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石非石 山非山 试析当代赏石艺术跨界融合的五大趋势
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作者 徐跃龙 《宝藏》 2016年第2期91-93,18,共4页
在"互联网+"的时代,"跨界融合"已成为一个热门关键词。而当代中国赏石艺术发展大势下,我们也不难发现众多跨界融合现象:比如世界著名建筑大师贝聿铭在苏州博物馆庭院创作的《片石假山》,雕塑家展望的不锈钢《假山... 在"互联网+"的时代,"跨界融合"已成为一个热门关键词。而当代中国赏石艺术发展大势下,我们也不难发现众多跨界融合现象:比如世界著名建筑大师贝聿铭在苏州博物馆庭院创作的《片石假山》,雕塑家展望的不锈钢《假山石》系列作品,软雕塑家施慧的纤维雕塑太湖石作品,当代艺术家徐累、丁乙的假山石装置艺术,当代艺术家陈原川研山索远系列作品……。 展开更多
关键词 赏石 当代艺术家 苏州博物馆 系列作品 著名建筑大师 石非 石假山 贝聿铭 研山 陶瓷艺术大师
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Failure mechanisms and destruction characteristics of cemented coal gangue backfill under compression effect of non-uniform load
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作者 FENG Guo-rui GUO Wei +5 位作者 QI Ting-ye LI Zhu CUI Jia-qing WANG Hao-chen CUI Ye-kai MA Jing-kai 《Journal of Central South University》 SCIE EI CAS CSCD 2024年第8期2676-2693,共18页
Backfill mining is one of the most important technical means for controlling strata movement and reducing surface subsidence and environmental damage during exploitation of underground coal resources. Ensuring the sta... Backfill mining is one of the most important technical means for controlling strata movement and reducing surface subsidence and environmental damage during exploitation of underground coal resources. Ensuring the stability of the backfill bodies is the primary prerequisite for maintaining the safety of the backfilling working face, and the loading characteristics of backfill are closely related to the deformation and subsidence of the roof. Elastic thin plate model was used to explore the non-uniform subsidence law of the roof, and then the non-uniform distribution characteristics of backfill bodies’ load were revealed. Through a self-developed non-uniform loading device combined with acoustic emission (AE) and digital image correlation (DIC) monitoring technology, the synergistic dynamic evolution law of the bearing capacity, apparent crack, and internal fracture of cemented coal gangue backfills (CCGBs) under loads with different degrees of non-uniformity was deeply explored. The results showed that: 1) The uniaxial compressive strength (UCS) of CCGB increased and then decreased with an increase in the degree of non-uniformity of load (DNL). About 40% of DNL was the inflection point of DNL-UCS curve and when DNL exceeded 40%, the strength decreased in a cliff-like manner;2) A positive correlation was observed between the AE ringing count and UCS during the loading process of the specimen, which was manifested by a higher AE ringing count of the high-strength specimen. 3) Shear cracks gradually increased and failure mode of specimens gradually changed from “X” type dominated by tension cracks to inverted “Y” type dominated by shear cracks with an increase in DNL, and the crack opening displacement at the peak stress decreased and then increased. The crack opening displacement at 40% of the DNL was the smallest. This was consistent with the judgment of crack size based on the AE b-value, i. e., it showed the typical characteristics of “small b-value-large crack and large b-value-small crack”. The research results are of significance for preventing the instability and failure of backfill. 展开更多
关键词 cemented coal gangue backfill non-uniform load degree of non-uniformity of load failure mode crack opening displacement
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A rock-physical modeling method for carbonate reservoirs at seismic scale 被引量:9
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作者 李景叶 陈小宏 《Applied Geophysics》 SCIE CSCD 2013年第1期1-14,117,共15页
Strong heterogeneity and complex pore systems of carbonate reservoir rock make its rock physics model building and fluid substitution difficult and complex. However, rock physics models connect reservoir parameters wi... Strong heterogeneity and complex pore systems of carbonate reservoir rock make its rock physics model building and fluid substitution difficult and complex. However, rock physics models connect reservoir parameters with seismic parameters and fluid substitution is the most effective tool for reservoir prediction and quantitative characterization. On the basis of analyzing complex carbonate reservoir pore structures and heterogeneity at seismic scale, we use the gridding method to divide carbonate rock into homogeneous blocks with independent rock parameters and calculate the elastic moduli of dry rock units step by step using different rock physics models based on pore origin and structural feature. Then, the elastic moduli of rocks saturated with different fluids are obtained using fluid substitution based on different pore connectivity. Based on the calculated elastic moduli of rock units, the Hashin-Shtrikman-Walpole elastic boundary theory is adopted to calculate the carbonate elastic parameters at seismic scale. The calculation and analysis of carbonate models with different combinations of pore types demonstrate the effects of pore type on rock elastic parameters. The simulated result is consistent with our knowledge of real data. 展开更多
关键词 Seismic scale fluid substitution carbonate rock rock physics modeling^heterogeneity
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Modeling of rock failure based on physical cellular automata 被引量:5
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作者 马志涛 谭云亮 张霆 《Journal of Southeast University(English Edition)》 EI CAS 2005年第3期348-352,共5页
To analyze the effects of heterogeneous material characteristics on rock failure,a micro-heterogeneous physical cellular automata (Mh-PCA) model is introduced according to the cellular automata theory from a general... To analyze the effects of heterogeneous material characteristics on rock failure,a micro-heterogeneous physical cellular automata (Mh-PCA) model is introduced according to the cellular automata theory from a general power view.In this model,the neighbor is the Moore pattern and the Weibull distribution is adopted to simulate the rock heterogeneousness.Using this model,the evolvements and acoustic emission of rock failure are simulated for four materials of different degree of homogeneousness (m=1,5,10,15).The results show that the heterogeneous characteristic has a great effect on the rock failure,the more the homogeneousness,the fewer the crack branches and the more concentrated acoustic emissions.The physical cellular automata theory gives a new idea for studying rock failure. 展开更多
关键词 rock failure acoustic emission heterogeneous characteristic physical cellular automata Weibull distribution
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Self-heating tendency evaluation of sulfide ores based on nonlinear multi-parameters fusion 被引量:1
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作者 潘伟 吴超 +1 位作者 李孜军 杨月平 《Transactions of Nonferrous Metals Society of China》 SCIE EI CAS CSCD 2015年第2期582-589,共8页
In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials ... In order to reveal the nonlinear dynamics characteristics of unsteady self-heating process of sulfide ores, nine different kinds of sulfide ore samples from a pyrite mine in China were taken as experimental materials and their self-heating characteristics were measured in laboratory. Furthermore, the measured temperature was studied by integrating wavelet transform, nonlinear characteristic parameters extraction and fuzzy comprehensive evaluation. The results indicate that only the ore samples 1, 2, 6 and 9 have obvious self-heating phenomenon, and their self-heating initiative temperatures are 220 ℃, 239 ℃, 220 ℃ and 220 ℃, respectively, which means that they are difficult to produce self-heating under normal mining conditions. The correlation dimension of self-heating process is fraction and the maximum Lyapunov exponent is positive, which means that it is feasible to study the self-heating process based on chaotic dynamics theory. The nonlinearities of self-heating process of these four samples (ore samples 1, 2, 6 and 9) are 0.8227, 0.7521, 0.9401 and 0.8827 respectively and the order of the samples according to these results is: sample 6, sample 9, sample 1, sample 2, which is consistent with the measured results of self-heating characteristics. Therefore, the nonlinearity method can be used to evaluate the self-heating tendency of sulfide ores, and it is an effective verification of the reliability of measured results. 展开更多
关键词 sulfide ores self-heating process nonlinear characteristic parameter NONLINEARITY self-heating tendency
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戴震金石文字观述论 被引量:2
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作者 徐道彬 《史学集刊》 CSSCI 北大核心 2005年第2期50-54,共5页
清儒大量运用金石文字考经证史是清代学术较为突出的特点之一。钱大昕、阮元之功已为学界所共认,但引领一代学风的考据学大师戴震在金石文字方面的实践及观点无人提及。而有相关实例来看,戴氏在运用金石文字考证经史方面颇有成绩,值得... 清儒大量运用金石文字考经证史是清代学术较为突出的特点之一。钱大昕、阮元之功已为学界所共认,但引领一代学风的考据学大师戴震在金石文字方面的实践及观点无人提及。而有相关实例来看,戴氏在运用金石文字考证经史方面颇有成绩,值得关注。 展开更多
关键词 戴震 金石文字 《石经补字正非》
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思念里的流浪狗
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作者 方晔云 丁志武 《校园文苑(小学版)》 2004年第19期4-7,共4页
背影是真的,人是假的,没什么执着,一百年后你不是你,我不是我;悲哀是真的,泪是假的,本来没因果,一百年后没有你,也没有我。
关键词 流浪狗 衣食无忧 半梦半醒 告诉我 陆真 你我 给你 石非 宠物店 京巴
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Numerical simulation on effect of heterogeneity on modeΙfracture characteristics of rock 被引量:5
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作者 WANG Jin-tao ZUO Jian-ping 《Journal of Central South University》 SCIE EI CAS CSCD 2020年第10期3063-3077,共15页
Rock is more sensitive to tensile loading than compressive loading,since the tensile strength of rock is much lower than compressive strength.The fracture characteristics of rock in the tensile state are of great sign... Rock is more sensitive to tensile loading than compressive loading,since the tensile strength of rock is much lower than compressive strength.The fracture characteristics of rock in the tensile state are of great significance to the understanding of rock failure mechanisms.To this end,we have conducted numerical simulation researches on modeⅠcracking process of rock with varying homogeneity,using the Realistic Failure Process Analysis program.With the increase of homogeneity,cracks are concentrating to the ligament area with a decreasing number of crack bifurcations,and the main crack path is becoming smooth.Crack behaviors and mechanical properties are influenced significantly when the homogeneity index is in the range of 1.5 to 5.When the homogeneity index is greater than 30,they are not affected by rock homogeneity and the rock can be considered as essentially homogeneous.It is considered that the global and local strengths are affected by the distribution of rock mechanical properties at mesoscale,which influence the crack behaviors and mechanical characteristics. 展开更多
关键词 rock heterogeneity crack evolution subcritical crack growth fracture mechanism
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Effects of porosity heterogeneity on chemical dissolution-front instability in fluid-saturated rocks 被引量:4
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作者 ZHAO Chong-bin Peter SCHAUBS Bruce HOBBS 《Journal of Central South University》 SCIE EI CAS CSCD 2017年第3期720-725,共6页
Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys ... Homogeneity and heterogeneity are two totally different concepts in nature.At the particle length scale,rocks exhibit strong heterogeneity in their constituents and porosities.When the heterogeneity of porosity obeys the random uniform distribution,both the mean value and the variance of porosities in the heterogeneous porosity field can be used to reflect the overall heterogeneous characteristics of the porosity field.The main purpose of this work is to investigate the effects of porosity heterogeneity on chemical dissolution front instability in fluid-saturated rocks by the computational simulation method.The related computational simulation results have demonstrated that:1) since the propagation speed of a chemical dissolution front is inversely proportional to the difference between the final porosity and the mean value of porosities in the initial porosity field,an increase in the extent of the porosity heterogeneity can cause an increase in the mean value of porosities in the initial porosity field and an increase in the propagation speed of the chemical dissolution front.2) An increase in the variance of porosities in the initial porosity field can cause an increase in the instability probability of the chemical dissolution front in the fluid-saturated rock.3) The greater the mean value of porosities in the initial porosity field,the quicker the irregular morphology of the chemical dissolution front changes in the supercritical chemical dissolution systems.This means that the irregular morphology of a chemical dissolution front grows quicker in a porosity field of heterogeneity than it does in that of homogeneity when the chemical dissolution system is at a supercritical stage. 展开更多
关键词 porosity heterogeneity chemical dissolution front instability computational simulation porous rocks
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Optical Resolution of DL-Tartaric Acid Mediated by Diastereomeric Salts Crystallization: A Useful Method for Exploring and Optimizing Experimental Conditions 被引量:1
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作者 LolaKokila 蔡水洪 陈孔常 《Chinese Journal of Chemical Engineering》 SCIE EI CAS CSCD 2002年第2期244-248,共5页
A response surface modeling approach for simultaneous optimization of optical purity and yield was applied to the resolution of tartaric acid to study the effects of both the amount of the solvent and the amount of th... A response surface modeling approach for simultaneous optimization of optical purity and yield was applied to the resolution of tartaric acid to study the effects of both the amount of the solvent and the amount of the resolving agent a-methylbenzyl amine on the resolution results. The direction of changing the experimental conditions was determined from the initial response study, and expected high yield of the pure L(+)-tartaric acid-L(-)-a-methylbenzyl amine salt was obtained. 展开更多
关键词 RESOLUTION optimization central composite rotatable design modeling
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Effect of heterogeneity on mechanical and acoustic emission characteristics of rock specimen 被引量:8
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作者 李术才 李国莹 《Journal of Central South University》 SCIE EI CAS 2010年第5期1119-1124,共6页
The influence of heterogeneity on mechanical and acoustic emission characteristics of rock specimen under uniaxial compress was studied with numerical simulation methods.Weibull distribution function was adopted to de... The influence of heterogeneity on mechanical and acoustic emission characteristics of rock specimen under uniaxial compress was studied with numerical simulation methods.Weibull distribution function was adopted to describe the mesoscopic heterogeneity of rocks.The failure process of heterogeneous rock specimen under uniaxial loading was simulated using FLAC 3D software.Five schemes were adopted to investigate the influence of heterogeneity.The results demonstrate that as the homogeneity increases,the peak strength and brittleness of rocks increase,and the macro elastic modulus improves as well.Heterogeneity has great influence on macro elastic modulus and strength when the homogeneity coefficient is less than 20.0.The volume expansion is not so obvious when the homogeneity increases.As the homogeneity coefficient increases the acoustic emissions modes change from swarm shock to main shock.When the homogeneity coefficient is high,the cumulative acoustic emission events-axial strain curve is gentle before the rock failure.The numerical results agree with the previously numerical results and earlier experimental measurements. 展开更多
关键词 HETEROGENEITY acoustic emission strain softening numerical simulation uniaxial compression elastic modulus
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Ordovician limestone aquosity prediction using nonlinear seismic attributes:Case from the Xutuan coal mine
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作者 黄亚平 董守华 耿建华 《Applied Geophysics》 SCIE CSCD 2009年第4期359-366,394,395,共10页
Ordovician limestone water is coal mines. In this paper, we analyze the the main source of water inrush in North China characteristic of three kinds of nonlinear seismic attributes, such as the largest lyapunov expone... Ordovician limestone water is coal mines. In this paper, we analyze the the main source of water inrush in North China characteristic of three kinds of nonlinear seismic attributes, such as the largest lyapunov exponent,fractal dimension and entropy and introduce their calculation methods. Taking the 81st and 82nd coal districts in the Xutuan coal mine as examples, we extract the three seismic attributes based on the 3D prestack migration seismic data of this area, which can display the Ordovician limestone fracture distribution in the mine. We comprehensively analyzed the three nonlinear seismic attributes and compared the results with transient electromagnetic exploration results and determined the possible Ordovician limestone aquosity distribution. This demonstrated that the nonlinear seismic attributes technology is an effective approach to predict the aquosity of Ordovician limestone. 展开更多
关键词 nonlinear seismic attribute LIMESTONE aquosity PREDICTION
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Debris Flow Disaster Prevention and Mitigation of NonStructural Strategies in Taiwan 被引量:6
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作者 CHEN Su-Chin WU Chun-Yi 《Journal of Mountain Science》 SCIE CSCD 2014年第2期308-322,共15页
Taiwan has disadvantageous conditions for sediment-related disasters such as debris flows. The construction of engineering structures is an effective strategy for reducing debris flow disasters. However, it is impossi... Taiwan has disadvantageous conditions for sediment-related disasters such as debris flows. The construction of engineering structures is an effective strategy for reducing debris flow disasters. However, it is impossible to construct engineering structures in all debris flow areas in a short period. Therefore, the government aims to gradually develop non-structural preventive strategies, including evacuation planning, debris flow disaster emergency action system, disaster resistant community program, recruitment of debris flow professional volunteers, debris flow warning systems, and land management strategies, to mitigate disasters and secure the safety of residents. This review describes the processes and effects of recent debris flow non-structural preventive strategies in Taiwan. The average number of casualties prior to the year 2000 was far higher than the corresponding number after 2000 because debris flow evacuation drills have been promoted since 2000 and the debris flow disaster emergency action system has been progressively improved since 2002. Furthermore, the changes in risks caused by debris flow disasters before and after the implementation of non-structural preventive strategies were used to explain the effectiveness of these strategies at the community level. The results showed that softwarebased non-structural preventive strategies can effectively reduce the casualties caused by debris flows at both the national and community levels. 展开更多
关键词 Debris flow Warning systems Evacuation planning Rainfall threshold Preventive strategies
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Flotation tree analysis for recovery of sillimanite from red sediments
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作者 Laxmi T. Rao R.Bhima 《International Journal of Mining Science and Technology》 SCIE EI CSCD 2015年第5期843-848,共6页
In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes ... In this paper an attempt is made to recover sillimanite by flotation tree analysis process and conventional flotation process from non magnetic fraction of red sediments.The experimental results of both the processes are presented.The data reveal that the deslimed sample contains 33.2%(by weight) total heavy minerals and out of which the sillimanite mineral content is 3.6%(by weight).It is observed that flotation tree analysis needs 10 cells to get five output products and where as conventional flotation process needs 15 cells to recover similar grade of five output products.Thus,flotation tree analysis is not only economic process but also efficient process(to say efficient process,the tree analysis product should be higher grade). 展开更多
关键词 Tree analysis FLOTATION Red sediment SILLIMANITE
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Minimum safe thickness of rock plug in karst tunnel according to upper bound theorem 被引量:11
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作者 YANG Zi-han ZHANG Jia-hua 《Journal of Central South University》 SCIE EI CAS CSCD 2016年第9期2346-2353,共8页
High pressure and water-bearing caverns ahead of a karst tunnel face tend to cause geological disasters, such as water and mud bursts. So, the determination of safe thickness of the reserved rock plug is a key technic... High pressure and water-bearing caverns ahead of a karst tunnel face tend to cause geological disasters, such as water and mud bursts. So, the determination of safe thickness of the reserved rock plug is a key technical problem to be solved for karst tunnel construction. Based on the Hoek-Brown nonlinear failure criterion, the minimum safe thickness of rock plug was investigated in the light of the limit analysis theory. On the basis of the proposed failure mode, the expression of the minimum thickness for rock plug was obtained by means of upper bound theorem in combination with variational principle. The calculation results show the influence of each parameter on safe thickness and reveal the damage range of rock plug. The proposed method is verified by comparing the results with those of the drain cavern of Maluqing Tunnel. The research shows that with the increase of compressive strength and tensile strength as well as constant A of Hoek-Brown criterion, the safe thickness decreases, whereas with the increase of cavern pressure, tunnel diameter, and constant B from Hoek-Brown criterion, the safe thickness increases. Besides, the tensile strength, or constants A and B affect the shear failure angle of rock plug structure, but other parameters do not. In conclusion, the proposed method can predict the minimum safe thickness of rock plug, and is useful for water burst study and prevention measures of tunnels constructed in high-risk karst regions. 展开更多
关键词 karst tunnels rock plug minimum safe thickness upper limit theorem failure mode
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Deposition of diamond like carbon films by using a single ion gun with varying beam source
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作者 姜金球 陈祝平 《Journal of Coal Science & Engineering(China)》 2001年第1期80-83,共4页
Diamond like carbon films have been successfully deposited on the steel substrate, by using a single ion gun with varying beam source. The films may appear blue, yellow and transparent in color, which was found relate... Diamond like carbon films have been successfully deposited on the steel substrate, by using a single ion gun with varying beam source. The films may appear blue, yellow and transparent in color, which was found related to contaminants from the sample holder and could be avoided. The thickness of the films ranges from tens up to 200 nanometers, and the hardness is in the range 20 to 30 GPa. Raman analytical results reveal the films are in amorphous structure. The effects of different beam source on the films structure are further discussed. 展开更多
关键词 ion beam deposition diamondlike carbon thin film beam source primary process
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Policies for Unconventional Oil and Gas Resources in China 被引量:1
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作者 Zheng Zhihong Zhu Jie Yang Hulin 《China Oil & Gas》 CAS 2015年第3期9-14,共6页
Regarding the abundant reserves in China, unconventional oil and gas resources has great potential in exploration and development, and may be the significant complement to conventional oil and gas resources. Based on ... Regarding the abundant reserves in China, unconventional oil and gas resources has great potential in exploration and development, and may be the significant complement to conventional oil and gas resources. Based on the summary of the reservoir potential and current situation of exploration and development of unconventional oil and gas resources, such as coalbed methane(CBM), shale gas and oil shale, we analyzed the incentive policies proposed to promote the development of unconventional oil and gas industry, including industrial planning, resource management and related tax policy. These policies played an important role in promoting the exploration, development and utilization of unconventional oil and gas resources. 展开更多
关键词 unconventional CBM shale gas oil shale policy
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Deposition Morphology of Non-homogeneous Debris Flow and Its Energy Characteristics
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作者 SHU An-ping TANG Chuan +2 位作者 ZHANG Xin SHAO Song-dong YANG Kai 《Journal of Mountain Science》 SCIE CSCD 2015年第5期1157-1168,共12页
Non-homogeneous two-phase debris flows are widely found in the western mountainous regions of China. To investigate the characteristics of the debris flow deposition process related to the morphology and extent of the... Non-homogeneous two-phase debris flows are widely found in the western mountainous regions of China. To investigate the characteristics of the debris flow deposition process related to the morphology and extent of the debris fan, a series of physical experiments were carried out using an experimental flume. Some useful relationships were obtained to link the flow velocity with the geometric characteristics of deposition morphology and the corresponding area or volume. Based on these, some expressions about energy dissipation process in both the transport-deposition zone and deposition zone are presented, and improved equations describing solidliquid two-phase energy transformations in the specific deposition zone are also established. These results provide a basis for further investigating the underlying mechanisms of non-homogeneous debris flows, based upon which effective disaster control measures can be undertaken. 展开更多
关键词 Non-homogeneous debris flow Deposition morphology Debris flow velocity Energydissipation
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Fluid components in accessory minerals of Pan-African granitoids in the S■r Rondane Mountains, East Antarctica
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作者 LI Zi-long CHEN Han-lin +3 位作者 YANG Shu-feng TAINOSHO Yoshiaki SHIRAISHI Kazuyuki OWADA Masaaki 《Journal of Zhejiang University-Science A(Applied Physics & Engineering)》 SCIE EI CAS CSCD 2007年第7期1004-1010,共7页
Fluids (fluorine, chlorine, and OH) in accessory minerals (apatite, titanite and allanite) of Pan-African granitoids (Group-I granitoids, Group-II granitoids and Mefjell Plutonic Complex) from the Sor Rondane Mo... Fluids (fluorine, chlorine, and OH) in accessory minerals (apatite, titanite and allanite) of Pan-African granitoids (Group-I granitoids, Group-II granitoids and Mefjell Plutonic Complex) from the Sor Rondane Mountains, East Antarctica were precisely measured by an electronic microprobe analyzer in this study. Apatites in the granites have commonly high fluorine contents. However, fluorine contents from the Group-Ⅰ, Group-Ⅱ granitoids and Mefjell Plutonic Complex (MPC) are of important variation, which F contents (3.21-7.20 wt%) in apatite from the Group-Ⅱ granitoids are much higher than those from the Group-Ⅰ granitoids (1.22-3.60 wt%) and the MPC (3.21-4.11 wt%). Titanite in the MPC has a low fluorine content (0.23-0.50 wt%), being less than those in the Group-Ⅰ granitoids (2.28 wt%) and Group-Ⅱ granitoids (1.85-2.78 wt%). Fluorine in allanite in the Group-Ⅱ granitoids seems to have much lower contents than those from the Group-Ⅰ granitoids and the MPC. Higher fluorine contents in the titanite from the Group-Ⅱ granitoids may be mainly controlled by late-magmatic fluid-rock interaction processes associated with melt, but may not be indicative of original magma contents based on its petrographic feature, Due to very lower chlorine contents from all of accessory minerals, the authors suggest that titanite and apatite with higher fluorine contents in the Group-Ⅱ granitoids have much lower H2O (OH) contents compared with those in the Group-Ⅰ granitoids according to the partition among (F, Cl, OH). Fluorine contents in whole-rock samples show a variation from the higher in the Group-Ⅰ granitoids to the lower in the Group-Ⅱ granitoids and the MPC, which are consistent with the changes of those from the biotite and hornblende as well as fluorite occurred in the Group-Ⅰ granitoids reported previously. Based on the above study of fluorine in accessory minerals and combined with the previous fluorine contents from biotites and hornblendes, the authors suggest that apatites and titanites with higher F contents in the Group-Ⅱ granitoids and the MPC may not be an indicator of higher fluorine contents in whole-rock, which reflect fluorine contents in magma sources and/or late-thermal activity. Higher fluorine contents in apatite, titanite and allanite may be an additional evidence of A-type affinity. 展开更多
关键词 Fluorine contents Accessory minerals Pan-African granitoids Sor Rondane Mountains ANTARCTICA
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2D metal‐free heterostructure of covalent triazine framework/g‐C_(3)N_(4) for enhanced photocatalytic CO_(2) reduction with high selectivity 被引量:3
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作者 Jie He Xuandong Wang +2 位作者 Shangbin Jin Zhao‐Qing Liu Mingshan Zhu 《Chinese Journal of Catalysis》 SCIE EI CAS CSCD 2022年第5期1306-1315,共10页
Solar‐driven CO_(2)conversion to precious fossil fuels has been proved to become a potential way to decrease CO_(2)with producing renewable fuels,which mainly relies on photocatalysts with efficient charge separation... Solar‐driven CO_(2)conversion to precious fossil fuels has been proved to become a potential way to decrease CO_(2)with producing renewable fuels,which mainly relies on photocatalysts with efficient charge separation.In this work,a metal free heterostructure of covalent triazine framework(CTF)and graphite carbon nitride(g‐C_(3)N_(4),abbreviated as CN)is applied in the CO_(2)photoreduction for the first time.Detailed characterization methods such as photoluminescence(PL)and time‐resolved PL(TR‐PL)decay are utilized to reveal the photo‐induced carries separating process on g‐C_(3)N_(4)/CTF(CN/CTF)heterostructure.The introduced CTF demonstrated a great boosting photocatalytic activity for CN,bringing about the transform rates of CO_(2)to CO reaching 151.1μmol/(g·h)with a 30 h stabilization time,while negligible CH_(4)was detected.The optimal CN/CTF heterostructure could more efficiently separate charges with a lower probability of recombination under visible light irradiation,which made the photoreduction efficiency of CO_(2)to CO be 25.5 and 2.5 times higher than that of CTF and CN,respectively.This investigation is expected to offer a new thought for fabricating high‐efficiency photocatalyst without metal in solar‐energy‐driven CO_(2)reduction. 展开更多
关键词 CO_(2)reduction Covalent triazine framework Graphite carbon nitride Metal‐free heterostructure Photocatalysis
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