experiments were conducted at various operating parameters. The operating parameters were amount of catalyst (50 rag, 100 mg and 150 mg), initial concentration of dye (30 mg/L, 50 mg/L and 70 mg/L), the pH of solution (2, 4, 6, 8, l0 and 12) and the UV light intensity (6 watt and 12 watt). The progress of the degradation reaction was monitored spectrophotometrically. It was found that the degradation process of AAB solution was accelerated with increased catalyst dosage and decreased initial concentration of AAB. It was also found that the removal efficiency of AAB significantly depend on pH value of solution. The results show that the degradation percent reaches the highest values with pH close to neutral. The data proved that removal percent of dye decreased when 6 watt lamp used instead of 12 watt lamp. The kinetic study confirmed that photocatalytic degradation of AAB dye follows a pseudo first order reaction rate.展开更多
The potential energy curves (PECs) of three low-lying electronic states (X^3∑, a^1△, and a^3△) of SO radical have been studied by ab initio quantum chemical method. The calcula- tions were carried out with the ...The potential energy curves (PECs) of three low-lying electronic states (X^3∑, a^1△, and a^3△) of SO radical have been studied by ab initio quantum chemical method. The calcula- tions were carried out with the full valence complete active space self-consistent field method followed by the highly accurate valence internally contracted multireference configuration in- teraction (MRCI) approach in combination with correlation-consistent basis sets. Effects of the core-valence correlation and relativistic corrections on the PECs are taken into account. The core-valence correlation correction is carried out with the cc-pCVDZ basis set. The way to consider the relativistic correction is to use the second-order Douglas-Kroll Hamiltonian approximation, and the correction is performed at the level of cc-pV5Z basis set. To obtain more reliable results, the PECs determined by the MRCI calculations are also corrected for size-extensivity errors by means of the Davidson modification (MRCI+Q). These PECs are extrapolated to the complete basis set limit by the two-point energy extrapolation scheme. With these PECs, the spectroscopic parameters are determined.展开更多
The PD(X^3∑^-) interaction potential is constructed using the CCSD(T) theory and the basis set, augcc-pV5Z. Using this potential, the spectroscopic parameters are accurately determined. The present Do, De, Re, ω...The PD(X^3∑^-) interaction potential is constructed using the CCSD(T) theory and the basis set, augcc-pV5Z. Using this potential, the spectroscopic parameters are accurately determined. The present Do, De, Re, ωe, ωeχe, αe, and Be are of 3.056 99 eV, 3.161 75 eV, 0.142 39 nm, 1701.558 cm^-1, 23.6583 cm^-1, 0.085 99 cm^-1, and 4.3963 cm^-1, respectively, which almost perfectly conform with the measurements. A total of 26 vibrational states is predicted when J = 0 by solving the radial Sehrodinger equation of nuclear motion. The complete vibrational levels, classical turning points, initial rotation and centrifugal distortion constants when J = 0 are reported for the first time, which favorably agree with the experiments. The total and various partial-wave cross sections are calculated for the elastic impact between two ground-state P and D atoms at 1.0 × 10^-12 - 1.0 × 10^-4 a.u. when they approach each other along the PD(X^3∑^-) potential. No shape resonances exist in the total elastic cross sections, though the peaks can be found for each partial wave until l=6. The shape of the total elastic cross sections is dominated by the s partial wave at very low temperatures. Due to the weakness of the shape resonances of each partial wave, they are all passed into oblivion by the strong total elastic cross sections.展开更多
文摘Photodetachment of H- irradiated by linearly polarized few-cycle laser field is investigated by time-dependent SchrSdinger equation numerically. The photo-electron left-right asymmetry parameter as a function of carrier-envelop (CE) phase of few-cycle pulses is attained. We confirm the asymmetry of photoelectron distribution in H- photodetachment and find that the maximal asymmetry parameter of H- is equal to that of H atom under the same conditions but the corresponding CE phases are quite different. Thus a CE phase shift appears. Compared to that of H atom and field free electron, the zero asymmetry CE phase shift is sensitively affected by Coulomb field. The Coulomb effect on the asymmetry of H- photodetachment mainly behaves in the CE phase shift of H- instead of the amplitude of asymmetry parameter curve.
文摘Objective:To evaluate the correlation of the quantifiable parameters of blood flow pattern derived with dynamic CT in solitary bronchogenic adenocarcinoma(SBA).Methods:46 patients with solitary bronchogenic adenocarcinomas (SBA)(diameter≤4 cm)underwent multi-location dynamic contrast material-enhanced(nonionic contrast material was administrated via the antecubital vein at a rate of 4 mL/s by using an autoinjector 90 mL,4×5 mm or 4×2.5 mm scanning mode with stable table were performed)serial CT.Precontrast and postcontrast attenuation on every scan was recorded.Perfusion (PBA),peak height(PHBA),ratio of peak height of the SPN to that of the aorta(BA-to-A ratio)and mean transit time(MTT)were calculated.The correlation between peak height of the aorta(PHA)and parameters of the SBA(PHBA,BA-to-A ratio,PBA,and MTT)and those among parameters of the SBA were assessed by means of linear regression analysis.Regression equation among parameters of the SBA were obtain by means of stepwise regression.Results:The correlation between the SBA peak height(PHBA,36.78 HU±12.02)and the aortic peak height(PHA)was significant(r=0.506,P<0.0001).No significant cor- relation was found between the BA-to-Apeak height ratio(15.33%±4.55)and the aortic peak height(r=0.130,P=0.388> 0.05)as it was between the SBA perfusion(PBA,31.86 mL/min/100 g±9.74)and the aortic peak height(r=0.049,P=0.749 >0.05).The SBA perfusion correlated with the PHBA and the BA-to-A peak height ratio(r=0.394,P=0.007<0.05;r=0.407, P=0.005<0.05).The PHBA correlated positively with the BA-to-A peak height ratio(r=0.781,P<0.0001).Mean transit time was 14.84 s±5.52.PBA=18.500+0.872×BA-to-A ratio.BA-to-A ratio=4.467+0.295×PHBA.Conclusion:The linear correlation between the SBA perfusion and BA-to-Aratio and that between BA-to-Aratio and PHBA can be expressed by equation. It is possible to design a simpler scanning procedure of investigation of bronchogenic adenocarcinoma angiogenesis.
文摘In this paper, Cramer-Rao Bound (CRB) is derived from phase-coding signal with additive white noise, where three important parameters are focused on: carrier frequency, chip width and amplitude. Simplified and close form expressions of CRB are obtained through complicated derivation, and then are applied to evaluate the performance of the cyclic estimator.The results are accurate enough and serve well as benchmark for evaluating the performance of parameter estimation method. Numerical simulations illustrate the accuracy and applicability of the derived CRB.
基金Science and Technology on Electronic Test and Measurement Laboratory(No.9140C12040515X)
文摘Accurate measurement of flow parameters is important in gas-solid two-phase flow,and such flow has to be dealt with in many processes involving bulk solids handling and transportation.The circular electrostatic sensor is one of those used for gas-solid flow measurement.In this paper,the finite element method(FEM)is used to establish the mathematical model of the sensor,the spatial sensitivity characteristics of the sensors is analyzed,and the analytic model is improved by the nonlinear least square method and the iterative method.Finally,the correlation coefficients between the experimental results and the improved processing are compared and analyzed,and the mathematical expression of the model is improved.The feasibility and practicability of the improved model are verified.
基金Project(U1334208)supported by the National Natural Science Foundation of ChinaProject(2013GK2001)supported by the Fund of Hunan Provincial Science and Technology Department,China
文摘In order to optimize the crashworthy characteristic of energy-absorbing structures, the surrogate models of specific energy absorption (SEA) and ratio of SEA to initial peak force (REAF) with respect to the design parameters were respectively constructed based on surrogate model optimization methods (polynomial response surface method (PRSM) and Kriging method (KM)). Firstly, the sample data were prepared through the design of experiment (DOE). Then, the test data models were set up based on the theory of surrogate model, and the data samples were trained to obtain the response relationship between the SEA &amp; REAF and design parameters. At last, the structure optimal parameters were obtained by visual analysis and genetic algorithm (GA). The results indicate that the KM, where the local interpolation method is used in Gauss correlation function, has the highest fitting accuracy and the structure optimal parameters are obtained as: the SEA of 29.8558 kJ/kg (corresponding toa=70 mm andt= 3.5 mm) and REAF of 0.2896 (corresponding toa=70 mm andt=1.9615 mm). The basis function of the quartic PRSM with higher order than that of the quadratic PRSM, and the mutual influence of the design variables are considered, so the fitting accuracy of the quartic PRSM is higher than that of the quadratic PRSM.
基金Research Projects of Nanjing University of Science and Technology
文摘As one of the most important geometric parameters for a PC-type fiber connector end face, apex offset can contribute to high insertion loss and high back-reflection reading. A novel measurement method for the parameter, connector rotating-π method, is proposed. With the method, the apex offset of a common connector end face is measured. The result is compared with that measured by a Norland 3000 fiber connector end face interferometer. It is found that the difference between two results is 1.8μm. Meantime, the influences of relevant error resources on apex offset measurement under rotating-π method and apex-core method are respectively analyzed, and two error equations are derived. The analytical result shows that, compared with apex-core method, if two additional sub-tilts of axis within and in the direction perpendicular to principal plane caused by its rotation are not bigger than the original axis tilt angle, the max. measurement error will then be reduced by at least 22.5% with rotating-π method. The practicability of the method is confirmed by the experiments.
基金The project supported by The President Foundation of the Chinese Academy of Sciences
文摘By virtue of the properties of bipartite entangled state representation we derive the common eigenvector of the parametric Hamiltonian and the two-mode number-difference operator. This eigenvector is superposition of some definite two-mode Foek states with the coefficients being proportional to hypergeometric functions. The Gauss contiguous relation of hypergeometrie functions is used to confirm the formal solution.
基金Supported by the National Natural Science Foundation of China under Grant Nos.90503009,10775116973 Program under Grant No.2005CB724508
文摘The thermal quantum discord (QD) is studied in a two-qubit Heisenberg XXZ system with DzyaloshinskiiMoriya (DM) interaction. We compare the thermal QD with thermal entanglement in this system and find remarkable differences between them. For instance, we show situations where QD decreases asymptotically to zero with temperature T while entanglement decreases to zero at the point of critical temperature, situations where QD decreases with certain tunable parameters such as Dx and Dx when entanglement increases. We find that the characteristic of QD is exotic in this system and this possibly offers a potential solution to enhance entanglement of a system. We also show that tunable parameter Dx is more efficient than parameter Dz in most regions for controlling the QD.
基金Projects(61672542,61573380)supported by the National Natural Science Foundation of China
文摘For the diagnosis of glaucoma,optical coherence tomography(OCT)is a noninvasive imaging technique for the assessment of retinal layers.To accurately segment intraretinal layers in an optic nerve head(ONH)region,we proposed an automatic method for the segmentation of three intraretinal layers in eye OCT scans centered on ONH.The internal limiting membrane,inner segment and outer segment,Bruch’s membrane surfaces under vascular shadows,and interaction of multiple high-reflectivity regions in the OCT image can be accurately segmented through this method.Then,we constructed a novel spatial-gradient continuity constraint,termed spatial-gradient continuity constraint,for the correction of discontinuity between adjacent image segmentation results.In our experiment,we randomly selected 20 B-scans,each annotated three retinal layers by experts.Signed distance errors of?0.80μm obtained through this method are lower than those obtained through the state-of-art method(?1.43μm).Meanwhile,the segmentation results can be used as bases for the diagnosis of glaucoma.
文摘The simplified incidence function model which is driven by the colored correlated noises is employed to investigate the extinction time of a metapopulation perturbed by environments. The approximate Fokker-Planck Equation and the mean first passage time which denotes the extinction time (Tex) are obtained by virtue of the Novikov theorem and the Fox approach. After introducing a noise intensity ratio and a dimensionless parameter R = D /α (D and a are the multiplicative and additive colored noise intensities respectively), and then performing numerical computations, the results indicate that: (i) The absolute value of correlation strength A and its correlation time τ3 play opposite roles on the Tex; (ii) For the case of 0 〈λ〈 1,α and its correlation time τ2 play opposite roles on the Tex in which R〉 1 is the best condition, and there is one-peak structure on the Tex - D plot; (iii) For the case of-1 〈 λ≤ 0, D and its correlation time τ1 play opposite roles on the Tex in which R 〈 1 is the best condition and there is one-peak structure on the Tex - τ2 plot.
基金National Natural Science Foundation of China under Grant Nos.60472018,60773085,and 60773012National 863 Project under Grant No.2006AA01Z255+2 种基金the Natural Science Foundation of Hunan Province under Grant No.07JJ3128the Postdoctoral Science Foundation of China under Grant No.20070420184Science and Technology Project of Hunan Province under Grant No.2008RS4016
文摘A quantum secure direct intercommunication scheme is proposed to exchange directly the communicators' secret messages by making ase of swapping entanglement of Bell states. It has great capacity to distribute the secret messages since these messages have been imposed on high-dimensional Bell states via the local unitary operations with superdense coding. The security is ensured by the secure transmission of the travel sequences and the application of entanglement swapping.
基金Supported by the National Natural Science Foundation of China under Grant Nos. 10947115, 10975125, and 11004001
文摘The effect of stochastic dephasing on the dynamics of entanglement of qutrit-qutrit states is investigated by using negativity and bound entanglement defined with realignment criterion, From the analysis, we, find that the time evolution of quantum free entanglement and bound entanglement depends on the fluctuations of the stochastic variables and the parameters of the particular initial states of concern. Our results imply that some qutrits states display both distillability sudden death and entanglement sudden death, while some states do not display distillability sudden death but only entanglement sudden death.
基金Supported by National Natural Science Foundation of China under Grant No. 10974016
文摘The Berry phase in a composite system induced by the time-dependent interaction is discussed. We choose two coupled spin-1/2 systems as the composite system: one of the subsystems is subjected to a static magnetic field, and the coupling parameters between two spins are controllable in time. We show that the time-dependent interaction can induce the Berry phase in a similar way as that a spin-1/2 system (qubit) is driven by an effective time-dependent magnetic field. Furthermore, using two consecutive cycles with opposite directions of both the static magnetic field as well as opposite signs of the coupling parameters, a nontrivial two-qubit unitary transformation purely based on Berry phases can be constructed.
文摘Zinc oxide (ZnO) has been used as heterogeneous catalyst for the degradation of Acid Alizarin Black S dye (AAB) in aqueous solutions using UV light irradiation. Experiments were conducted at various operating parameters. The operating parameters were amount of catalyst (50 rag, 100 mg and 150 mg), initial concentration of dye (30 mg/L, 50 mg/L and 70 mg/L), the pH of solution (2, 4, 6, 8, l0 and 12) and the UV light intensity (6 watt and 12 watt). The progress of the degradation reaction was monitored spectrophotometrically. It was found that the degradation process of AAB solution was accelerated with increased catalyst dosage and decreased initial concentration of AAB. It was also found that the removal efficiency of AAB significantly depend on pH value of solution. The results show that the degradation percent reaches the highest values with pH close to neutral. The data proved that removal percent of dye decreased when 6 watt lamp used instead of 12 watt lamp. The kinetic study confirmed that photocatalytic degradation of AAB dye follows a pseudo first order reaction rate.
文摘The potential energy curves (PECs) of three low-lying electronic states (X^3∑, a^1△, and a^3△) of SO radical have been studied by ab initio quantum chemical method. The calcula- tions were carried out with the full valence complete active space self-consistent field method followed by the highly accurate valence internally contracted multireference configuration in- teraction (MRCI) approach in combination with correlation-consistent basis sets. Effects of the core-valence correlation and relativistic corrections on the PECs are taken into account. The core-valence correlation correction is carried out with the cc-pCVDZ basis set. The way to consider the relativistic correction is to use the second-order Douglas-Kroll Hamiltonian approximation, and the correction is performed at the level of cc-pV5Z basis set. To obtain more reliable results, the PECs determined by the MRCI calculations are also corrected for size-extensivity errors by means of the Davidson modification (MRCI+Q). These PECs are extrapolated to the complete basis set limit by the two-point energy extrapolation scheme. With these PECs, the spectroscopic parameters are determined.
基金Supported by the Program for Science & Technology Innovation Talents in Universities of Henan Province in China under GrantNo. 2008HASTIT008the National Natural Science Foundation of China under Grant Nos. 60777012 and 10874064
文摘The PD(X^3∑^-) interaction potential is constructed using the CCSD(T) theory and the basis set, augcc-pV5Z. Using this potential, the spectroscopic parameters are accurately determined. The present Do, De, Re, ωe, ωeχe, αe, and Be are of 3.056 99 eV, 3.161 75 eV, 0.142 39 nm, 1701.558 cm^-1, 23.6583 cm^-1, 0.085 99 cm^-1, and 4.3963 cm^-1, respectively, which almost perfectly conform with the measurements. A total of 26 vibrational states is predicted when J = 0 by solving the radial Sehrodinger equation of nuclear motion. The complete vibrational levels, classical turning points, initial rotation and centrifugal distortion constants when J = 0 are reported for the first time, which favorably agree with the experiments. The total and various partial-wave cross sections are calculated for the elastic impact between two ground-state P and D atoms at 1.0 × 10^-12 - 1.0 × 10^-4 a.u. when they approach each other along the PD(X^3∑^-) potential. No shape resonances exist in the total elastic cross sections, though the peaks can be found for each partial wave until l=6. The shape of the total elastic cross sections is dominated by the s partial wave at very low temperatures. Due to the weakness of the shape resonances of each partial wave, they are all passed into oblivion by the strong total elastic cross sections.