This paper presents the combined influence of heat-loss and radiation on the pyrolysis of biomass particles by considering the structure of one-dimensional, laminar and steady state flame propagation in uniformly prem...This paper presents the combined influence of heat-loss and radiation on the pyrolysis of biomass particles by considering the structure of one-dimensional, laminar and steady state flame propagation in uniformly premixed wood particles. The assumed flame structure consists of a broad preheat-vaporization zone where the rate of gas-phase chemical reaction is small, a thin reaction zone composed of three regions: gas, tar and char combustion where convection and the vaporization rate of the fuel particles are small, and a broad convection zone. The analysis is performed in the asymptotic limit, where the value of the characteristic Zeldovich number is large and the equivalence ratio is larger than unity(i.e.u≥1). The principal attention is made on the determination of a non-linear burning velocity correlation. Consequently, the impacts of radiation, heat loss and particle size as the determining factors on the flame temperature and burning velocity of biomass particles are declared in this research.展开更多
The original nonlinear chirp scaling(NCS) algorithm was extended for high precision processing of the highly squinted curvilinear trajectory synthetic aperture radar(CTSAR).Based on the analysis of slant range model a...The original nonlinear chirp scaling(NCS) algorithm was extended for high precision processing of the highly squinted curvilinear trajectory synthetic aperture radar(CTSAR).Based on the analysis of slant range model and the frequency spectrum characteristics of the echo signal,a novel nonlinear chirp scaling function and more complex phase compensation factors with both velocity and acceleration parameters were proposed in the new algorithm for accommodation to curvilinear trajectory.The processing flow and computational complexity of modified NCS algorithm were fundamentally the same as the original NCS algorithm.However,the higher order phase compensation,range cell migration correction(RCMC) and range-variant secondary range compression(SRC) caused by the non-linear aperture and the severe range-azimuth coupling were accomplished accurately and efficiently without interpolation.Simulation results show that data acquired with a curvilinear aperture and a squint angle up to about 50° for X-band can be processed with no evident degradation of impulse response function.展开更多
Second order rate constants, ka have been determined for three bi-molecular Diels-Alder reactions to demonstrate that the high viscosity of ionic liquids can be a detrimental property in carrying out Diels-Alder react...Second order rate constants, ka have been determined for three bi-molecular Diels-Alder reactions to demonstrate that the high viscosity of ionic liquids can be a detrimental property in carrying out Diels-Alder reactions, if ionic liquids are employed as solvent media. It is possible to enhance the reaction rates of the reaction if a co-solvent is mixed in pure ionic liquid used as a solvent.展开更多
文摘This paper presents the combined influence of heat-loss and radiation on the pyrolysis of biomass particles by considering the structure of one-dimensional, laminar and steady state flame propagation in uniformly premixed wood particles. The assumed flame structure consists of a broad preheat-vaporization zone where the rate of gas-phase chemical reaction is small, a thin reaction zone composed of three regions: gas, tar and char combustion where convection and the vaporization rate of the fuel particles are small, and a broad convection zone. The analysis is performed in the asymptotic limit, where the value of the characteristic Zeldovich number is large and the equivalence ratio is larger than unity(i.e.u≥1). The principal attention is made on the determination of a non-linear burning velocity correlation. Consequently, the impacts of radiation, heat loss and particle size as the determining factors on the flame temperature and burning velocity of biomass particles are declared in this research.
基金Project(61171133) supported by the National Natural Science Foundation of ChinaProject(61101182) supported by the National Natural Science Foundation for Young Scientists of ChinaProject(11JJ1010) supported by the Natural Science Foundation for Distinguished Young Scholars of Hunan Province,China
文摘The original nonlinear chirp scaling(NCS) algorithm was extended for high precision processing of the highly squinted curvilinear trajectory synthetic aperture radar(CTSAR).Based on the analysis of slant range model and the frequency spectrum characteristics of the echo signal,a novel nonlinear chirp scaling function and more complex phase compensation factors with both velocity and acceleration parameters were proposed in the new algorithm for accommodation to curvilinear trajectory.The processing flow and computational complexity of modified NCS algorithm were fundamentally the same as the original NCS algorithm.However,the higher order phase compensation,range cell migration correction(RCMC) and range-variant secondary range compression(SRC) caused by the non-linear aperture and the severe range-azimuth coupling were accomplished accurately and efficiently without interpolation.Simulation results show that data acquired with a curvilinear aperture and a squint angle up to about 50° for X-band can be processed with no evident degradation of impulse response function.
文摘Second order rate constants, ka have been determined for three bi-molecular Diels-Alder reactions to demonstrate that the high viscosity of ionic liquids can be a detrimental property in carrying out Diels-Alder reactions, if ionic liquids are employed as solvent media. It is possible to enhance the reaction rates of the reaction if a co-solvent is mixed in pure ionic liquid used as a solvent.
