Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spec- troscopy can extract the curve of spectral gain from its parametric superfluorescence. This unique spectrum correction method...Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spec- troscopy can extract the curve of spectral gain from its parametric superfluorescence. This unique spectrum correction method enables fluorescence non-collinear optical parametric amplification spectroscopy acquiring the genuine transient fluorescence spectrum of the studied system. In this work we employ fluorescence non-collinear optical parametric amplification spectroscopy technique to study the solvation dynamics of DCM dye in ethanol solution, and confirm that genuine solvation correlation function and shift of peak frequency can be derived from transient fluorescence spectra after the spectral gain correction. It demonstrates that fluorescence non-collinear optical parametric amplification spectroscopy can benefit the research fields, which focuses on both fluorescence intensity dynamics and fluorescence spectral shape evolution.展开更多
A one-dimensional column is set up to study the mass transfer during air sparging process for methyl tertiary butyl ether（MTBE） removal in saturated soil and groundwater, with the condition of different airflow and ...A one-dimensional column is set up to study the mass transfer during air sparging process for methyl tertiary butyl ether（MTBE） removal in saturated soil and groundwater, with the condition of different airflow and soil penetrability. It is shown that the removal rate of MTBE can reach 80%, 90% and 95% when airflow is 0.05 m^3/h, 0. 085 m^3/h and 0. 10 m^3/h, respectively. Increasing airflow will help to increase the removal rate of dissolved MTBE, but eventually a threshold removal rate is reached, above which further increasing air injection rates does not increase the removal rate. Fine sand allows the injected air to travel in bubble form, while coarse sand and medium sand allow the injected air to travel in the form of discrete channels; the greater the soil grain size is, the more extensive the channel net work forms, which in turn leads to higher removal rate. A tailing effect of lingering residual contaminant concentrations occur within the fine sand. About 20% of MTBE cannot be removed.展开更多
文摘Femtosecond time-resolved fluorescence non-collinear optical parametric amplification spec- troscopy can extract the curve of spectral gain from its parametric superfluorescence. This unique spectrum correction method enables fluorescence non-collinear optical parametric amplification spectroscopy acquiring the genuine transient fluorescence spectrum of the studied system. In this work we employ fluorescence non-collinear optical parametric amplification spectroscopy technique to study the solvation dynamics of DCM dye in ethanol solution, and confirm that genuine solvation correlation function and shift of peak frequency can be derived from transient fluorescence spectra after the spectral gain correction. It demonstrates that fluorescence non-collinear optical parametric amplification spectroscopy can benefit the research fields, which focuses on both fluorescence intensity dynamics and fluorescence spectral shape evolution.
基金Supported by National Natural Science Foundation of China(No. 20276048)
文摘A one-dimensional column is set up to study the mass transfer during air sparging process for methyl tertiary butyl ether（MTBE） removal in saturated soil and groundwater, with the condition of different airflow and soil penetrability. It is shown that the removal rate of MTBE can reach 80%, 90% and 95% when airflow is 0.05 m^3/h, 0. 085 m^3/h and 0. 10 m^3/h, respectively. Increasing airflow will help to increase the removal rate of dissolved MTBE, but eventually a threshold removal rate is reached, above which further increasing air injection rates does not increase the removal rate. Fine sand allows the injected air to travel in bubble form, while coarse sand and medium sand allow the injected air to travel in the form of discrete channels; the greater the soil grain size is, the more extensive the channel net work forms, which in turn leads to higher removal rate. A tailing effect of lingering residual contaminant concentrations occur within the fine sand. About 20% of MTBE cannot be removed.
