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受阻酚类抗氧剂与聚乙烯树脂的相容作用研究 被引量:4
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作者 王俊 史春霞 +1 位作者 李翠勤 陈帅 《石油化工高等学校学报》 CAS 2011年第4期21-25,共5页
同时采用质量增重法和傅里叶红外光谱法(FT-IR)定量和定性研究了4种常用受阻酚类抗氧剂与PE(7047)树脂的相容作用,结果表明,高温时受阻酚类抗氧剂与PE的相容作用平稳性较差,而浓度对4种受阻酚类抗氧剂与PE的相容作用影响较小。4种抗氧... 同时采用质量增重法和傅里叶红外光谱法(FT-IR)定量和定性研究了4种常用受阻酚类抗氧剂与PE(7047)树脂的相容作用,结果表明,高温时受阻酚类抗氧剂与PE的相容作用平稳性较差,而浓度对4种受阻酚类抗氧剂与PE的相容作用影响较小。4种抗氧剂在添加量范围内与PE树脂均具有良好的相容性,且以BHT最优,其次为抗氧剂1098和1076,最后为抗氧剂1010,并简要探讨了分子结构对相容作用的影响。 展开更多
关键词 受阻酚类抗氧剂 聚乙烯 相容作用
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相容剂对CR/PVC热塑性弹性体的相容作用 被引量:3
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作者 杜爱华 张国年 +1 位作者 孟宪德 纪奎江 《橡胶工业》 CAS 北大核心 2001年第2期75-79,共5页
研究了相容剂NBR和Elvaloy 741对CR/PVC共混物 (共混比 70 / 30 )性能的影响 ,并通过透射电镜和红外光谱表征了相容剂NBR和Elvaloy 741对CR/PVC共混物的相容效果。结果表明 ,相容剂Elvaloy 741与CR和PVC之间有较强的相互作用 ,相容剂NBR... 研究了相容剂NBR和Elvaloy 741对CR/PVC共混物 (共混比 70 / 30 )性能的影响 ,并通过透射电镜和红外光谱表征了相容剂NBR和Elvaloy 741对CR/PVC共混物的相容效果。结果表明 ,相容剂Elvaloy 741与CR和PVC之间有较强的相互作用 ,相容剂NBR和Elvaloy 741加入CR/PVC共混物中 ,使分散相尺寸变小 ;当相容剂用量为CR/PVC共混物中PVC用量的 10 %时 。 展开更多
关键词 相容 CR PVC 热塑性弹性体 相容作用 聚氯乙烯
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离聚体及其相容作用
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作者 林春雷 《中山大学研究生学刊(自然科学与医学版)》 1997年第4期43-47,共5页
本文阐述了离聚体的合成、结构、性质,以及离聚体在共混体系中的相容作用;综述了离聚体相容剂的研究进展。
关键词 离聚体 相容作用
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动态流变行为在三元乙丙橡胶/硅橡胶共混物形态结构研究中的应用
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作者 陈大鹏 王灿 +2 位作者 熊其鹏 罗权焜 吴叔青 《合成橡胶工业》 CAS 2024年第1期22-28,共7页
利用开放式炼胶机制备了三元乙丙橡胶(EPDM)与硅橡胶(SR)混炼胶和单相硫化硅橡胶(v-SR)的共混胶,通过流变行为研究了组成比例、界面交联作用等对共混体系形态结构的影响,并采用扫描电子显微镜和两相剥离强度对形态结构的研究结果进行了... 利用开放式炼胶机制备了三元乙丙橡胶(EPDM)与硅橡胶(SR)混炼胶和单相硫化硅橡胶(v-SR)的共混胶,通过流变行为研究了组成比例、界面交联作用等对共混体系形态结构的影响,并采用扫描电子显微镜和两相剥离强度对形态结构的研究结果进行了验证。结果表明,动态流变行为成功预测了高黏度聚合物复合体系的形态结构。共混物中EPDM的用量在30~70份(质量,下同)时,EPDM/SR混炼胶的形态呈双相连续结构。用超过1份的过氧化物交联剂对EPDM用量为70份的EPDM/SR混炼胶中的SR进行单相交联,v-SR的连续结构发生了融合,转变成颗粒状结构,且颗粒结构的相畴随着交联剂用量的增加而增大,而高剂量的交联剂可以使两相形成共交联。 展开更多
关键词 三元乙丙橡胶 硅橡胶 共混物 动态流变行为 形态结构 界面交联作用 界面相容作用
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马来酸酐改性腰果壳油对丁苯橡胶性能的影响 被引量:1
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作者 王舒婷 陈福林 +3 位作者 龚湛林 刘玄 岑兰 周彦豪 《橡胶工业》 CAS 北大核心 2014年第11期666-670,共5页
以马来酸酐接枝共聚改性环氧基腰果壳油(M-CNSL)作为反应性增塑剂,研究M-CNSL用量对丁苯橡胶(SBR)硫化特性、物理性能和耐热空气老化性能的影响,并与芳烃油和未改性腰果壳油(CNSL)进行对比试验.结果表明:不同增塑剂对SBR的增塑... 以马来酸酐接枝共聚改性环氧基腰果壳油(M-CNSL)作为反应性增塑剂,研究M-CNSL用量对丁苯橡胶(SBR)硫化特性、物理性能和耐热空气老化性能的影响,并与芳烃油和未改性腰果壳油(CNSL)进行对比试验.结果表明:不同增塑剂对SBR的增塑作用从大到小依次为CNSL、芳烃油、M-CNSL,而其硫化胶的耐热空气老化性能没有明显差别;加入CNSL的SBR胶料焦烧时间和正硫化时间显著延长,硫化胶硬度、100%定伸应力较小,拉断伸长率较大;在0~25份用量范围内,添加CNSL或M-CNSL的硫化胶拉伸强度和撕裂强度均出现一个最大值,而添加芳烃油的硫化胶拉伸强度和撕裂强度随着增塑剂用量的增大而减小.硫化胶拉伸断面扫描电镜分析结果表明,M-CNSL的加入有利于白炭黑在胶料中的分散,起到了相容作用. 展开更多
关键词 丁苯橡胶 腰果壳油 芳烃油 马来酸酐 接枝共聚 相容作用
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Excess Molar Volume, Viscosity and Heat Capacity for the Binary Mixture of p-Xylene and Acetic Acid at Different Temperatures 被引量:1
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作者 杨长生 马沛生 +2 位作者 唐多强 尹秋响 赵长伟 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第5期604-609,共6页
Experimental densities, viscosities and heat capacities atdifferent temperatures were presented over the entire range of molefraction for the binary mixture of p-xylene and acetic acid. Densityvalues were used in the ... Experimental densities, viscosities and heat capacities atdifferent temperatures were presented over the entire range of molefraction for the binary mixture of p-xylene and acetic acid. Densityvalues were used in the determination of excess molar volumes, V^E.At the same time, the excess viscosity and excess molar heatcapacities were calculated. The values of V^E, η~E and c^E_p werefitted to the Redlich-Kister equation. Good agreements were observed.The excess molar volumes are positive with a large maximum valuelocated in the central concentration range. 展开更多
关键词 VISCOSITY heat capacity DENSITY excess molar volume
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Corporate Behavior Theory on Stakeholder Harmonious Corporate Governance
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作者 Guizhen Yang SHunzhong Xia Li Liu 《International English Education Research》 2015年第9期42-45,共4页
Corporate governance is the focus of all stakeholders in the balance of contradictions and conflicts in the view of corporatc behavior theory, harmonious governance may be the development direction of future corporate... Corporate governance is the focus of all stakeholders in the balance of contradictions and conflicts in the view of corporatc behavior theory, harmonious governance may be the development direction of future corporate governance. The article explains the framework of harmonious governance based on the theory of corporate behavior, and holds that shareholder value and stakeholder value is as important as, combination of incentive-compatible and mutually compatible, interaction between market governance and relationship governance, is a major innovation path of harmonious corporate governance by stakeholders. 展开更多
关键词 corporate behavior STAKEHOLDER harmonious corporate governance innovation
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新型芳胺类抗氧剂与聚乙烯相容性研究
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作者 王玉如 闫义彬 +3 位作者 马立莉 牛娜 赵千 任鹤 《塑料科技》 CAS 北大核心 2020年第5期121-124,共4页
采用傅里叶红外光谱(FTIR)和氧化诱导期(OIT)对芳胺类抗氧剂与聚乙烯材料的相容作用进行研究。实验结果表明:随着温度的升高,抗氧剂与聚乙烯材料的相容量增加,其中防老剂D与聚乙烯材料的相容量增加最大。抗氧剂浓度对其与聚乙烯材料的... 采用傅里叶红外光谱(FTIR)和氧化诱导期(OIT)对芳胺类抗氧剂与聚乙烯材料的相容作用进行研究。实验结果表明:随着温度的升高,抗氧剂与聚乙烯材料的相容量增加,其中防老剂D与聚乙烯材料的相容量增加最大。抗氧剂浓度对其与聚乙烯材料的相容作用几乎无影响。随着实验时间的延长,抗氧剂与聚乙烯材料的相容量增加,其中新型芳胺抗氧剂的相容速率最慢,但相容性最好。 展开更多
关键词 芳胺抗氧剂 聚乙烯 相容作用
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Experimental study on the adhesion, migration and three-dimensional growth of Schwann cells on absorbable biological materials 被引量:4
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作者 王光林 林卫 +2 位作者 杨志明 裴福兴 刘雷 《Chinese Journal of Traumatology》 CAS 2003年第4期209-212,共4页
OBJECTIVE: To study the adhesion, migration and three-dimentional growth of Schwann cells on PLA (polylactic acid) nonspinning fibre cloth and polyglycolic/polylactic acid (PLGA) fibres. METHODS: Schwann cells/ECM gel... OBJECTIVE: To study the adhesion, migration and three-dimentional growth of Schwann cells on PLA (polylactic acid) nonspinning fibre cloth and polyglycolic/polylactic acid (PLGA) fibres. METHODS: Schwann cells/ECM gel solution and PLA nonspinning fibre cloth and PLGA fibres pretreated by collagen, polylysine and ECM were co-cultured. Then the migration and three-dimensional growth of Schwann cells on the fibres were observed under phase contrast microscope and laser scanning confocal microscope. RESULTS: Schwann cell/ECM solution was compounded with PLA nonspinning fibre cloth. With formation of gel, most Schwann cells resided in the fibre net holes, and adhered to the fibres to form a multiplayer-arranged Schwann cell column like Bungner band. Schwann cells could adhere to PLGA fibres and grew and migrated along the fibres. ECM gel could significantly increase the adhering and migrating cell number. CONCLUSIONS: ECM gel can facilitate the adhesion, growth and migration of Schwann cells on the seteroframe. It is a good integrating material for tissue engineering bioartificial nerve. 展开更多
关键词 Tissue Engineering Cell Adhesion Cell Division Cell Movement Humans Lactic Acid Polyglycolic Acid Polymers Research Support Non-U.S. Gov't Schwann Cells
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Electron-electron interactions in monolayer graphene quantum capacitors 被引量:1
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作者 Xiaolong Chen Lin Wang Wei Li Yang Wang Zefei Wu Mingwei Zhang Yu Han Yuheng He Ning Wang 《Nano Research》 SCIE EI CAS CSCD 2013年第8期619-626,共8页
We demonstrate the effects of electron-electron (e-e) interactions in monolayer graphene quantum capacitors. Ultrathin yttrium oxide showed excellent per-formance as the dielectric layer in top-gate device geometry.... We demonstrate the effects of electron-electron (e-e) interactions in monolayer graphene quantum capacitors. Ultrathin yttrium oxide showed excellent per-formance as the dielectric layer in top-gate device geometry. The structure and dielectric constant of the yttrium oxide layers have been carefully studied. The inverse compressibility retrieved from the quantum capacitance agreed fairly well with the theoretical predictions for the e--e interactions in monolayer graphene at different temperatures. We found that electron-hole puddles played a significant role in the low-density carrier region in graphene. By considering the temperature-dependent charge fluctuation, we established a model to explain the round-off effect originating from the e-e interactions in monolayer graphene near the Dirac point. 展开更多
关键词 GRAPHENE e-e interaction inverse compressibility quantum capacitance charge fluctuation electron-hole puddles
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Chiral polymer-based biointerface materials 被引量:2
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作者 LI MinMin QING GuangYan +1 位作者 ZHANG MingXi SUN TaoLei 《Science China Chemistry》 SCIE EI CAS 2014年第4期540-551,共12页
Chirality is a unique phenomenon in nature. Chiral interactions play an important role in biological and physiological process- es, which provides much inspiration for scientists to develop cbiral materials. As a brea... Chirality is a unique phenomenon in nature. Chiral interactions play an important role in biological and physiological process- es, which provides much inspiration for scientists to develop cbiral materials. As a breakthrough from traditional materials, bi- ointerface materials based on chiral polymers have attracted increasing interest over the past few years. Such materials ele- gantly combine the advantages of chiral surfaces and traditional polymers, and provide a novel solution not only for the inves- tigation of chiral interaction mechanisms but also for the design of biomaterials with diverse applications, such as in tissue en- gineering and biocompatible materials, bioregulation, chiral separation and chiral sensors. Herein, we summarize recent ad- vances in the study of chiral effects and applications of chiral polymer-based biointerface materials, and also present some challenges and perspectives. 展开更多
关键词 CHIRALITY POLYMER chiral interaction biointerface materials chiral effects applications
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Mesoporous silica nanoparticles-assisted ruthenium(Ⅱ) complexes for live cell staining 被引量:2
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作者 Jia Wen Hui Yan +3 位作者 Pengyi Xia Yongqian Xu Hongjuan Li Shiguo Sun 《Science China Chemistry》 SCIE EI CAS CSCD 2017年第6期799-805,共7页
Ruthenium complexes which can bind to DNA via electrostatic and intercalation interactions producing strong luminescence have become ideal candidates for DNA staining. However, some of them such as Ru(phen)_3Cl_2 and ... Ruthenium complexes which can bind to DNA via electrostatic and intercalation interactions producing strong luminescence have become ideal candidates for DNA staining. However, some of them such as Ru(phen)_3Cl_2 and Ru(phen)_2(dppz)Cl_2 could hardly cross the cellular membrane of live cells which limited their further interaction with DNA in live cells. To solve this problem, a potential approach is to find a proper vehicle for loading and delivery of these ruthenium complexes into live cells.Mesoporous silica nanoparticles(MSNs) with non-toxicity and good biocompatibility can be good candidates. More importantly,ruthenium complexes with positively charge could be loaded on negatively charged MSNs via electrostatic attractions to form MSNs-Ru hybrid. In vitro test demonstrated that MSNs had no side effects on the interactions between Ru complexes and DNA.Furthermore, it is found that the MSNs-Ru hybrid can enter into living human cervical cancer cells HeLa and stain the DNA while the corresponding ruthenium complexes alone could hardly cross the cellular membrane in the control experiment, demonstrating MSNs can be employed to be an efficient ruthenium complexes delivery nanomaterial for live cell staining. 展开更多
关键词 ruthenium complexes mesoporous silica DNA imaging
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Inter-signal interaction and uncertain information in anuran multimodal signals 被引量:2
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作者 Ryan C. TAYLOR Barrett A. KLEIN Michael J. RYAN 《Current Zoology》 SCIE CAS CSCD 北大核心 2011年第2期153-161,共9页
Disentangling the influence of multiple signal components on receivers and elucidating general processes influencing complex signal evolution are difficult tasks. In this study we test mate preferences of female squir... Disentangling the influence of multiple signal components on receivers and elucidating general processes influencing complex signal evolution are difficult tasks. In this study we test mate preferences of female squirrel treefrogs Hyla squirella and female tungara frogs Physalaemus pustulosus for similar combinations of acoustic and visual components of their multimodal courtship signals. In a two-choice playback experiment with squirrel treefrogs, the visual stimulus of a male model significantly increased the attractivness of a relatively unattractive slow call rate. A previous study demonstrated that faster call rates are more attractive to female squirrel treefrogs, and all else being equal, models of male frogs with large body stripes are more attractive. In a similar experiment with female tungara frogs, the visual stimulus of a robotic frog failed to increase the attractiveness of a relatively unattractive call. Females also showed no preference for the distinct stripe on the robot that males commonly bear on their throat. Thus, features of conspicuous signal components such as body stripes are not universally important and signal function is likely to differ even among species with similar ecologies and communication systems. Finally, we discuss the putative information content of anuran signals and suggest that the categorization of redundant versus multiple messages may not be sufficient as a general explanation for the evolution of multimodal signaling. Instead of relying on untested assumptions concerning the information content of signals, we discuss the value of initially collecting comparative empirical data sets related to receiver responses. 展开更多
关键词 Inter-signal interaction Multimodal signaling Signal detection Signal weighting Squirrel treefrog Hyla squirella Tfingara frog Physalaemus pustulosus Vocal sac
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