同化混染对五大连池石龙岩的影响及石龙岩成因探讨

黑龙江五大连池火山群钾质火山岩,曾被小仓勉(1936)定名为“石龙岩”。关于它的成因,除牛来正夫(1940)基于岩石中有大量熔蚀的花岗岩捕虏体及捕虏晶存在,认为它是钠质碱性玄武岩同化花岗岩形成的(以下称“同化说”)以外,别无详细的研究。

五大连池世界地质公园曾经山崩

老黑山、火烧山火山是著名的黑龙江省五大连池火山群中的两座火山,五大连池火山群有14座火山。以往一直认为老黑山、火烧山火山为公元1720-1721年(清朝康熙年间)喷发形成。正是此次喷出的大规模的碱性玄武岩,即著名的"石龙岩",堵塞了乌德邻河故道,形成五个堰塞湖,即五大连池。波涛翻滚的渣状熔岩和千姿百态的绳状熔岩使这里成为享誉海内外的世界地质公园和火山博物馆。

年产30万吨硝酸铵生产装置建设

一、项目名称年产30万吨硝酸铵生产装置建设二、项目建设地点泸州市纳溪区三、项目建设内容借助四川在泸州化工园区打造200亿立方米煤气化基地项目,发展煤化工下游产业,新建30万吨年硝酸铵生产装置,其中:多孔硝酸铵年产量10万吨,其余20万吨硝酸铵溶液作为硝基复合肥装置原料。

Shales in the Qiongzhusi and Wufeng–Longmaxi Formations:a rock-physics model and analysis of the effective pore aspect ratio

The shales of the Qiongzhusi Formation and Wufeng-Longmaxi Formations at Sichuan Basin and surrounding areas are presently the most important stratigraphic horizons for shale gas exploration and development in China. However, the regional characteristics of the seismic elastic properties need to be better determined. The ultrasonic velocities of shale samples were measured under dry conditions and the relations between elastic properties and petrology were systemically analyzed. The results suggest that 1） the effective porosity is positively correlated with clay content but negatively correlated with brittle minerals, 2） the dry shale matrix consists of clays, quartz, feldspars, and carbonates, and 3） organic matter and pyrite are in the pore spaces, weakly coupled with the shale matrix. Thus, by assuming that all connected pores are only present in the clay minerals and using the Gassmann substitution method to calculate the elastic effect of organic matter and pyrite in the pores, a relatively simple rock-physics model was constructed by combining the self-consistent approximation （SCA）, the differential effective medium （DEM）, and Gassmann＇s equation. In addition, the effective pore aspect ratio was adopted from the sample averages or estimated from the carbonate content. The proposed model was used to predict the P-wave velocities and generally matched the ultrasonic measurements very well.

Emplacement age and tectonic implications of the brecciated limestone at the edge of the Longmenshan klippe

The Longmenshan thrust belt(LMTB) is one of the best natural laboratories for thin-skinned tectonics and has developed a series of NE-SW trending fold-and-thrust structures represented by a series of nappes and klippes, exemplified by the Tangbazi and Bailuding klippe. However, the timing and emplacement mechanism of these klippes are still in dispute. Three possible mechanisms have been proposed:(1) a Mesozoic-Cenozoic southeastward thrusting,(2) a Cenozoic gravity gliding, and(3) glacial deposition. Almost all of these klippes are tectonic and overlaid on folded Late Triassic sandstone except the Tangbazi klippe, which is located in the center of the LMTB and has a narrow tail extending southeastward and covering Jurassic-Quaternary rocks. This geometric relationship is considered the most important stratigraphic evidence to support the post-Cenozoic emplacement of the Longmenshan klippe. Our structural and petrological observations show that the rocks at the front of the Tangbazi and Bailuding structures are brecciated limestone, which is assumed to have been generated by a gravitational collapse and is not characteristic of the massive Permian strata. Artemisia pollen, which has been exclusively recognized in post-Late Eocene strata in Central Asia, was found in the matrix of this brecciated limestone. Therefore, our discovery indicates that the brecciated limestone was deposited after the Late Eocene rather than during the Permian as annotated on the geological map. In contrast, unbrecciated, massive Permian limestone overlaid on the folded Late Triassic rocks. Hence, the anomalous relationship of Permian strata overlaying Late Triassic rocks cannot be evidence of Cenozoic emplacement. According to currently recognized bulk strata relationships, we can only be sure that the klippe was emplaced in the post Late Triassic. The petrological characteristics of the brecciated limestone show that it was crumbled before the re-sedimentation of the breccia, implying that the LMTB might have experienced a rapid uplift during the Late Eocene.

Water-enhanced plastic deformation in felsic rocks

Using Fourier transform infrared spectroscopy(FTIR),we measured water contents in quartz and feldspar for four kinds of felsic rocks,i.e.,undeformed granite,banded granitic gneiss,fine-grained felsic mylonite,and fine-grained quartz-mica schist,collected from Pengguan Complex and Kangding Complex in the Longmenshan tectonic zone,Sichuan,China.The absorbance spectra suggest that water in coarse-grained quartz and feldspar of undeformed granite and banded granitic gneiss occurs mainly as hydroxyl in crystal defects,and water in most of fine-grained quartz and feldspar of felsic mylonite is molecular water in inclusions and liquid-type water in grain boundaries,but in some cases it still occurs as hydroxyl in crystal defects.Water content of quartz in undeformed granite is 0.001 wt%-0.009 wt %,and that of feldspar 0.005 wt%-0.02 wt%.The banded granitic gneiss shows water contents of 0.002 wt%-0.011 wt% in quartz and 0.012 wt%-0.036 wt% in feldspar.Quartz ribbon and feldspar ribbon in fine-grained felsic mylonite show that their water contents are similar to those of coarse-grained quartz and feldspar in granite,0.002 wt%-0.011 wt%,and 0.004 wt%-0.02 wt%,respectively.Water contents of fine-grained quartz and feldspar are respectively 0.004 wt%-0.02 wt% and 0.012 wt%-0.06 wt%.Water content of quartz in fine-grained quartz-mica schist is 0.007 wt%-0.15 wt%.Water-bearing minerals display much higher water contents than those of nominally anhydrous minerals,and the percentage of water-bearing minerals in felsic rocks increases with the strain of rocks.These new data indicate that hydroxyl in crystal defects has basically not been released during the shear deformation,and on the contrary,the increase in molecular water in inclusions and liquid-type water in grain boundaries as well as water-bearing minerals after shear deformation leads to a significant increase of the water content in deformed rocks.Based on data of creep tests,it is inferred here that the fine-grained mylonites with more water have much lower strength than that of the weakly deformed coarse-grained rocks in the middle crust,and this indicates that trace amount of water significantly helped develop the ductile shear zone.