The growing concern about thermal conductivityand electromagnetic shielding inelectronic equipment has promoted the development of interfacial film materials.In this work,polyvinylidene fluoride(PVDF)/graphene composi...The growing concern about thermal conductivityand electromagnetic shielding inelectronic equipment has promoted the development of interfacial film materials.In this work,polyvinylidene fluoride(PVDF)/graphene composite films with different graphene contents were fabricated by high-energy ball milling,cold isostatic pressing,scraping and coating,successively.High-energy ball milling is beneficial to the dispersion of graphene powder,while cold isostatic pressing can greatly enhance thermal conductivity and mechanical strength by reducing the voids in the film and increasing the contact area of graphene sheets.The thermal conductivity,tensile strength and electromagnetic shielding properties of the films were carefully investigated and compared.It was demonstrated that the thermal conductivity increased from 0.19 Wm-1.K-1 for pure PVDF to 103.9 W-m-1.K-1 for the composite film with PVDF:graphene=1:3.Meanwhile the electromagnetic shielding efficiency can reach 36.55 dB.The prepared PVDF/graphene composite films exhibit outstanding overall performance and have the potential for practical applications.展开更多
基金This work was supported by the National Natural ScienceFoundationofChina(No.U22B2066,No.12064044)the Major Science and Technology Projects of Anhui Province(No.202103a05020016)+1 种基金the open competition project to select the best candidates to undertake major science and key research projectsofTonglingcity,AnhuiProvince(No.202101JB002)A proportion of this work was supported by the High Magnetic Field Laboratory of Anhui Province and Academician workstation of Hangzhou Xingyu Carbon Environmental Tech Co.,Ltd.,and the Hefei Institutes of Physical Science Director's Fund(No.YZJJ-GGZX-2022-01).
文摘The growing concern about thermal conductivityand electromagnetic shielding inelectronic equipment has promoted the development of interfacial film materials.In this work,polyvinylidene fluoride(PVDF)/graphene composite films with different graphene contents were fabricated by high-energy ball milling,cold isostatic pressing,scraping and coating,successively.High-energy ball milling is beneficial to the dispersion of graphene powder,while cold isostatic pressing can greatly enhance thermal conductivity and mechanical strength by reducing the voids in the film and increasing the contact area of graphene sheets.The thermal conductivity,tensile strength and electromagnetic shielding properties of the films were carefully investigated and compared.It was demonstrated that the thermal conductivity increased from 0.19 Wm-1.K-1 for pure PVDF to 103.9 W-m-1.K-1 for the composite film with PVDF:graphene=1:3.Meanwhile the electromagnetic shielding efficiency can reach 36.55 dB.The prepared PVDF/graphene composite films exhibit outstanding overall performance and have the potential for practical applications.
