The massive accumulation of flue gas desulfurization(FGD)gypsum produced in the wet limestone-gypsum flue gas desulfurization process not only encroaches on lands but also causes serious environmental pollution.The pr...The massive accumulation of flue gas desulfurization(FGD)gypsum produced in the wet limestone-gypsum flue gas desulfurization process not only encroaches on lands but also causes serious environmental pollution.The preparation ofα-hemihydrate gypsum(α-HH)is an important way to achieve high-value utilization of FGD gypsum.Although the glycerol-water solution approach can be used to produceα-HH from FGD gypsum under mild conditions,the transition is kinetically unfavorable in the mixed solution.Here,an easy pretreatment was used to activate FGD gypsum by calcination and hydration to readily complete the transition.The pretreatment deteriorated the crystallinity of FGD gypsum and caused it to form small irregular flaky crystals,which dramatically increased the specific surface area.Additionally,most of the organics adsorbed onto FGD gypsum surfaces were removed after pretreatment.The poor crystallinity,increased specific surface area,and elimination of organics adsorbed onto crystal surfaces effectively improved the conversion activity of FGD gypsum,thereby promoting dihydrate gypsum(DH)dissolution andα-HH nucleation.Overall,the phase transition of FGD gypsum toα-HH is facilitated.展开更多
Application of lime or gypsum is a common agricultural practice to ameliorate soils with low pH which prohibits crop production. Its integrated effect on soil properties in a red soil derived from Quaternary red clay ...Application of lime or gypsum is a common agricultural practice to ameliorate soils with low pH which prohibits crop production. Its integrated effect on soil properties in a red soil derived from Quaternary red clay in Southeast China is discussed in this paper. Application of gypsum in the topsoil without leaching raised soil pH and promoted the production of soil NH 4, but lime addition had a contrary effect. Generally, application of lime and/or gypsum has little effect on soil electrical properties. Gypsum had a little effect on soil exchange complex and its effect went down to 30 cm in depth. The effect of lime reached only to 5 cm below its application layer. With leaching, Ca transferred from top soil to subsoil and decreased exchangeable Al in subsoil. Gypsum application led to a sharp decrease in soil exchangeable Mg but had no effect on K.展开更多
This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurizatio...This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurization project, the technical features and differencesof Phase I and II desulfurization plants, and puts forward some suggestions for FGD projectconstruction.[展开更多
The issues of reducing CO_2 emissions, sustainably utilizing natural mineral resources, and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an effic...The issues of reducing CO_2 emissions, sustainably utilizing natural mineral resources, and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an efficient methodology via the co-reaction of K-feldspar and phosphogypsum for the extraction of soluble potassium salts and recovery of SO_2 with reduced CO_2 emission and energy consumption. The results of characterization and reactivity evaluation indicated that the partial melting of K-feldspar and phosphogypsum in the hightemperature co-reaction significantly facilitated the reduction of phosphogypsum to SO_2 and the exchange of K^+(K-feldspar) with Ca^(2+)(CaSO_4 in phosphogypsum). The reaction parameters were systematically investigated with the highest sulfur recovery ratio of ~ 60% and K extraction ratio of ~ 87.7%. This novel methodology possesses an energy consumption reduction of ~ 28% and CO_2 emission reduction of ~ 55% comparing with the present typical commercial technologies for utilization of K-feldspar and the treatment of phosphogypsum.展开更多
Selected non-burned method and took fly-ash as main material, together with lime and gypsum, to inspire the activity of volcanic ash, took a kind of poly-organics to re-place the clay as binder, and then made small ba...Selected non-burned method and took fly-ash as main material, together with lime and gypsum, to inspire the activity of volcanic ash, took a kind of poly-organics to re-place the clay as binder, and then made small balls with machine, wrapped slurry twice and autoclaved 8 hours at normal atmosphere, made ceramsite in this way can endure higher compression strength. Comparing with common concrete, the ceramsite concrete is about 25% lighter on weight.展开更多
基金Projects(51904104,51974117,51804114)supported by the National Natural Science Foundation of ChinaProjects(2018YFC1901601,2018YFC1901602,2018YFC1901605)supported by the National Key Scientific Research Project of China+1 种基金Project(2015CX005)supported by the Innovation Driven Plan of Central South University,ChinaProject(18B226)supported by the Excellent Youth Project of Hunan Education Department,China
文摘The massive accumulation of flue gas desulfurization(FGD)gypsum produced in the wet limestone-gypsum flue gas desulfurization process not only encroaches on lands but also causes serious environmental pollution.The preparation ofα-hemihydrate gypsum(α-HH)is an important way to achieve high-value utilization of FGD gypsum.Although the glycerol-water solution approach can be used to produceα-HH from FGD gypsum under mild conditions,the transition is kinetically unfavorable in the mixed solution.Here,an easy pretreatment was used to activate FGD gypsum by calcination and hydration to readily complete the transition.The pretreatment deteriorated the crystallinity of FGD gypsum and caused it to form small irregular flaky crystals,which dramatically increased the specific surface area.Additionally,most of the organics adsorbed onto FGD gypsum surfaces were removed after pretreatment.The poor crystallinity,increased specific surface area,and elimination of organics adsorbed onto crystal surfaces effectively improved the conversion activity of FGD gypsum,thereby promoting dihydrate gypsum(DH)dissolution andα-HH nucleation.Overall,the phase transition of FGD gypsum toα-HH is facilitated.
文摘Application of lime or gypsum is a common agricultural practice to ameliorate soils with low pH which prohibits crop production. Its integrated effect on soil properties in a red soil derived from Quaternary red clay in Southeast China is discussed in this paper. Application of gypsum in the topsoil without leaching raised soil pH and promoted the production of soil NH 4, but lime addition had a contrary effect. Generally, application of lime and/or gypsum has little effect on soil electrical properties. Gypsum had a little effect on soil exchange complex and its effect went down to 30 cm in depth. The effect of lime reached only to 5 cm below its application layer. With leaching, Ca transferred from top soil to subsoil and decreased exchangeable Al in subsoil. Gypsum application led to a sharp decrease in soil exchangeable Mg but had no effect on K.
文摘This paper elaborates the wet limestone gypsum technology adopted in the flue gasdesulfurization projects of 4×360 MW generating units in Luohuang Power Plant, theimplementation process of Phase II desulfurization project, the technical features and differencesof Phase I and II desulfurization plants, and puts forward some suggestions for FGD projectconstruction.[
基金Supported by the National Natural Science Foundation of China(21336004)the State Key Research Plan of the Ministry of Science and Technology(2013BAC12B03)
文摘The issues of reducing CO_2 emissions, sustainably utilizing natural mineral resources, and dealing with industrial waste offer challenges for sustainable development in energy and the environment. We propose an efficient methodology via the co-reaction of K-feldspar and phosphogypsum for the extraction of soluble potassium salts and recovery of SO_2 with reduced CO_2 emission and energy consumption. The results of characterization and reactivity evaluation indicated that the partial melting of K-feldspar and phosphogypsum in the hightemperature co-reaction significantly facilitated the reduction of phosphogypsum to SO_2 and the exchange of K^+(K-feldspar) with Ca^(2+)(CaSO_4 in phosphogypsum). The reaction parameters were systematically investigated with the highest sulfur recovery ratio of ~ 60% and K extraction ratio of ~ 87.7%. This novel methodology possesses an energy consumption reduction of ~ 28% and CO_2 emission reduction of ~ 55% comparing with the present typical commercial technologies for utilization of K-feldspar and the treatment of phosphogypsum.
文摘Selected non-burned method and took fly-ash as main material, together with lime and gypsum, to inspire the activity of volcanic ash, took a kind of poly-organics to re-place the clay as binder, and then made small balls with machine, wrapped slurry twice and autoclaved 8 hours at normal atmosphere, made ceramsite in this way can endure higher compression strength. Comparing with common concrete, the ceramsite concrete is about 25% lighter on weight.
