石油化工企业“三违”行为及预防措施

针对石油化工企业作业现场、施工的三违情况,分析原因进行剖析,采取预防措施,充分结合现代事故管理理论进行事故预防控制,防范各类事故的发生。本文就此进行了阐述。

Simulation of hydrocarbons pyrolysis in a fast-mixing reactor

Currently, thermal decomposition of hydrocarbons for the production of basic petrochemicals(ethylene, propylene) is carried out in steam-cracking processes. Aside from the conventional method, under consideration are alternative ways purposed for process intensification. In the context of these activities, the method of hightemperature pyrolysis of hydrocarbons in a heat-carrier flow is studied, which differs from previous ones and is based on the ability of an ultra-short time of feedstock/heat-carrier mixing. This enables to study the pyrolysis process at high temperature(up to 1500 K) at the reactor inlet. A set of model experiments is conducted on the lab scale facility. Liquefied petroleum gas(LPG) and naphtha are used as a feedstock. The detailed data are obtained on temperature and product distributions within a wide range of the residence time. A theoretical model based on the detailed kinetics of the process is developed, too. The effect of governing parameters on the pyrolysis process is analyzed by the results of the simulation and experiments. In particular, the optimal temperature is detected which corresponds to the maximum ethylene yield. Product yields in our experiments are compared with the similar ones in the conventional pyrolysis method. In both cases(LPG and naphtha), ethylene selectivity in the fast-mixing reactor is substantially higher than in current technology.

A Hybrid Model Predictive Control for Handling Infeasibility and Constraint Prioritization

A hybrid approach using MLD (mixed logical dynamical) framework to handle infeasibility and constraint prioritization issues in MPC (model predictive control) based on input-output model is introduced. By expressing constraint priorities as propositional logics and by transforming the propositional logics into inequalities,the infeasibility and constraint prioritization issues are solved in the MPC. Constraints with higher priorities are met first, and then these with lower priorities are satisfied as much as possible. This new approach is illustrated in the control of a heavy oil fractionator-Shell column. The overall control performance has been significantly improved through the infeasibility and control priorities handling.

Development and Commercial Application of Third Generation Resid Hydrotreating Catalysts

Based on the mechanism of resid hydrotreating reaction by coordinating the catalyst activity and stability, the diffusion mechanism and catalyst reactivity, the cost and catalyst performance, and the production and application requirements, the third-generation series catalysts for residue hydrotreating have been developed by Research Institute of Petroleum Processing, SINOPEC. The new series RHT catalysts possess higher activity for HDS, HDM and HDCCR performance as well as longer run length. The commercial results for application of these catalysts have demonstrated that the new catalyst system performs better than the reference ones.

Dynamic Modeling and Simulation of a Commercial Naphtha Catalytic Reforming Process

A first principles-based dynamic model for a continuous catalyst regeneration (CCR) platforming process, the UOP commercial naphtha catalytic reforming process, is developed in this paper. The lumping details of the naphtha feed and reaction scheme of the reaction model are given. The process model is composed of the reforming reaction model with catalyst deactivation, the furnace model and the separator model, which is capable of capturing the major dynamics that occurs in this process system. Dynamic simulations are performed based on Gear numerical algorithm and method of lines (MOL), a numerical technique dealing with partial differential equations (PDEs). The results of simulation are also presented. Dynamic responses caused by disturbances in the process system can be correctly predicted through simulations.

Research and Commercial Application of CPP Technology for Producing Light Olefins from Heavy Oil

Catalytic pyrolysis process(CPP)producing ethylene and propylene from paraffin base atmospheric residue was developed by RIPP and its first in the world unit was put into commercial operation successfully.The results of performance test showed that the yield of ethylene and propylene reached 14.84% and 22.21% ,respectively,at a reaction temperature of610℃by using Daqing atmospheric residue as the feedstock under an operation mode of producing ethylene and propylene at the same time,and the aromatic content of cracked naphtha reached 82.46% .The successful operation of this unit has opened a novel route for producing light olefins and aromatics from heavy oil,which is also a good example symbolizing the integration of refining technology with petrochemical process.

Commercial Application of the RAR Sulfur Recovery and Tail Gas Treating Process

The 40kt/a sulfur recovery unit for tail gas treating applying the reduction-absorption-recycling (RAR) technology is aimed at regeneration of the rich amine solution and recovery of sulfur to operate in tandem with the 1.2Mt/a diesel hydrofining unit. The process unit calibration data have revealed that the recovery of total sulfur reaches 99.86%, which is 6.65 percentage points higher than that before application of the RAR technology. The SO2 content in vented tail gas is 0.27 t/d, which is much less than the latest emission standard prescribed by the State. The factors that can affect the unit operation have been analyzed and corresponding measures have been suggested including the necessity to improve the control over the reaction temperature in the tail gas hydrogenation unit.

Study on Lumped Kinetic Model for FDFCC Ⅱ.Validation and Prediction of Model

On the basis of formulating the 9-lump kinetic model for gasoline catalytic upgrading and the 12- lump kinetic model for heavy oil FCC, this paper is aimed at development of a combined kinetic model for a typical FDFCC process after analyzing the coupled relationship and combination of these two models. The model is also verified by using commercial data, the results of which showed that the model can better predict the product yields and their quality, with the relative errors between the main products of the unit and commercial data being less than five percent. Furthermore, the combined model is used to predict and optimize the operating conditions for gasoline riser and heavy oil riser in FDFCC. So this paper can offer some guidance for the processing of FDFCC and is instructive to model research and development of such multi-reactor process and combined process.

The Application of RUF Series Catalysts and Its Grading Optimization Technology

Qilu Petrochemical Company in order to synchronize the replacement of catalysts in the upflow reactor (UFR) and fixed-bed reactors and achieve the 1.5-year operating cycle of the residue hydrotreating unit has revamped the UFR and optimized catalysts grading. Commercial operation results have revealed that the series of catalysts for residue hydrotreating after optimized grading achieved an operating cycle of 1.5 years with the quality of hydrotreated oil products meeting the requirements for FCC feedstock.

Steam Reforming of Natural Gas： A Value Addition to Natural Gas Utilization in Nigeria

Petrochemicals play a vital role in the economy of any nation. The products of the industry are the building blocks in many industries as they deepen the forward and backward linkages of the petroleum sector with the rest of the economy. The industry uses a variety of hydrocarbon feedstock such as different cuts of naphtha from refinery and natural gas. One of the problems facing the industry is lack of reliable feedstock supplies. Nigeria has the potential to be a major petrochemicals producer. With proven gas reserves currently estimated at 187 tcf, not much has been accomplished with respect to the effective exploitation and utilization of this resource as most of the nation＇s natural gas production has been flared, liquefied for export or re-injected to enhance greater crude oil recovery. It has become imperative to further find ways to exploit and utilize the nation＇s natural gas reserves and translate it to the improvement of the nation＇s economy. Steam reforming of natural gas is one of the avenues for conversion of natural gas to petrochemicals. This paper, however, reviews various ways of utilizing natural gas, examines the process details of steam reforming of natural gas as a route to optimized natural gas utilization and industrialization in Nigeria. Syngas （synthesis gas） is a versatile feedstock for most petrochemicals and chemical intermediates. Thus utilizing natural gas in this way would strengthen the petrochemical industry making it possible for the country to change from raw materials to value-added products supplier, boost the economy and solve the ＂hydra-headed＂ problem of unemployment in Nigeria with its multiplier employment effect.

Development of RSDS-III Technology for Ultra-Low-Sulfur Gasoline Production

The 3rd generation catalytic cracking naphtha selective hydrodesulfurization(RSDS-III) technology developed by RIPP included the catalysts selective adjusting(RSAT) technology, the development of new catalysts and optimized process conditions. The pilot plant test results showed that the RSDS-III technology could be adapted to different feedstocks. The sulfur content dropped from 600 μg/g and 631 μg/g to 7 μg/g and 9 μg/g, respectively, by RSDS-III technology when feed A and feed B were processed to meet China national V gasoline standard, with the RON loss of products equating to 0.9 units and 1.0 unit, respectively. While the feed C with a medium sulfur content was processed according to the full-range naphtha hydrotreating technology, the sulfur content dropped from 357 μg/g in the feed to 10 μg/g in gasoline, with the RON loss of product decreased by only 0.6 units. Thanks to the high HDS activity and good selectivity of RSDS-III technology, the ultra-low-sulfur gasoline meeting China V standard could be produced by the RSDS-III technology with little RON loss.

Development and Commercial Application of Resid Hydrotreating Technology--RHT

The RHT technology is developed by Research Institute of Petroleum Processing (RIPP) for residuum hydrotreating in order to produce good quality RFCC feed. The advantages of the RHT series catalysts are presented in this article, based on the results of activity tests and a 9500 hours service life test in pilot plants and the assessment on a commercial application.

China’s Largest Integrated Oil Refining & Chemical JV Project Officially Launched

On July 8th, 2005, China＇s largest integrated oil refining and chemical joint-venture project was officially launched in Quanzhou, Fujian Province, indicating that another petrochemical base is growing up following Sinopec Qilu Petrochemical Company, Sinopec Beijing Yanhua Petrochemical Co. Ltd,

Sinopec, Qingdao Port Group Signed Crude Oil Cooperative Project Contract

Sinopec and Qingdao Port Group held a formal ceremony to sign the “joint venture contract and the issues of association for Qingdao Shihua Crude Oil Wharf Co. Ltd.”on June 21,2005. This is another association between the both parties since they formed a strategic alliance on the successful transfer of the 1.80 million cubic meters of crude oil tanks in 2001.

RIPP Works on Crude Formulation Technique to Grapple with Refiners' Tough Problems

Currently ＂The Crude Formulation Technique＂ developed by the SINOPEC Research Institute of Petroleum Processing（RIPP） has passed the technical review sponsored by the Sinopec Corp.This technique by means of adopting the advanced algorithm on the basis of the crude assay data bank and the large crude spectroscopic database can intelligently blend together different kinds of crude oils to obtain multiple crude formulations, the quality of which is quite close to the target crude in a bid to provide technical support to the refining enterprises in the area of crude procurement and sustained property stabilization of crude oils pro-cessed thereby.

Impact of crude distillation unit model accuracy on refinery production planning

In this work, we examine the impact of crude distillation unit(CDU) model errors on the results of refinery-wide optimization for production planning or feedstock selection. We compare the swing cut + bias CDU model with a recently developed hybrid CDU model(Fu et al., 2016). The hybrid CDU model computes material and energy balances, as well as product true boiling point(TBP) curves and bulk properties(e.g., sulfur% and cetane index, and other properties). Product TBP curves are predicted with an average error of 0.5% against rigorous simulation curves. Case studies of optimal operation computed using a planning model that is based on the swing cut + bias CDU model and using a planning model that incorporates the hybrid CDU model are presented. Our results show that significant economic benefits can be obtained using accurate CDU models in refinery production planning.

Floating production storage and offloading systems＇ cost and motion performance： A systems thinking application

Floating production storage and offloading （FPSO） units increasingly represent a practical and economic means for deep-water oil extraction and production. Systems thinking gives a unique opporamity to seek a balance between FPSO technical performance（s）, with whole-cost; stakeholder decision-making is charged to align different fit-for-use design specification options＇ that address technical-motion（s）, with respective life-cycle cost analyses （LCCA）. Soft system methodology allows situation based analyses over set periods-of-time by diagnosing the problem-at-hand; namely, assessing the antecedents of life-cycle cost relative to FPSO sub- component design alternatives. Alternative mooring- component comparisons for either new-build hulls or refurbished hulls represent an initial necessary considera- tion to facilitate extraction, production and storage of deep- water oil reserves. Coupled dynamic analysis has been performed to generate FPSO motion in six degrees of freedom using SESAM DeepC, while life-cycle cost analysis （LCAA） studies give net-present-value comparsons reflective of market conditions. A parametric study has been conducted by varying wave heights from 4 - 8 m to understand FPSO motion behavior in the presence of wind and current, as well as comparing the motions of turreted versus spread mooring design alternatives. LCCA data has been generated to compare the cost of such different mooring options/hull conditions over 10 and 25- year periods. Systems thinking has been used to explain the interaction of problem variables; resultantly this paper is able to identify explicit factors affecting the choice of FPSO configurations in terms of motion and whole-cost, toward assisting significantly with the front-end engineering design （FEED） phase of fit-for-purpose configured FPSOs, in waters off Malaysia and Australia.