By pot experiment under artificially simulated water stress conditions, soluble protein content, MDA content and SOD, POD, CAT and APX activities in Malus sieversfi leaves were determined to reveal the response mechan...By pot experiment under artificially simulated water stress conditions, soluble protein content, MDA content and SOD, POD, CAT and APX activities in Malus sieversfi leaves were determined to reveal the response mechanism of M. sieversii to changes of relative soil water content. According to the results, with the decrease of relative soil water content, MDA content in M. sieversii leaves increased by mem- brane lipid peroxidation. Cells resist water stress-induced membrane lipid peroxidation and clear the increased reactive oxygen species by improving soluble protein content and SOD, POD, CAT and APX activities. However, various enzymes were involved in the response to water stress under different moisture conditions. In addition, the results indicated that M. sieversii had a good adaptability to higher relative soil water contents.展开更多
Low lying excited states of beryllium are calculated with multiconfiguration interaction method. The relativisitic corrections and mass polarization are included. The oscillator strength and radiation rates are also ...Low lying excited states of beryllium are calculated with multiconfiguration interaction method. The relativisitic corrections and mass polarization are included. The oscillator strength and radiation rates are also calculated. Our results are in good agreement with other theoretical data.展开更多
The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c r...The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c ratio) during early and later hydration stages. From the water distribution spectrum deduced from relaxation time distribution in paste, it is suggested that the water fills in the capillary pores at initial period, and then diffuses to the mesopores and gel pores in hydration products with the hydration proceeding. The decrease of peak area in water distribution spectrum reflects the transformation from physically bound water to chemically bound water. In addition, based on the connection between relaxation time and pore size, the relative content changes of water in various states and constrained in different types of pores were also measured. The results demonstrate that it is influenced by the formation of pore system and the original water-to-cement ratio in the paste. Consequently, the relative content of capillary water is dropped to less than 2% in the paste with low w/c ratio of 0.3 when being hydrated for 1 d, while the contents are still 16% and 36% in the pastes with w/c ratios of 0.4 and 0.5, respectively.展开更多
A laboratory reactor was designed to test the effect of the interference instant of HY on the pyrolysis of pubescens.The time instant for intermediate species from pyrolysis to contact HY was controlled by varying the...A laboratory reactor was designed to test the effect of the interference instant of HY on the pyrolysis of pubescens.The time instant for intermediate species from pyrolysis to contact HY was controlled by varying the position of the catalyst bed relative to the pyrolytic cell.It was found that the effect of the interference instant was significant on the variation of different intermediate species,and the yield and quality of the products.The results also showed that,with the increase in the distance between the pyrolytic cell and the catalyst bed,the yield of liquid and relative content of the organics such as aldehyde,phenols,etc.,decreased,while the yield of residue and relative content of acetic acid increased.The deoxygenation of the intermediate species was favored when the catalyst exerted its performance on them immediately after their formation.展开更多
Three polysaccharides (EW, EH and EA) were prepared from a red alga Eucheuma denticulatum by sequential extraction with cold water, hot water and sodium hydroxide water solution. Their monosaccharide compositions, r...Three polysaccharides (EW, EH and EA) were prepared from a red alga Eucheuma denticulatum by sequential extraction with cold water, hot water and sodium hydroxide water solution. Their monosaccharide compositions, relative molecular mass and structural characterization were determined by gas chromatography, high performance liquid chromatography, fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy methods. EW was hybrid l/k/v-carrageenan (701/17k/13v-car- rabiose), EH was mainly t-carrageenan, and EA was mainly α-1,4-Glucan (88%) but mixed with small amount of t-carrageenan (12%). The relative molecular mass ofEW, EH and EA was 480, 580 and 510kDa, respectively. The anti-influenza A (H1N1) virus activity of these three polysaccharides was evaluated using the Madin-Darby canine kidney cells model. EW showed good anti-H1N1 virus activity, its ICso was 276.5 μg mL-1, and the inhibition rate to H1N1 virus was 52% when its concentration was 250 μgmL-1. The ICs0 of t-carrageenan EH was 366.4 μgmL1, whereas EA showed lower anti-H1N1 virus activity (IC50〉430μgmL-1). Available data obtained give positive evidence that the hybrid carrageenan EW from Eueheuma denticulatum can be used as potential anti-H1N1 virus inhibitor in future.展开更多
Perfluorolyether is characterized by highly chemical inertness, oxidative stability, anticorrosion as well as radiation resistance. It can be used as lubricant especially in harsh environmental conditions. In this wor...Perfluorolyether is characterized by highly chemical inertness, oxidative stability, anticorrosion as well as radiation resistance. It can be used as lubricant especially in harsh environmental conditions. In this work, hexafluoropylene oxide was catalytically polymerized at low temperature using the methods of anionic polymerization, and perfluorolyethers were obtained with number-average degree of polymerization more than 15. CsF and RbF were used as catalysts and their catalytic activities were investigated. Experimental results show that perfluorolyethers with number-average molar masses up to 3 000 g/mol could be obtained using the two kinds of catalysts, respectively. As compared to CsF, the number-average degree of polymerization is higher and the relative molecular mass distribution interval is narrower when RbF is used as catalyst. The effect of factors such as impurities' content, reaction temperature and reaction time on the number-average degree of polymerization was also investigated. It is found that low impurities' content and low temperature are beneficial to the generation of high number-average degree of perfluorolyethers. The optimization reaction time is 24 h, and fiarther increase of reaction time does not significantly affect the average relative molecular mass. The product was characterized by IR, 19F NMR and GC-MS, and the catalytic mechanism was analyzed finally.展开更多
Comparing the relativistic and nonrelativistic frame works, we study the effect of the relativistic center-of-mass vector on the electric polarizability of a compound system.
We estimate the correction of relativistic center-of-mass vector on electric polarizability of an equal-mass quark-antiquark system numerically. Effect on the system confined by different interactive potentials is ana...We estimate the correction of relativistic center-of-mass vector on electric polarizability of an equal-mass quark-antiquark system numerically. Effect on the system confined by different interactive potentials is analysed. A great improvement for the electric polarizability of pion meson is obtained.展开更多
The present study was conducted to evaluate the effects of partial root-zone drying (PRD) irrigation technique on stomatal conductance (gs), leaf water potential (qJpd), leaf relative water content (RWC), vege...The present study was conducted to evaluate the effects of partial root-zone drying (PRD) irrigation technique on stomatal conductance (gs), leaf water potential (qJpd), leaf relative water content (RWC), vegetative growth, fruit quality and enzymatic antioxidants of young plants of four Olea europaea L. varieties (Picholine Marocaine, Haouzia, Picholine Languedoc and Manzanilla) grown under arid conditions in Southern Morocco. In this irrigation strategy, a split-root technique was used to divide the root system of the plants in two parts. Two water regimes were used: (1) control, with both root compartments well watered; (2) PRD, with one compartment irrigated (50% of the control), the other compartment was kept dry switching every 10 days. For all olive varieties studied, gs and the shoot length of the plants subjected to PRD decreased, whereas, Woo and RWC remained higher. The effect of PRD was similar among the four olive varieties, with their stomata closing in response to the water deficit before any significant changes in leaf water status were detectable. At the agronomic level, the benefits of PRD on olive were expressed by an earlier maturity and by higher values of olive fruit weight and dimensions, especially, in Manzanilla, which produced a fruit reaching 7.1 g and 2.6 cm, respectively. The enzymatic activities of soluble peroxidases (POX), insoluble peroxidases (POXins), polyphenoloxidase (PPO) and superoxide dismutase (SOD) were up-regulated under PRD. Picholine Marocaine and Haouzia showed higher enzymatic activities revealing that in these two varieties, PRD had possibly induced oxidative stress, which resulted in an up-regulation of the antioxidant activities of POXins, POX, PPO and SOD under water deficit.展开更多
The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full fac...The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO par- ticle formation using scCO2. The solubility of RPO was 0.5-11.3 mg. (g CO2) -1 and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi-Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R2 of 0.9667, whereas the Peng-Robinson equation of state thermodynamic model recorded deviations of 17%-30%.展开更多
基金Supported by Science and Technology Innovation Project of Ji'nan City "Identification of Stress-resistant Malus sieversii Germplasm Resources and Screening of Stressresistance Functional Genes"(201401125)~~
文摘By pot experiment under artificially simulated water stress conditions, soluble protein content, MDA content and SOD, POD, CAT and APX activities in Malus sieversfi leaves were determined to reveal the response mechanism of M. sieversii to changes of relative soil water content. According to the results, with the decrease of relative soil water content, MDA content in M. sieversii leaves increased by mem- brane lipid peroxidation. Cells resist water stress-induced membrane lipid peroxidation and clear the increased reactive oxygen species by improving soluble protein content and SOD, POD, CAT and APX activities. However, various enzymes were involved in the response to water stress under different moisture conditions. In addition, the results indicated that M. sieversii had a good adaptability to higher relative soil water contents.
文摘Low lying excited states of beryllium are calculated with multiconfiguration interaction method. The relativisitic corrections and mass polarization are included. The oscillator strength and radiation rates are also calculated. Our results are in good agreement with other theoretical data.
基金Project(2009CB623105) supported by the National Basic Research Program of ChinaProject(51108341) supported by the National Natural Science Foundation of ChinaProjects(20110490703, 2012T50437) supported by China Postdoctoral Science Foundation
文摘The low field nuclear magnetic resonance (NMR), as a nondestructive and noninvasive technique, was employed to investigate the water distribution and content in cement paste with different water-to-cement ratio (w/c ratio) during early and later hydration stages. From the water distribution spectrum deduced from relaxation time distribution in paste, it is suggested that the water fills in the capillary pores at initial period, and then diffuses to the mesopores and gel pores in hydration products with the hydration proceeding. The decrease of peak area in water distribution spectrum reflects the transformation from physically bound water to chemically bound water. In addition, based on the connection between relaxation time and pore size, the relative content changes of water in various states and constrained in different types of pores were also measured. The results demonstrate that it is influenced by the formation of pore system and the original water-to-cement ratio in the paste. Consequently, the relative content of capillary water is dropped to less than 2% in the paste with low w/c ratio of 0.3 when being hydrated for 1 d, while the contents are still 16% and 36% in the pastes with w/c ratios of 0.4 and 0.5, respectively.
基金Supported by the State Key Development Program for Basic Research of China(2007CB210203)the Special Research Fund for the Doctoral Program of Higher Education of China(20050610013)
文摘A laboratory reactor was designed to test the effect of the interference instant of HY on the pyrolysis of pubescens.The time instant for intermediate species from pyrolysis to contact HY was controlled by varying the position of the catalyst bed relative to the pyrolytic cell.It was found that the effect of the interference instant was significant on the variation of different intermediate species,and the yield and quality of the products.The results also showed that,with the increase in the distance between the pyrolytic cell and the catalyst bed,the yield of liquid and relative content of the organics such as aldehyde,phenols,etc.,decreased,while the yield of residue and relative content of acetic acid increased.The deoxygenation of the intermediate species was favored when the catalyst exerted its performance on them immediately after their formation.
基金supported by International Science and Technology Collaboration Program of China (2007DFA-30980)Program for Changjiang Scholars,Innovative Research Team in University (IRT0944)+1 种基金Natural Science Foundation of China (31070724)Special Fund for Marine Scientific Research in the Public Interest (201005024)
文摘Three polysaccharides (EW, EH and EA) were prepared from a red alga Eucheuma denticulatum by sequential extraction with cold water, hot water and sodium hydroxide water solution. Their monosaccharide compositions, relative molecular mass and structural characterization were determined by gas chromatography, high performance liquid chromatography, fourier transform infrared spectroscopy and nuclear magnetic resonance spectroscopy methods. EW was hybrid l/k/v-carrageenan (701/17k/13v-car- rabiose), EH was mainly t-carrageenan, and EA was mainly α-1,4-Glucan (88%) but mixed with small amount of t-carrageenan (12%). The relative molecular mass ofEW, EH and EA was 480, 580 and 510kDa, respectively. The anti-influenza A (H1N1) virus activity of these three polysaccharides was evaluated using the Madin-Darby canine kidney cells model. EW showed good anti-H1N1 virus activity, its ICso was 276.5 μg mL-1, and the inhibition rate to H1N1 virus was 52% when its concentration was 250 μgmL-1. The ICs0 of t-carrageenan EH was 366.4 μgmL1, whereas EA showed lower anti-H1N1 virus activity (IC50〉430μgmL-1). Available data obtained give positive evidence that the hybrid carrageenan EW from Eueheuma denticulatum can be used as potential anti-H1N1 virus inhibitor in future.
基金Project(53110704012) supported by the Fundamental Research Funds for the Central Universities,China
文摘Perfluorolyether is characterized by highly chemical inertness, oxidative stability, anticorrosion as well as radiation resistance. It can be used as lubricant especially in harsh environmental conditions. In this work, hexafluoropylene oxide was catalytically polymerized at low temperature using the methods of anionic polymerization, and perfluorolyethers were obtained with number-average degree of polymerization more than 15. CsF and RbF were used as catalysts and their catalytic activities were investigated. Experimental results show that perfluorolyethers with number-average molar masses up to 3 000 g/mol could be obtained using the two kinds of catalysts, respectively. As compared to CsF, the number-average degree of polymerization is higher and the relative molecular mass distribution interval is narrower when RbF is used as catalyst. The effect of factors such as impurities' content, reaction temperature and reaction time on the number-average degree of polymerization was also investigated. It is found that low impurities' content and low temperature are beneficial to the generation of high number-average degree of perfluorolyethers. The optimization reaction time is 24 h, and fiarther increase of reaction time does not significantly affect the average relative molecular mass. The product was characterized by IR, 19F NMR and GC-MS, and the catalytic mechanism was analyzed finally.
基金The project supported by National Natural Science Foundation of China under Grant No.10075056CAS Knowledge Innovation Project No.KC2-SW-N02 of the Institute of Theoretical Physics
文摘Comparing the relativistic and nonrelativistic frame works, we study the effect of the relativistic center-of-mass vector on the electric polarizability of a compound system.
基金国家自然科学基金,the Institute of Theoretical Physics,中国科学院知识创新工程项目
文摘We estimate the correction of relativistic center-of-mass vector on electric polarizability of an equal-mass quark-antiquark system numerically. Effect on the system confined by different interactive potentials is analysed. A great improvement for the electric polarizability of pion meson is obtained.
文摘The present study was conducted to evaluate the effects of partial root-zone drying (PRD) irrigation technique on stomatal conductance (gs), leaf water potential (qJpd), leaf relative water content (RWC), vegetative growth, fruit quality and enzymatic antioxidants of young plants of four Olea europaea L. varieties (Picholine Marocaine, Haouzia, Picholine Languedoc and Manzanilla) grown under arid conditions in Southern Morocco. In this irrigation strategy, a split-root technique was used to divide the root system of the plants in two parts. Two water regimes were used: (1) control, with both root compartments well watered; (2) PRD, with one compartment irrigated (50% of the control), the other compartment was kept dry switching every 10 days. For all olive varieties studied, gs and the shoot length of the plants subjected to PRD decreased, whereas, Woo and RWC remained higher. The effect of PRD was similar among the four olive varieties, with their stomata closing in response to the water deficit before any significant changes in leaf water status were detectable. At the agronomic level, the benefits of PRD on olive were expressed by an earlier maturity and by higher values of olive fruit weight and dimensions, especially, in Manzanilla, which produced a fruit reaching 7.1 g and 2.6 cm, respectively. The enzymatic activities of soluble peroxidases (POX), insoluble peroxidases (POXins), polyphenoloxidase (PPO) and superoxide dismutase (SOD) were up-regulated under PRD. Picholine Marocaine and Haouzia showed higher enzymatic activities revealing that in these two varieties, PRD had possibly induced oxidative stress, which resulted in an up-regulation of the antioxidant activities of POXins, POX, PPO and SOD under water deficit.
基金supported by Geran Putra IPS(Vote No.:9469400),University Putra Malaysia
文摘The solubility of red palm oil (RPO) in supercritical carbon dioxide (scCO2) was determined using a dynamic method at 8.5-25 MPa and, 313.15-333.15 K and at a fixed scCO2 flow rate of 2.9 g. mn -1 using a full factorial design. The solubility was determined under low pressures and temperatures as a preliminary study for RPO par- ticle formation using scCO2. The solubility of RPO was 0.5-11.3 mg. (g CO2) -1 and was significantly affected by the pressure and temperature. RPO solubility increased with pressure and decreased with temperature. The Adachi-Lu model showed the best-fit for RPO solubility data with an average relative deviation of 14% with a high coefficient of determination, R2 of 0.9667, whereas the Peng-Robinson equation of state thermodynamic model recorded deviations of 17%-30%.