双液系气液平衡相图实验中环己烷和异丙醇的回收

本文介绍了双液系气液平衡相图实验中环己烷、异丙醇的回收利用的新方法。

金属相图实验的改进

对金属相图实验仪器和方法进行了改进。

《水盐体系相图》课程中相图应用实验设计——以三元体系(NaCl-KCl-H2O)相图分离NaCl和KCl为例

针对普通高等院校《水盐体系相图》课程的内容、特点及要求,阐述了其对应实验课程开设的意义以及课程设置的具体标准,并以多温下三元体系(NaCl-KCl-H2O)相图分离NaCl和KCl为例,探讨和研究了《水盐体系相图及其应用》实验课程体系,通过相图分析,制定工艺路线,掌握相图应用实验方法,为培养"工学并举"的专业综合应用型人才打下基础。

部分填充水平旋转圆柱筒内涂层流动的实验研究

通过改变液体的动力黏度、填充体积分数(液体体积与圆柱筒容积之比)、圆柱筒转速等实验参数,对部分填充了粘性液体的圆柱筒在绕其水平对称轴旋转时,圆柱筒内液体自由表面出现的各种现象进行了实验探究和初步定性解释.并作出了当固定液体黏度时转速与填充体积分数的实验相图和固定填充体积分数时转速与黏度的实验相图.

Individualized Pixel Synthesis and Characterization of Combinatorial Materials Chips

Conventionally, an experimentally determined phase diagram requires studies of phase formation at a range of temperatures for each composition, which takes years of effort from multiple research groups. Combinatorial materials chip technology, featuring high-throughput synthesis and characterization, is able to determine the phase diagram of an entire composition spread of a binary or ternary system at a single temperature on one materials library, which, though significantly increasing efficiency, still requires many libraries processed at a series of temperatures in order to complete a phase diagram. In this paper, we propose a "one-chip method" to construct a complete phase diagram by individually synthesizing each pixel step by step with a progressive pulse of energy to heat at different temperatures while monitoring the phase evolution on the pixel in situ in real time. Repeating this process pixel by pixel throughout the whole chip allows the entire binary or ternary phase diagram to be mapped on one chip in a single experiment. The feasibility of this methodology is demonstrated in a study of a Ge-Sb-Te ternary alloy system, on which the amorphouscrystalline phase boundary is determined.

NUMERICAL STUDY ON THE FORMATION OF THE SOUTH CHINA SEA WARM CURRENT I. BAROTROPIC CASE

In this work, Princeton Ocean Model (POM) was used to study the formation of the South China Sea Warm Current (SCSWC) in the barotropic case. Monthly averaged wind stress and the inflow/outflow transports in January were used in the numerical simulation which reproduced the SCSWC. The effects of wind stress and inflow/outflow were studied separately. Numerical experiments showed that the Kuroshio intrusion through the Luzon Strait and the slope shelf in the northern SCS are necessary conditions for the formation of the SCSWC. In a flat bottom topography experiment, the wind stress driven northeast current in the northern SCS is a compensatory current.

Method of Precise Auto Tool Setting for Micro Milling

Based on microscope and image processing, a new method of auto tool setting for micro milling was presented. Firstly, a realtime image of tool setting area was obtained by microscope and CCD camera, then image processing was carried out on this image and the gap between the tool and workpiece was calculated. The gap measurement was sent to motion controlling card to make the tool approach to the surface of workpiece. These steps were repeated until the gap is zero, which means that tool setting was finished. Moreover, a reliability verification test was conducted. Results indicated that the precision of tool setting is satisfactory.

Thermodynamic assessment of Mg-Ga binary system

In order to obtain the thermodynamic description of the Mg-Ga binary system,the thermodynamic assessment of the system was carried out using the CALPHAD method through Thermo-calc software package based on the evaluation of all available experimental data from the published literature.The solution phases,including liquid,hcp(Mg) and orthorhombic(Ga),were described by the substitutional solution model,of which the excess Gibbs energies were expressed with the Redlich-Kister polynomial.Meanwhile,all intermetallic compounds,Mg5Ga2,Mg2Ga,MgGa,MgGa2 and Mg2Ga5,were modeled as stoichiometric compounds.A set of self-consistent thermodynamic parameters formulating the Gibbs energies of various phases in the Mg-Ga binary system were obtained finally.The much better agreement is achieved between the calculated results and the reported experimental data.

Measurement method and experimental research on flame emissivity in coal-fired furnaces

The combustion condition in coal-fired furnaces of the large power station boiler is very complex and the flame emissivity is one of the important combustion parameters. A measurement method of the flame emissivity based on the blackbody furnace calibration of CCD （Charge Coupled Device） cameras and the color image processing techniques of computer was introduced. The experimental research on the flame emissivity in a 200 MW boiler furnace and a 300 MW boiler furnace was conducted respectively through the several CCD cameras installed at different height in furnace. The measurement results show： the flame emissivity increases with the increase of the unit load, the flame emissivity of the burner areas in furnace is the highest and the flame emissivity decrease with the increase of height of furnace above the burners area.

Effect of Cu content on the glass forming ability of Cu-Zr-Ti system studied by ion beam mixing

Based on the Cu-Zr-Ti ternary phase diagram,four sets of Cu-Zr-Ti multilayered films with various compositions of Cu20Zr36Ti44,Cu36Zr31Ti33,Cu49Zr24Ti27,and Cu67Zr16Ti17 were prepared and then the ion beam mixing was carried out.It turned out that the increase of Cu content doesn't always have a positive effect on the glass forming ability.The glass forming ability of Cu49Zr24Ti27 was degraded due to the appearance of a Cs Cl-type B2 structure Cu Zr phase in the eutectic region.The experimental observations justify the existence of the Cu Zr phase under the non-equilibrium condition.Possible formation mechanisms for the crystalline phase were also discussed in terms of the atomic collision theory.

Thermodynamic description of the Mn-Si-Zn system

The experimental phase equilibria of the Mn-Si-Zn system available in the literature were critically evaluated.Thermodynamic assessment of the Mn-Si-Zn system was then performed in the framework of CALPHAD(CALculation of PHAse Diagram) method on the basis of the experimental data in the literature.The optimal thermodynamic parameters of the ternary system were then obtained,yielding a good agreement with most of the experimental data.The complete liquidus projection and reaction scheme was also presented for the Mn-Si-Zn system.It is noteworthy that a stable closed liquid miscibility gap appears in the computed ternary phase diagrams,even though it is metastable in three boundary binaries.The occurrence of such a closed miscibility gap can be predicted by a criterion considering the general thermodynamic rules and the features of the three constituent binary systems.

Image reconstruction of a neutron scatter camera

Recently, Sandia Laboratories developed a neutron scatter camera to detect special nuclear materials. This camera exhibits the following advantages: high efficiency, direction discrimination, neutron-gamma discrimination ability, and wide field of view. However, using the direct projection method, the angular resolution of this camera is limited by uncertainties in the energies estimated from pulse height and time of flight measurements. In this study, we established an eight-element neutron scatter camera and conducted the experiment with a ^(252)Cf neutron source. The results show that it has an angular resolution better than 8°(1s) and a detection efficiency of approximately 2.6′10-4. Using maximum likelihood expectation maximization method, the image artifact was eliminated, and the angular resolution was improved. We proposed an average scattering angle method to estimate the scattering energy of neutrons and Compton gamma rays. As such, we can obtain a recognizable image and energy spectrum of the source with some degradation of energy and image resolutions. Finally, a newly measured light response function based on the MPD^(-4) device was used for image reconstruction. Although we did not obtain a better result than that of the standard light response function, we have observed the effects of light response function on image reconstruction.

Experimental and numerical investigation of failure mode in geometrically imperfect DP590 steel

Various microstructure-level finite element models were generated according to the real microstructure of DP590 steel to capture the mechanical behavior and fracture mode.The failure mode of the dual-phase(DP)steels,mainly resulting from microstructure-level inhomogeneity and initial geometrical imperfection,was predicted using the plastic strain localization theory.In addition,dog-bone-type tensile test specimens with different edge qualities were prepared and the deformation processes were recorded using a digital image correlation system.When the steel exhibited no initial geometrical imperfection,void initiation was triggered by decohesion between martensite and ferrite which was predicted based on the severe strain concentration,or tensile stress in areas where stress triaxiality and strain values were high.Final failure was caused by shear localization in the vicinity.Moreover,the initial geometrical imperfections severely affected the overall ductility and failure mode of the DP590steel.When initial geometrical imperfections were deeply ingrained,an incipient crack began at the site of initial geometrical imperfection,and then caused progressive damage throughout the microstructure,from the area of shear localization to the final fracture.Overall,the depth of the geometrical imperfection was the critical factor in determining whether internal decohesion or a local crack plays a dominant role.