The conversion of biomass-derived products to fine chemicals and fuels is extremely important for the utilization of renewable energy sources.Water is not only a by-product formed during the hydrogenation of biomass-d...The conversion of biomass-derived products to fine chemicals and fuels is extremely important for the utilization of renewable energy sources.Water is not only a by-product formed during the hydrogenation of biomass-derived oxygenated chemicals,but also an inexpensive and nontoxic solvent.The instability of solid catalysts for aqueous-phase reactions caused by metal leaching and the collapse of a catalyst support represents a significant challenge.In this work,various catalyst stabilization strategies including the nanospace and interfacial confinements that prevent sintering and leaching of metal nanoparticles as well as modification methods for increasing the support stability are summarized and systemically discussed.In addition,feasible approaches to designing stable and efficient heterogeneous catalysts for aqueous-phase reactions are proposed.展开更多
The adsorption state and catalytic properties of pepsin and acidic protease from microorganisms Asp. awamori and Asp. oryzae were studied in solid phase system （in presence of sorsilen, DEAE- and CM-cellulose）. Acco...The adsorption state and catalytic properties of pepsin and acidic protease from microorganisms Asp. awamori and Asp. oryzae were studied in solid phase system （in presence of sorsilen, DEAE- and CM-cellulose）. According to the results, adsorption capacity and catalytic activity of enzymes depend on the physical nature of surface groups of the solid phase. Changing the stability of enzymes in the system with solid phase is observed even the adsorption bond is less stable （in the case of DEAE- and CM-cellulose in acidic media）. Injection to the medium ethanol, surfactants, sodium chloride and changing the temperature of the incubation medium could prevent the negative effects of the solid phases. When sorsilen is used as solid phase, pepsin and acidic protease from Asp. awamori suffer from high surface inactivation. Various surfactants influence adsorption state of enzymes differently. Non-ionic surfactants （Triton X-100） prevent adsorption and restore catalytic properties of enzymes.展开更多
文摘The conversion of biomass-derived products to fine chemicals and fuels is extremely important for the utilization of renewable energy sources.Water is not only a by-product formed during the hydrogenation of biomass-derived oxygenated chemicals,but also an inexpensive and nontoxic solvent.The instability of solid catalysts for aqueous-phase reactions caused by metal leaching and the collapse of a catalyst support represents a significant challenge.In this work,various catalyst stabilization strategies including the nanospace and interfacial confinements that prevent sintering and leaching of metal nanoparticles as well as modification methods for increasing the support stability are summarized and systemically discussed.In addition,feasible approaches to designing stable and efficient heterogeneous catalysts for aqueous-phase reactions are proposed.
文摘The adsorption state and catalytic properties of pepsin and acidic protease from microorganisms Asp. awamori and Asp. oryzae were studied in solid phase system （in presence of sorsilen, DEAE- and CM-cellulose）. According to the results, adsorption capacity and catalytic activity of enzymes depend on the physical nature of surface groups of the solid phase. Changing the stability of enzymes in the system with solid phase is observed even the adsorption bond is less stable （in the case of DEAE- and CM-cellulose in acidic media）. Injection to the medium ethanol, surfactants, sodium chloride and changing the temperature of the incubation medium could prevent the negative effects of the solid phases. When sorsilen is used as solid phase, pepsin and acidic protease from Asp. awamori suffer from high surface inactivation. Various surfactants influence adsorption state of enzymes differently. Non-ionic surfactants （Triton X-100） prevent adsorption and restore catalytic properties of enzymes.
