相变混凝土复合材料的性能研究综述及展望

相变混凝土(phase change concrete,PCC)是一种新型建筑材料,在相变温度范围内吸收或释放大量热量,在节能和环保方面体现了优异性能。首先综述了相变混凝土的基本原理及其发展应用概况;其次分析了相变混凝土材料性能、力学性能、热学性能的研究现状,指出了当前研究中存在的问题与挑战;最后总结了相变混凝土的试验研究与工程实际应用,并提出了基于相变混凝土复合材料的智能化发展建议。

沥青混合料用相变储能微胶囊型调温剂的制备及性能研究

针对南方高温地区的气候情况,在先前自调温材料低温性能及应用技术研究的基础上,从适用于高温条件下的相变材料、定形材料比选、相变储能微胶囊型调温剂制备等几个方面进行了研究,通过多种试验和数据分析,最终研发了一款适用于高温地区沥青混合料用的相变储能微胶囊型调温剂,并对该微胶囊型调温剂的微观形貌、热性能进行了观测和分析。研究成果能起到夏季高温时段路面高温削峰、延迟极端高温出现时间的作用,有效防止了沥青路面病害,对于延长路面的使用寿命,构建畅通和谐的出行环境有重要借鉴意义。

An Experimental Study on Thermal Characteristics of Laurie Acid as a Latent Heat Storage Material during Melting Process

The objective of this study was to establish the thermal characteristics of the lauric acid (95% purity) as a latent heat storage material filled in the annulus of vertical concentric double pipe during its melting process,The temperature data were used to determine the thermal characteristics,including the temporal temperature variations and the effects of the mass flow rate and the inlet temperature of the heat transfer fluid on the heat transfer coefficient and the heat charging fraction during the melting process,The results indicated that the time to reach to heat charging fraction of 1.0 could be altered by changing the mass flow rate and the inlet temperature of the heat transfer fluid.

Combined powder metallurgy routes to improve thermal and mechanical response of Al−Sn composite phase change materials

Powder metallurgy processes are suitable to produce form-stable solid−liquid phase change materials from miscibility gap alloys.They allow to obtain a composite metallic material with good dispersion of low-melting active phase particles in a high-melting passive matrix,preventing leakage of the particles during phase transition and,therefore,increasing the stability of thermal response.Also,the matrix provides structural properties.The aim of this work is to combine conventional powder mixing techniques(simple mixing and ball milling)to improve active phase isolation and mechanical properties of an Al−Sn alloy.As matter of fact,ball milling of Sn powder allows to reduce hardness difference with Al powder;moreover,ball milling of the two powders together results in fine microstructure with improved mechanical properties.In addition,different routes applied showed that thermal response depends on the microstructure and,in particular,on the particle size of the active phase.In more detail,coarse active phase particles provide a fast heat release with small undercooling,while small particles solidify more slowly in a wide range of temperature.On the other hand,melting and,consequently,heat storage are independent of the particle size of the active phase.This potentially allows to“tailor”the thermal response by producing alloys with suitable microstructure.

Innovative Production of PCMs （Phase Change Materials） Preparation by Vacuum Impregnation： Thermal and Physical Properties

Energy is essential for every human activity for more comfortable life but also consumes more natural resources. In order to control human comfort, temperature usually required when the differences in temperature swing between indoor and outdoor temperatures. PCMs （phase change materials） are the high latent heat materials which can be used in building materials for energy conservation purpose. PCMs can store thermal energy and also can prevent heat to pass through temperature control areas. Paraffin has been used as PCMs are absorbed into the pore of fly ash as paraffin/fly-ash composite and mixed into the buildings materials. Paraffin is an organic material with high melting point （-59℃）, and nonflammable materials therefore paraffin can be used as the building materials for the function of PCMs for energy saving purposes. Composite PCMs can be prepared by vacuum impregnation process. Paraffin in liquid form will be impregnated into the pore of fly ash by vacuum capillary force to form paraffin/fly ash composite PCMs. Vacuum impregnation pressures, vacuum times, impregnation times of liquid paraffin in fly ash pores and temperatures for melting the solid paraffin into the liquid form are all affect on the thermal properties of paraffin/fly ash composite PCMs. Paraffin or PCMs impregnation are also relate to the physical property including the fractal dimensions of the pores of the fly ash particles and paraffin/fly ash composite PCMs. The fractal dimensions of the pore of fly ash and paraffin/fiy ash composites PCMs are between the values of 1.0 and 2.0. Fractal dimensions of paraffin/fly-ash composite PCMs have the same trend as the thermal properties for heat capacity and latent heat of melting. These fractal dimensions technique is a novel method to measure physical property of building material related to latent heat and heat capacity.

Thermal performances of non-equidistant helical-coil phase change accumulator for latent heat storage

Helical-coil is a common structure of heat exchanger unit in phase change heat accumulator and usually has the equal coil pitch between adjacent coils. Its thermal performances could be improved by improving the uniformity of the phase change material （PCM） temperature distribution. Thus, a novel non-equidistant helical-coil structure was proposed in this study. Its coil pitch decreased along the flow direction of heat transfer fluid, which made the heat exchange area in unit volume increase to match the decreasing temperature difference between the heat transfer fluid and PCM. The structure was optimized using numerical simulation. An experimental system was developed and the experiment results indicated that the proposed non-equidistant helical-coil heat accumulator was more effective than equidistant helical-coil for latent heat storage. The uniformity of the temperaalre distribution was also confirmed by simulation results.

A macroscopic constitutive model of shape memory alloy considering cyclic effects

This paper presents a macroscopic constitutive model reproducing the hysteretic behaviors of the superelastic shape memory alloy (SMA) under cyclic loading. The progressive increase of residual strain with the increased cycle number in such materials is assumed to be a consequence of the progressive increase of residual stress-induced martensitic volume fraction upon the cyclic effects. The progressive decrease of phase transformation critical stresses with the increased cycle number in such materials is assumed to be a result from the progressive increase of phase transformation critical temperatures upon the cyclic effects. A cyclic evolution equation is supposed to describe the influences of cycle effects on the material properties of the SMA under cyclic loading. A phase transformation equation expressing the phase transformation behaviors of the SMA under cyclic loading is established based on the differential relationship between martensitic volume fraction and the free energy increment of phase transformation. A mechanical constitutive equation predicting the mechanical characteristics of the SMA under cyclic loading is developed on the basis of thermodynamics and continuum mechanics. The cyclic evolution equation, phase transformation equation, and mechanical constitutive equation together compose the presented macroscopic constitutive model considering cyclic effects. Results of the numerical simulations illustrate that it can well reproduce the superelastic hysteretic behaviors of the SMA under cyclic loading.