TiAlN multilayer coatings composed of TiAl and TiAlN layers were deposited on ZL109 alloys using filtered cathodic vacuum arc(FCVA)technology.The effect of bias voltage on the microstructure and properties of the coat...TiAlN multilayer coatings composed of TiAl and TiAlN layers were deposited on ZL109 alloys using filtered cathodic vacuum arc(FCVA)technology.The effect of bias voltage on the microstructure and properties of the coating was systematically studied.The results show that the coating exhibits a multi-phase structure dominated by TiAlN phase.As the bias voltage increases,the orientation of TiAlN changes from(200)plane to(111)plane due to the increase of atomic mobility and lattice distortion.The hardness,elastic modulus and adhesion of the coating show the same trend of change,that is,first increase and then decrease.When the bias voltage is 75 V,the coating exhibits the highest hardness(~30.3 GPa),elastic modulus(~229.1 GPa),adhesion(HF 2)and the lowest wear rate(~4.44×10^(−5)mm^(3)/(N·m)).Compared with bare ZL109 alloy,the mechanical and tribological properties of TiAlN coated alloy surface can effectively be improved.展开更多
A combined process of molten salt electro-deoxidation and vacuum hot-pressing sintering was proposed to prepare AlCrFeNiTi_(x) high-entropy alloy(HEA)-TiN ceramic coating composites on low-carbon steel surfaces,where ...A combined process of molten salt electro-deoxidation and vacuum hot-pressing sintering was proposed to prepare AlCrFeNiTi_(x) high-entropy alloy(HEA)-TiN ceramic coating composites on low-carbon steel surfaces,where nitrides were introduced from BN isolater between graphite mold and HEA powders.The effect of Ti content on the microstructure,ultimate tensile strength,hardness,and wear resistance of the composites was investigated,and the bonding mechanism was elucidated.Results demonstrate that the composites have excellent hardness and wear resistance.The hardness of composites is significantly increased with the increase in Ti content.The extremely high wear resistance is attributed to the extremely high melting point and high thermal hardness of TiN,which can effectively prevent oxidation deformation of the worn surface.展开更多
基金Hunan Provincial Natural Science Foundation,China(No.2021JJ30646)Educational Commission of Hunan Province,China(No.20B579)+1 种基金the National Natural Science Foundation of China(Nos.51701172,12027813)Innovation Team of Hunan Province,China(No.2018RS3091).
文摘TiAlN multilayer coatings composed of TiAl and TiAlN layers were deposited on ZL109 alloys using filtered cathodic vacuum arc(FCVA)technology.The effect of bias voltage on the microstructure and properties of the coating was systematically studied.The results show that the coating exhibits a multi-phase structure dominated by TiAlN phase.As the bias voltage increases,the orientation of TiAlN changes from(200)plane to(111)plane due to the increase of atomic mobility and lattice distortion.The hardness,elastic modulus and adhesion of the coating show the same trend of change,that is,first increase and then decrease.When the bias voltage is 75 V,the coating exhibits the highest hardness(~30.3 GPa),elastic modulus(~229.1 GPa),adhesion(HF 2)and the lowest wear rate(~4.44×10^(−5)mm^(3)/(N·m)).Compared with bare ZL109 alloy,the mechanical and tribological properties of TiAlN coated alloy surface can effectively be improved.
基金National Natural Science Foundation of China(52174315)Youth Scholars Promotion Plan of North China University of Science and Technology(QNTJ202304)。
文摘A combined process of molten salt electro-deoxidation and vacuum hot-pressing sintering was proposed to prepare AlCrFeNiTi_(x) high-entropy alloy(HEA)-TiN ceramic coating composites on low-carbon steel surfaces,where nitrides were introduced from BN isolater between graphite mold and HEA powders.The effect of Ti content on the microstructure,ultimate tensile strength,hardness,and wear resistance of the composites was investigated,and the bonding mechanism was elucidated.Results demonstrate that the composites have excellent hardness and wear resistance.The hardness of composites is significantly increased with the increase in Ti content.The extremely high wear resistance is attributed to the extremely high melting point and high thermal hardness of TiN,which can effectively prevent oxidation deformation of the worn surface.