The volume defects in pure pyrite and quartz from a classical Cu-Pb-Zn-Fe sulfide deposit were investigated.The results indicate that a large number of volume defects exist in natural pyrite and quartz.The volume defe...The volume defects in pure pyrite and quartz from a classical Cu-Pb-Zn-Fe sulfide deposit were investigated.The results indicate that a large number of volume defects exist in natural pyrite and quartz.The volume defects assume a variety of shapes,including long strips,oval shapes and irregular shapes,with sizes ranging from a few microns to dozens of microns.These volume defects are rich in metallogenic elements as a result of the capture of metallogenic and mineralizing fluid during the defect-forming process.The volume defects are fractured during the grinding process,and their chemical components are released into the solution,as confirmed by the abundant presence of various metal and non-metal components in the cleaning water and EDS results.Under the experimental conditions of 10 g pyrite or quartz with grinding fineness of d90=37 μm,which was cleaned in 40 m L of pure deionised water under an inert atmosphere,the total average concentrations of Cu,Pb,Zn,Fe,Ca,Mg and Cl-in the aqueous solution are 32.09×10^-7,16.51×10^-7,19.45×10^-7,516.52×10^-7,129.50×10^-7,35.30×10^-7 and 433.80×10^-7 mol/L,respectively,for pyrite and 19.20×10^-7,8.88×10^-7,8.31×10^-7,82.71×10^-7,16.21×10^-7,4.28×10^-7 and 731.26×10^-7 mol/L,respectively,for quartz.These values are significantly greater than those from the experimental non-oxidative dissolution of the pyrite or quartz,respectively.Therefore,the metallogenic fluid in volume defects of mineral crystal is concluded to represent the dominant contribution to the solution chemistry of sulfide flotation pulp.The present investigation will help to deeply understand the flotation theory of sulfide minerals.展开更多
The Qiangsheng gold deposit belongs to quartz vein type. The fluid inclusions consist of four types： aqueous single-phase inclusions, aqueous two-phase inclusions, carbonated two-phase inclusions and carbona- ted thr...The Qiangsheng gold deposit belongs to quartz vein type. The fluid inclusions consist of four types： aqueous single-phase inclusions, aqueous two-phase inclusions, carbonated two-phase inclusions and carbona- ted three-phase inclusions. The fluid inclusions are characterized by low salinity （5%-9% NaCl eqv） , low density （0.66-0.72 g/cm^3 ） and medium temperature （210℃-250℃）. The pressure of ore-forming is 60-95 MPa and the metallogenic depth is about 5.49-7.56 km. During the mineralizing process, ore-forming fluid under- went fluid unmixing in CO2-H2O-NaCl system. The stable isotope resuhs indicate that the ore-forming fluids mainly generated from mantle, with the participation of a small amount of atmospheric water. Comprehensive studies have suggested that Qiangsheng gold deposit belongs to the type of mesothermal hydrotherm with mantlederived fluid participating in mineralization.展开更多
基金Project(51464029)supported by the National Natural Science Foundation of ChinaProject(2014M562343)supported by the China Postdoctoral Science FoundationProject(KKSY201421110)supported the Scholar Development Project of Yunnan Province,China
文摘The volume defects in pure pyrite and quartz from a classical Cu-Pb-Zn-Fe sulfide deposit were investigated.The results indicate that a large number of volume defects exist in natural pyrite and quartz.The volume defects assume a variety of shapes,including long strips,oval shapes and irregular shapes,with sizes ranging from a few microns to dozens of microns.These volume defects are rich in metallogenic elements as a result of the capture of metallogenic and mineralizing fluid during the defect-forming process.The volume defects are fractured during the grinding process,and their chemical components are released into the solution,as confirmed by the abundant presence of various metal and non-metal components in the cleaning water and EDS results.Under the experimental conditions of 10 g pyrite or quartz with grinding fineness of d90=37 μm,which was cleaned in 40 m L of pure deionised water under an inert atmosphere,the total average concentrations of Cu,Pb,Zn,Fe,Ca,Mg and Cl-in the aqueous solution are 32.09×10^-7,16.51×10^-7,19.45×10^-7,516.52×10^-7,129.50×10^-7,35.30×10^-7 and 433.80×10^-7 mol/L,respectively,for pyrite and 19.20×10^-7,8.88×10^-7,8.31×10^-7,82.71×10^-7,16.21×10^-7,4.28×10^-7 and 731.26×10^-7 mol/L,respectively,for quartz.These values are significantly greater than those from the experimental non-oxidative dissolution of the pyrite or quartz,respectively.Therefore,the metallogenic fluid in volume defects of mineral crystal is concluded to represent the dominant contribution to the solution chemistry of sulfide flotation pulp.The present investigation will help to deeply understand the flotation theory of sulfide minerals.
基金Supported by projects of Geological Exploration of Jilin Province(No.22201300111)Shanhou Gold Deposit of Laixi of Shandong Province(SDLX2012-3-28)
文摘The Qiangsheng gold deposit belongs to quartz vein type. The fluid inclusions consist of four types： aqueous single-phase inclusions, aqueous two-phase inclusions, carbonated two-phase inclusions and carbona- ted three-phase inclusions. The fluid inclusions are characterized by low salinity （5%-9% NaCl eqv） , low density （0.66-0.72 g/cm^3 ） and medium temperature （210℃-250℃）. The pressure of ore-forming is 60-95 MPa and the metallogenic depth is about 5.49-7.56 km. During the mineralizing process, ore-forming fluid under- went fluid unmixing in CO2-H2O-NaCl system. The stable isotope resuhs indicate that the ore-forming fluids mainly generated from mantle, with the participation of a small amount of atmospheric water. Comprehensive studies have suggested that Qiangsheng gold deposit belongs to the type of mesothermal hydrotherm with mantlederived fluid participating in mineralization.
