A three dimensional numerical model of nonlinear wave action on a quasi-ellipse caisson in a time domain was developed in this paper. Navier-Stokes equations were solved by the finite difference method, and the volume...A three dimensional numerical model of nonlinear wave action on a quasi-ellipse caisson in a time domain was developed in this paper. Navier-Stokes equations were solved by the finite difference method, and the volume of fluid （VOF） method was employed to trace the free surface. The partial cell method was used to deal with the irregular boundary typical of this type of problem during first-time wave interaction with the structure, and a satisfactory result was obtained. The numerical model was verified and used to investigate the effects of the relative wave height H/d, relative caisson width kD, and relative length-width ratio B/D on the wave forces of the quasi-ellipse caisson. It was shown that the relative wave height H/d has a significant effect on the wave forces of the caisson. Compared with the non-dimensional inline wave force, the relative length-width ratio BID was shown to have significant influence on the non-dimensional transverse wave force.展开更多
A novel method for on-site determination of trace iron was developed using membrane preconcentration and spectrophotometric detection. Fe（II）-ferrozine complex was reacted with cetyltrimethylammonium bromide （CTAB...A novel method for on-site determination of trace iron was developed using membrane preconcentration and spectrophotometric detection. Fe（II）-ferrozine complex was reacted with cetyltrimethylammonium bromide （CTAB） to form a Fe（II）-ferrozine-CTAB paired compound, which was collected on a membrane by filtration under vacuum. The membrane was immersed in 2 mL of ethanol-nitric acid and the absorbance of the solution measured for quantitative analysis. Various factors affecting the iron collection and determination were investigated. With different sample preconcentration volumes, the range of determination was broadened to 0.5-120 ~tg/L. The detection limit of this method reached 0.19 ktg/L and the recoveries were between 97.2 and 109% when the concentration enrichment was about 45. The relative standard deviation （n = 7） was 1.9% for samples containing 10 ~g/L Fe. Twelve seawater samples were analyzed on-site using the proposed method, and two were also analyzed in inductively coupled plasma mass spectrometry. No significant difference was shown between the two methods by the Student＇s t-test. The method has also been used on-site for iron enrichment experiments with phytoplankton and concluded to be simple, accurate and inexpensive.展开更多
With the increasing researches on geotechnical properties of the diesel contaminated soil( DCS),the water content measured is indispensable part during the early period. In this study,the relative error of water conte...With the increasing researches on geotechnical properties of the diesel contaminated soil( DCS),the water content measured is indispensable part during the early period. In this study,the relative error of water content measurement using the traditional method is as high as 20. 78%,which is no longer suitable for contaminated soil. Through a series of tests to measure the loss coefficient of diesel in the drying time,the authors finally proposed a modified calculation formula for test samples. The results show that the maximum relative error calculated by using the modified formula is 0. 96%,far lower than that of traditional formula,which can provide accurate data for further study of diesel contaminated soil.展开更多
基金Supported by the Science and Technology Program on Transportation Construction in Western China Ministry of Communications under Grant No.2004-328-832-51
文摘A three dimensional numerical model of nonlinear wave action on a quasi-ellipse caisson in a time domain was developed in this paper. Navier-Stokes equations were solved by the finite difference method, and the volume of fluid （VOF） method was employed to trace the free surface. The partial cell method was used to deal with the irregular boundary typical of this type of problem during first-time wave interaction with the structure, and a satisfactory result was obtained. The numerical model was verified and used to investigate the effects of the relative wave height H/d, relative caisson width kD, and relative length-width ratio B/D on the wave forces of the quasi-ellipse caisson. It was shown that the relative wave height H/d has a significant effect on the wave forces of the caisson. Compared with the non-dimensional inline wave force, the relative length-width ratio BID was shown to have significant influence on the non-dimensional transverse wave force.
基金Supported by State Key Laboratory of Marine Environmental Science(MEL)Funds(No.MELRI1001)
文摘A novel method for on-site determination of trace iron was developed using membrane preconcentration and spectrophotometric detection. Fe（II）-ferrozine complex was reacted with cetyltrimethylammonium bromide （CTAB） to form a Fe（II）-ferrozine-CTAB paired compound, which was collected on a membrane by filtration under vacuum. The membrane was immersed in 2 mL of ethanol-nitric acid and the absorbance of the solution measured for quantitative analysis. Various factors affecting the iron collection and determination were investigated. With different sample preconcentration volumes, the range of determination was broadened to 0.5-120 ~tg/L. The detection limit of this method reached 0.19 ktg/L and the recoveries were between 97.2 and 109% when the concentration enrichment was about 45. The relative standard deviation （n = 7） was 1.9% for samples containing 10 ~g/L Fe. Twelve seawater samples were analyzed on-site using the proposed method, and two were also analyzed in inductively coupled plasma mass spectrometry. No significant difference was shown between the two methods by the Student＇s t-test. The method has also been used on-site for iron enrichment experiments with phytoplankton and concluded to be simple, accurate and inexpensive.
文摘With the increasing researches on geotechnical properties of the diesel contaminated soil( DCS),the water content measured is indispensable part during the early period. In this study,the relative error of water content measurement using the traditional method is as high as 20. 78%,which is no longer suitable for contaminated soil. Through a series of tests to measure the loss coefficient of diesel in the drying time,the authors finally proposed a modified calculation formula for test samples. The results show that the maximum relative error calculated by using the modified formula is 0. 96%,far lower than that of traditional formula,which can provide accurate data for further study of diesel contaminated soil.
