山东天然鳞片石墨微波法制备石墨烯片

石墨烯是由单层碳原子成六方环、构成二维蜂窝状晶格结构的一种碳质新材料,是目前已知世界上强度最高、最薄的材料(Geim&Novoselov,2007)。自从2010年诺贝尔物理奖以来,石墨烯成为炭科学的热点问题。因为优异的电学、力学性能。

三种氟化石墨的合成与性能的研究

利用自制电解槽电解ＫＦ·２ＨＦ电解液可制得氟气，将其净化后再与鳞片石墨、人造石墨和土状石墨分别进行反应，保持温度５００℃，并经１５ｈ连续不断的反应，可合成制得３种氟化石墨。测试结果表明：鳞片石墨合成的氟化石墨在红外光谱波数１２１９ｃｍ－１处吸收谱峰强度大于另外两种氟化石墨，且其真密度、含氟量、电阻率最高。因此，作为合成氟化石墨的原料。

氟化石墨工艺技术研究

气相法制备氟化石墨由于工艺简单、产品纯度高而成为合成氟化石墨最常用的方法。氟化石墨的合成过程涉及高温与活性单质氟气两方面的因素,安全控制十分重要。从原料、反应时间、反应温度、反应设备和纯化方法等方面对合成氟化石墨的工艺技术进行对比,旨在避免生产过程中出现潜在的危险,寻求提高氟化石墨产品质量的新方法,提升氟化石墨整体制备工艺的安全性。

碳素原料种类对低碳镁碳材料结构与性能的影响

摘要以电熔镁砂、鳞片石墨、炭黑、膨胀石墨为原料，研究不同种类碳素原料的引人对低碳镁碳材料结构号I生能的影响。对镁碳材料的常温耐压强度、显气孔率、体积密度、常温热导率及抗氧化性进行检测，利用SEM对其显微结构进行表征。研究结果表明以超细鳞片石墨作为碳素原料的低碳镁碳材料其结构号陛能较优，而以炭黑为碳素原料的低碳镁碳材料其结构与性能较差。

Synthesis of Cu_2O/reduced graphene oxide composites as anode materials for lithium ion batteries

A facile way was used to synthesize Cu2O/reduced graphene oxide （rGO） composites with octahedron-like morphology in aqueous solution without any surfactant. TEM images of the obtained Cu2O/rGOs reveal that the Cu2O particles and rGO distribute hierarchically and the primary Cu2O particles are encapsulated well in the graphene nanosheets. The electrochemical performance of Cu2O/rGOs is enhanced compared with bare Cu2O when they are employed as anode materials for lithium ion batteries. The Cu2O/rGO composites maintain a reversible capacity of 348.4 mA？h/g after 50 cycles at a current density of 100 mA/g. In addition, the composites retain 305.8 mA？h/g after 60 cycles at various current densities of 50, 100, 200, 400 and 800 mA/g.

Trial Production of Needle Coke at Shanghai Petrochemical Company

Needle coke is the starting material for manufacture of premium graphite electrode,which at present cannot be produced by SINOPEC and even other domestic refining enterprises so that the carbon producing plants inside China have to import a significant amount of high-quality needle coke every year.

Selective synthesis of Sb2S3 nanostructures with different morphologies for high performance in dye-sensitized solar cells

In this work,we initially synthesized Sb2S3 with uniform flower-like structures via a facile hydrothermal method through the modification of the Sb source and pH value.Afterward,Sb2S3 with a nanosheet structure was successfully synthesized on reduced graphene oxide(Sb2S3@RGO).The flower-like Sb2S3 and the Sb2S3@RGO nanosheets were tested as the counter electrode(CE)of dye-sensitized solar cells,and the latter exhibited a higher electrocatalytic property than the former owing to the introduction of graphene.The results from electrochemical tests indicated that the as-prepared Sb2S3@RGO nanosheets possess higher catalytic activity,charge-transfer ability,and electrochemical stability than Sb2S3,RGO,and Pt CEs.More notably,the power conversion efficiency of Sb2S3@RGO reached 8.17%,which was higher than that of the standard Pt CE(7.75%).

Nitrogen‐doped graphene aerogel‐supported ruthenium nanocrystals for pH‐universal hydrogen evolution reaction

The design and synthesis of high‐performance and low‐cost electrocatalysts for the hydrogen evolution reaction(HER),a key half‐reaction in water electrolysis,are essential.Owing to their modest hydrogen adsorption energy,ruthenium(Ru)‐based nanomaterials are considered outstanding candidates to replace the expensive platinum(Pt)‐based HER electrocatalysts.In this study,we developed an adsorption‐pyrolysis method to construct nitrogen(N)‐doped graphene aerogel(N‐GA)‐supported ultrafine Ru nanocrystal(Ru‐NC)nanocomposites(Ru‐NCs/N‐GA).The particle size of the Ru‐NCs and the conductivity of the N‐GA substrate can be controlled by varying the pyrolysis temperature.Optimal experiments reveal revealed that 10 wt%Ru‐NCs/N‐GA nanocomposites require overpotentials of only 52 and 36 mV to achieve a current density of 10 mA cm^(−2) in 1 mol/L HClO4 and 1 mol/L KOH electrolytes for HER,respectively,which is comparable to 20 wt%Pt/C electrocatalyst.Benefiting from the ultrafine size and uniform dispersion of the Ru‐NCs,the synergy between Ru and the highly conductive substrate,and the anchoring effect of the N atom,the Ru‐NCs/N‐GA nanocomposites exhibit excellent activity and durability in the pH‐universal HER,thereby opening a new avenue for the production of commercial HER electrocatalysts.

Preparation of graphene/MgCl_2-supported Ti-based Ziegler-Natta catalysts by the coagglomeration method and their application in ethylene polymerization

We report a facile coagglomeration method for preparing graphene (G)/MgCl2‐supported Ti‐based Ziegler‐Natta catalysts. The effects of graphene feed ratio on catalyst morphology and ethylene polymerization behavior were examined. The synthesized catalyst exhibited very high activity for ethylene polymerization. The resultant polyethylene (PE)/G nanocomposites showed a layered morphology, and the graphene fillers were well dispersed in the PE matrix. In addition, the thermal stability and mechanical properties of PE were significantly enhanced with the introduction of a very small amount of G fillers (0.05 wt%). This work provides a facile approach to the production o fhigh‐performance PE.

石墨对Al_2O_3、SiC质浇注料各种特性的影响

Al2O3—SiC—C质浇注料作为炼铁的不定形材料,使用范围较广。本文报告不同的石墨原料对Al2O3、SiC质浇注料各种特性的影响。1 试验用料表1为使用的石墨原料的组成,表2所示供给试料的配比,石墨（Ⅰ）采用1mm以下的颗粒,石墨（Ⅱ）。

High densities of magnetic nanoparticles supported on graphene fabricated by atomic layer deposition and their use as efficient synergistic microwave absorbers

An atomic layer deposition （ALD） method has been employed to synthesize Fe3O4/graphene and Ni/graphene composites. The structure and microwave absorbing properties of the as-prepared composites are investigated. The surfaces of graphene are densely covered by Fe3O4 or Ni nanoparticles with a narrow size distribution, and the magnetic nanoparticles are well distributed on each graphene sheet without significant conglomeration or large vacancies. The coated graphene materials exhibit remarkably improved electromagnetic （EM） absorption properties compared to the pristine graphene. The optimal reflection loss （RL） reaches -46.4 dB at 15.6 GHz with a thickness of only 1.4 mm for the Fe3O4/graphene composites obtained by applying 100 cycles of Fe2O3 deposition followed by a hydrogen reduction. The enhanced absorption ability arises from the effective impedance matching, multiple interfacial polarization and increased magnetic loss from the added magnetic constituents. Moreover, compared with other recently reported materials, the composites have a lower filling ratio and smaller coating thickness resulting in significantly increased EM absorption properties. This demonstrates that nanoscale surface modification of magnetic particles on graphene by ALD is a very promising way to design lightweight and high-efficiency microwave absorbers.

Unconventional chemical graphitization and functionalization of graphene oxide toward nanocomposites by degradation of ZnSe[DETA]0.5 hybrid nanobelts

The high surface energy of nanomaterials endows them a metastable nature,which greatly limits their application.However,in some cases,the degradation process derived from the poor stability of nanomaterials offers an unconventional approach to design and obtain functional nanomaterials.Herein,based on the poor stability of ZnSe-[DETA]0.5 hybrid nanobelts,we developed a new strategy to chemically graphitize and functionalize graphene oxide(GO).When ZnSe[DETA]0.5 hybrid nanobelts encountered a strong acid,they were attacked by H^+cations and could release highly reactive Se^2−anions into the reaction solution.Like other common reductants(such as N2H4·H2O),these Se^2−anions exhibited an excellent ability to restore the structure of GO.The structural restoration of GO was greatly affected by the reaction time,the volume of HCl,and the mass ratio between GO and ZnSe[DETA]0.5 nanobelts.By carefully controlling the reaction process and the post-processing process,we finally obtained several Se-based reduced GO(RGO)nanocomposites(such as ZnSe/Se-RGO,ZnSe-RGO,and Se-RGO)and various selenide/metal-RGO nanocomposites(such as Ag2Se-RGO,Cu2Se-RGO,and Pt-RGO).Although the original structure and composition of ZnSe[DETA]0.5 nanobelts are destroyed,the procedure presents an unconventional way to chemically graphitize and functionalize GO and thus provides a new material synthesis platform for nanocomposites.