A two-stage oxidation—alkali leaching—acid leaching method was proposed to recovery Fe,V,and Ti in modified Ti-bearing blast furnace slag.The optimal experiment conditions of iron extraction were one-stage oxidation...A two-stage oxidation—alkali leaching—acid leaching method was proposed to recovery Fe,V,and Ti in modified Ti-bearing blast furnace slag.The optimal experiment conditions of iron extraction were one-stage oxidation time 40 s and holding time 8 min.The recovery rate of iron was 89.93%.The optimum experiment conditions of vanadium extraction were total oxidation time of 126 s,NaOH concentration of 4.0 mol/L,leaching temperature of 95℃,leaching time of 90 min,and the number of cycle was 4.The leaching rate of vanadium was 92.13%.The optimal experiment conditions of titanium extraction were HCl concentration of 4.5 mol/L,leaching temperature of 75℃,and leaching time of 90 min.The TiO_(2)content of synthetic rutile was 98.61%.展开更多
Jiangjia Ravine is a world-famous debris flow valley in Dongchuan,Yunnan Province,China.Every year large numbers of landslides and collapses happened and caused enormous damages to people's properties and lives.Wi...Jiangjia Ravine is a world-famous debris flow valley in Dongchuan,Yunnan Province,China.Every year large numbers of landslides and collapses happened and caused enormous damages to people's properties and lives.With longtime observation and testing in Jiangjia Ravine we had found out one kind of special landslide which had the characteristics of landslide and collapse.Landslide and collapse supplied sufficient materials for debris flow.When a debris flow broke out,some kind of intergrowth existed among rainfall,landslide and debris flow.In order to study the intergrowth and some key parameters,we carried out artificial rainfall landslide tests and model experiments to observe the phenomena such as collapse,surface slide and surface flow.By observing the experimental phenomena and monitoring water contents,the transformation process among landslide deposits and debris flow under the condition of rainfall had been analyzed.Research results revealed the relationship of this kind of intergrowth among rainfall,landslide and debris flow in Jiangjia Ravine.Meanwhile,it was found that this kind of intergrowth relationship existed only when the moisture content was in a certain range.That is,the critical state seemed to be existed in the transformation process.展开更多
This article describes the application of the PIMS software in formulating monthly refining production plan. Application of the PIMS software can help to solve a series of problems related with monthly plan of refinin...This article describes the application of the PIMS software in formulating monthly refining production plan. Application of the PIMS software can help to solve a series of problems related with monthly plan of refining production such as optimized selection of crude and feedstocks, optimized selection of production scale and processing scheme, identification of bottlenecks and their mitigation,optimized selection of turnaround time and optimized selection of operating regime, which have increased the economic benefits of refining enterprises. With the further development and improvement of models the PIMS software will play an increasingly important role in formulating monthly plans of refining operations and production management at refineries. This article also explores the problems existing in refinery monthly planning, and has made recommendations on developing and improving models and reporting system, enhancement of basic data acquisition, model maintenance personnel and staff training.展开更多
Graphene possesses unique physical and chemical properties, which have inspired a wide range of potential biomedical applications. However, little is known about the adverse effects of graphene on the human body and e...Graphene possesses unique physical and chemical properties, which have inspired a wide range of potential biomedical applications. However, little is known about the adverse effects of graphene on the human body and ecological environment. The purpose of our work is to make assessment on the toxicity of graphene oxide (GO) against human cell line (human bone marrow neuroblastoma cell line and human epithelial carcinoma cell line) and zebrafish (Danio rerio) by comparing the toxic effects of GO with its sister, multi-walled carbon nanotubes (MWNTs). The results show that GO has a moderate toxicity to organisms since it can induce minor (about 20%) cell growth inhibition and slight hatching delay of zebrafish embryos at a dosage of 50 mg/L, but did not result in significant increase of apoptosis in embryo, while MWNTs exhibit acute toxicity leading to a strong inhibition of cell proliferation and serious morphological defects in developing embryos even at relatively low concentration of 25 mg/L. The distinctive toxicity of GO and MWNTs should be ascribed to the different models of interaction between nanomaterials and organisms, which arises from the different geometric structures of nanomaterials. Collectively, our work suggests that GO does actual toxicity to organisms posing potential environmental risks and the result is also shedding light on the geometrical structure-dependent toxicity of graphitic nanomaterials.展开更多
基金financial support from the National Science and Technology Support Program of China(No.2015BAB18B00)。
文摘A two-stage oxidation—alkali leaching—acid leaching method was proposed to recovery Fe,V,and Ti in modified Ti-bearing blast furnace slag.The optimal experiment conditions of iron extraction were one-stage oxidation time 40 s and holding time 8 min.The recovery rate of iron was 89.93%.The optimum experiment conditions of vanadium extraction were total oxidation time of 126 s,NaOH concentration of 4.0 mol/L,leaching temperature of 95℃,leaching time of 90 min,and the number of cycle was 4.The leaching rate of vanadium was 92.13%.The optimal experiment conditions of titanium extraction were HCl concentration of 4.5 mol/L,leaching temperature of 75℃,and leaching time of 90 min.The TiO_(2)content of synthetic rutile was 98.61%.
基金financially supported by the National Natural Science Foundation of China(Grant No.50709035,40672193)the Youth Science and Technology Dawn Plan of Wuhan,China(Grant No.20065004116-42)
文摘Jiangjia Ravine is a world-famous debris flow valley in Dongchuan,Yunnan Province,China.Every year large numbers of landslides and collapses happened and caused enormous damages to people's properties and lives.With longtime observation and testing in Jiangjia Ravine we had found out one kind of special landslide which had the characteristics of landslide and collapse.Landslide and collapse supplied sufficient materials for debris flow.When a debris flow broke out,some kind of intergrowth existed among rainfall,landslide and debris flow.In order to study the intergrowth and some key parameters,we carried out artificial rainfall landslide tests and model experiments to observe the phenomena such as collapse,surface slide and surface flow.By observing the experimental phenomena and monitoring water contents,the transformation process among landslide deposits and debris flow under the condition of rainfall had been analyzed.Research results revealed the relationship of this kind of intergrowth among rainfall,landslide and debris flow in Jiangjia Ravine.Meanwhile,it was found that this kind of intergrowth relationship existed only when the moisture content was in a certain range.That is,the critical state seemed to be existed in the transformation process.
文摘This article describes the application of the PIMS software in formulating monthly refining production plan. Application of the PIMS software can help to solve a series of problems related with monthly plan of refining production such as optimized selection of crude and feedstocks, optimized selection of production scale and processing scheme, identification of bottlenecks and their mitigation,optimized selection of turnaround time and optimized selection of operating regime, which have increased the economic benefits of refining enterprises. With the further development and improvement of models the PIMS software will play an increasingly important role in formulating monthly plans of refining operations and production management at refineries. This article also explores the problems existing in refinery monthly planning, and has made recommendations on developing and improving models and reporting system, enhancement of basic data acquisition, model maintenance personnel and staff training.
基金supported by the National Natural Science Foundation of China (21035005)the Doctoral Program Foundation of Institutions of Higher Education of China (20115301120002)the Natural Science Foundation of Yunnan Province of China (2011FB007)
文摘Graphene possesses unique physical and chemical properties, which have inspired a wide range of potential biomedical applications. However, little is known about the adverse effects of graphene on the human body and ecological environment. The purpose of our work is to make assessment on the toxicity of graphene oxide (GO) against human cell line (human bone marrow neuroblastoma cell line and human epithelial carcinoma cell line) and zebrafish (Danio rerio) by comparing the toxic effects of GO with its sister, multi-walled carbon nanotubes (MWNTs). The results show that GO has a moderate toxicity to organisms since it can induce minor (about 20%) cell growth inhibition and slight hatching delay of zebrafish embryos at a dosage of 50 mg/L, but did not result in significant increase of apoptosis in embryo, while MWNTs exhibit acute toxicity leading to a strong inhibition of cell proliferation and serious morphological defects in developing embryos even at relatively low concentration of 25 mg/L. The distinctive toxicity of GO and MWNTs should be ascribed to the different models of interaction between nanomaterials and organisms, which arises from the different geometric structures of nanomaterials. Collectively, our work suggests that GO does actual toxicity to organisms posing potential environmental risks and the result is also shedding light on the geometrical structure-dependent toxicity of graphitic nanomaterials.