A model describing the absorption process of SO2 into limestone slurry with a spray scrubber is presented. Both the physical performance of the spray liquid in the scrubber and the involved chemical reactions are anal...A model describing the absorption process of SO2 into limestone slurry with a spray scrubber is presented. Both the physical performance of the spray liquid in the scrubber and the involved chemical reactions are analyzed in the model. A con- tinuous concentration change of H+ was solved by iterative coupling using Matlab, and it was found that there was a remarkable influence on the concentration of the other elements in the process of SO2 absorption. The calculations show that the enhancement factor exponentially grows with an increasing value of pH and logarithmically decays with an increasing value of the driving force. To verify the accuracy of the model, experiments were also carried out, and the results suggest that the model, after combining the physical performance of the spray and the enhancement factor, can more precisely describe SO2 absorption in a spray scrubber. Furthermore, a commercial computational fluid dynamics (CFD) tool is used to perform several simulations which describe and clarify the effects of variables on SO2 absorption. The results of numerical simulation can provide a basis for further design and optimization of the scrubber.展开更多
In this paper, concrete with limestone coarse aggregate was studied due to frost action in saline and nonsaline environments. The main focus is to explain the damaging formula of concrete with poor quality of limeston...In this paper, concrete with limestone coarse aggregate was studied due to frost action in saline and nonsaline environments. The main focus is to explain the damaging formula of concrete with poor quality of limestone aggregate in frost actions. All investigated concretes fulfill the recommendations of the European standard EN 206, Concrete--Specification, Performance, Production and Conformity limiting values for composition and properties of concrete （maximum W/C （water/cement） ratio, minimal class of compressive strength, minimal mass of cement and minimal percentage of entrained air）. The damaging formula of the frost resistant concrete is studied through scaling test of concrete during freeze/thaw process, frost resistant test of coarse limestone aggregate and chemical analysis of limestone. Experiments results showed that there is a correlation between CaO/MgO ratio and Al2O3 of limestone and frost resistance of concrete, using chemical composition for determining potential ACR （alkali-carbonate reactivity） will indicate higher risk of damaging effect of concrete.展开更多
基金Project supported by the National Key Technologies Supporting Program of China during the 11th Five-Year Plan Period (No.2006BAA01B04)the New Century Excellent Talent in University(No. NCET-06-0513), China
文摘A model describing the absorption process of SO2 into limestone slurry with a spray scrubber is presented. Both the physical performance of the spray liquid in the scrubber and the involved chemical reactions are analyzed in the model. A con- tinuous concentration change of H+ was solved by iterative coupling using Matlab, and it was found that there was a remarkable influence on the concentration of the other elements in the process of SO2 absorption. The calculations show that the enhancement factor exponentially grows with an increasing value of pH and logarithmically decays with an increasing value of the driving force. To verify the accuracy of the model, experiments were also carried out, and the results suggest that the model, after combining the physical performance of the spray and the enhancement factor, can more precisely describe SO2 absorption in a spray scrubber. Furthermore, a commercial computational fluid dynamics (CFD) tool is used to perform several simulations which describe and clarify the effects of variables on SO2 absorption. The results of numerical simulation can provide a basis for further design and optimization of the scrubber.
文摘In this paper, concrete with limestone coarse aggregate was studied due to frost action in saline and nonsaline environments. The main focus is to explain the damaging formula of concrete with poor quality of limestone aggregate in frost actions. All investigated concretes fulfill the recommendations of the European standard EN 206, Concrete--Specification, Performance, Production and Conformity limiting values for composition and properties of concrete （maximum W/C （water/cement） ratio, minimal class of compressive strength, minimal mass of cement and minimal percentage of entrained air）. The damaging formula of the frost resistant concrete is studied through scaling test of concrete during freeze/thaw process, frost resistant test of coarse limestone aggregate and chemical analysis of limestone. Experiments results showed that there is a correlation between CaO/MgO ratio and Al2O3 of limestone and frost resistance of concrete, using chemical composition for determining potential ACR （alkali-carbonate reactivity） will indicate higher risk of damaging effect of concrete.
