Based on the fluid transient theory and explosive dynamics, a new type explosive driven jet is put forward. The generator of the proposed jet system comprises an explosive power source, a dynamic cavity, a spacing blo...Based on the fluid transient theory and explosive dynamics, a new type explosive driven jet is put forward. The generator of the proposed jet system comprises an explosive power source, a dynamic cavity, a spacing block, a water storage chamber, and a rubber membrane. The dynamic explosive source of power for the jet is composed of a cartridge and a bullet. The pressure in the dynamic cavity goes up to a range from 300 MPa to 350 MPa very quickly when the bullet is emitted. Driven by such a high pressure, the speed of the jet reaches 120 m/s. The effective distance to distinguish a fire is within 40 m. The jet has the following advantages over a conventional high-pressure water jet system: 1)strong power and strong transient force produced by dynamic source; 2) the energy of the dynamical source concentrated in a small scope with very little loss; 3) extensive applicability; and 4) safe usage without sparkling and smoke.展开更多
Time-dependent density functional theory （TDDFT） and femtosecond transient absorption spectroscopy were used to investigate the photophysical properties of 2,3-dihydro-3-keto-lH- pyrido[3,2,1-kl]phenothiazine （PTZ4...Time-dependent density functional theory （TDDFT） and femtosecond transient absorption spectroscopy were used to investigate the photophysical properties of 2,3-dihydro-3-keto-lH- pyrido[3,2,1-kl]phenothiazine （PTZ4） and 3-keto-lH-pyrido[3,2,1-kl]phenothiazine （PTZ5）. The calculated results obtained from TDDFT suggest that the red-shifts of the absorption spectra of these two fluorophores in methanol are due to the formation of hydrogen-bonded complexes at the ground state. Four conformers of PTZ4 were obtained by TDDFT. The two fluorescence peaks of PTZ4 in tetrahydrofuran （THF） came from the ICT states of the four conformers. The fluorescence of PTZ4 in THF showed a dependence on the excitation wavelength because of butterfly bending. The excited state dynamics of PTZ4 in THF and methanol were obtained by transient absorption spectroscopy. The lifetime of the excited PTZ4 in methanol was 53.8 ps, and its relaxation from the LE state to the ICT state was completed within several picoseconds. The short lifetime of excited PTZ4 in methanol was due to the formation of out-of-plane model hydrogen bonds between PTZ4 and methanol at the excited state.展开更多
The excited-state double proton transfer(ESDPT)properties of 1,5-dihydroxyanthraquinone(1,5-DHAQ)in various solvents were investigated using femtosecond transient absorption spectroscopy and the DFT/TDDFT method.The s...The excited-state double proton transfer(ESDPT)properties of 1,5-dihydroxyanthraquinone(1,5-DHAQ)in various solvents were investigated using femtosecond transient absorption spectroscopy and the DFT/TDDFT method.The steady-state fluorescence spectra in toluene,tetrahydrofuran(THF)and acetonitrile(ACN)solvents presented that the solvent polarity has an effect on the position of the ESDPT fluorescence emission peak for the 1,5-DHAQ system.Transient absorption spectra show that the increasing polarity of the solvent accelerates the rate of excited state dynamics.Calculated potential energy curves analysis further verified the experimental results.The ESDPT barrier decreases gradually with the increase of solvent polarity from toluene,THF to ACN solvent.It is convinced that the increase of solvent polarity can promote the occurrence of the ESDPT dynamic processes for the 1,5-DHAQ system.This work clarifies the mechanism of the influence of solvent polarity on the ESDPT process of 1,5-DHAQ,which provides novel ideas for design and synthesis of new hydroxyanthraquinone derivatives.展开更多
In this paper,a high-efficiency aerothermoelastic analysis method based on unified hypersonic lifting surface theory is established.The method adopts a two-way coupling form that couples the structure,aerodynamic forc...In this paper,a high-efficiency aerothermoelastic analysis method based on unified hypersonic lifting surface theory is established.The method adopts a two-way coupling form that couples the structure,aerodynamic force,and aerodynamic thermo and heat conduction.The aerodynamic force is first calculated based on unified hypersonic lifting surface theory,and then the Eckert reference temperature method is used to solve the temperature field,where the transient heat conduction is solved using Fourier’s law,and the modal method is used for the aeroelastic correction.Finally,flutter is analyzed based on the p-k method.The aerothermoelastic behavior of a typical hypersonic low-aspect ratio wing is then analyzed,and the results indicate the following:(1)the combined effects of the aerodynamic load and thermal load both deform the wing,which would increase if the flexibility,size,and flight time of the hypersonic aircraft increase;(2)the effect of heat accumulation should be noted,and therefore,the trajectory parameters should be considered in the design of hypersonic flight vehicles to avoid hazardous conditions,such as flutter.展开更多
基金the national Natural Science Foundation of China (No. 59874033).
文摘Based on the fluid transient theory and explosive dynamics, a new type explosive driven jet is put forward. The generator of the proposed jet system comprises an explosive power source, a dynamic cavity, a spacing block, a water storage chamber, and a rubber membrane. The dynamic explosive source of power for the jet is composed of a cartridge and a bullet. The pressure in the dynamic cavity goes up to a range from 300 MPa to 350 MPa very quickly when the bullet is emitted. Driven by such a high pressure, the speed of the jet reaches 120 m/s. The effective distance to distinguish a fire is within 40 m. The jet has the following advantages over a conventional high-pressure water jet system: 1)strong power and strong transient force produced by dynamic source; 2) the energy of the dynamical source concentrated in a small scope with very little loss; 3) extensive applicability; and 4) safe usage without sparkling and smoke.
文摘Time-dependent density functional theory （TDDFT） and femtosecond transient absorption spectroscopy were used to investigate the photophysical properties of 2,3-dihydro-3-keto-lH- pyrido[3,2,1-kl]phenothiazine （PTZ4） and 3-keto-lH-pyrido[3,2,1-kl]phenothiazine （PTZ5）. The calculated results obtained from TDDFT suggest that the red-shifts of the absorption spectra of these two fluorophores in methanol are due to the formation of hydrogen-bonded complexes at the ground state. Four conformers of PTZ4 were obtained by TDDFT. The two fluorescence peaks of PTZ4 in tetrahydrofuran （THF） came from the ICT states of the four conformers. The fluorescence of PTZ4 in THF showed a dependence on the excitation wavelength because of butterfly bending. The excited state dynamics of PTZ4 in THF and methanol were obtained by transient absorption spectroscopy. The lifetime of the excited PTZ4 in methanol was 53.8 ps, and its relaxation from the LE state to the ICT state was completed within several picoseconds. The short lifetime of excited PTZ4 in methanol was due to the formation of out-of-plane model hydrogen bonds between PTZ4 and methanol at the excited state.
基金supported by the National Basic Research Program of China(No.2019YFA0307701)the National Natural Science Foundation of China(No.11874180)the Young and Middle-aged Scientific and Technological Innovation leaders and Team Projects in Jilin Province(No.20200301020RQ)。
文摘The excited-state double proton transfer(ESDPT)properties of 1,5-dihydroxyanthraquinone(1,5-DHAQ)in various solvents were investigated using femtosecond transient absorption spectroscopy and the DFT/TDDFT method.The steady-state fluorescence spectra in toluene,tetrahydrofuran(THF)and acetonitrile(ACN)solvents presented that the solvent polarity has an effect on the position of the ESDPT fluorescence emission peak for the 1,5-DHAQ system.Transient absorption spectra show that the increasing polarity of the solvent accelerates the rate of excited state dynamics.Calculated potential energy curves analysis further verified the experimental results.The ESDPT barrier decreases gradually with the increase of solvent polarity from toluene,THF to ACN solvent.It is convinced that the increase of solvent polarity can promote the occurrence of the ESDPT dynamic processes for the 1,5-DHAQ system.This work clarifies the mechanism of the influence of solvent polarity on the ESDPT process of 1,5-DHAQ,which provides novel ideas for design and synthesis of new hydroxyanthraquinone derivatives.
基金supported by the National Natural Science Foundation of China(Grant Nos.11172025 and 91116005)
文摘In this paper,a high-efficiency aerothermoelastic analysis method based on unified hypersonic lifting surface theory is established.The method adopts a two-way coupling form that couples the structure,aerodynamic force,and aerodynamic thermo and heat conduction.The aerodynamic force is first calculated based on unified hypersonic lifting surface theory,and then the Eckert reference temperature method is used to solve the temperature field,where the transient heat conduction is solved using Fourier’s law,and the modal method is used for the aeroelastic correction.Finally,flutter is analyzed based on the p-k method.The aerothermoelastic behavior of a typical hypersonic low-aspect ratio wing is then analyzed,and the results indicate the following:(1)the combined effects of the aerodynamic load and thermal load both deform the wing,which would increase if the flexibility,size,and flight time of the hypersonic aircraft increase;(2)the effect of heat accumulation should be noted,and therefore,the trajectory parameters should be considered in the design of hypersonic flight vehicles to avoid hazardous conditions,such as flutter.
