The volume defects in pure pyrite and quartz from a classical Cu-Pb-Zn-Fe sulfide deposit were investigated.The results indicate that a large number of volume defects exist in natural pyrite and quartz.The volume defe...The volume defects in pure pyrite and quartz from a classical Cu-Pb-Zn-Fe sulfide deposit were investigated.The results indicate that a large number of volume defects exist in natural pyrite and quartz.The volume defects assume a variety of shapes,including long strips,oval shapes and irregular shapes,with sizes ranging from a few microns to dozens of microns.These volume defects are rich in metallogenic elements as a result of the capture of metallogenic and mineralizing fluid during the defect-forming process.The volume defects are fractured during the grinding process,and their chemical components are released into the solution,as confirmed by the abundant presence of various metal and non-metal components in the cleaning water and EDS results.Under the experimental conditions of 10 g pyrite or quartz with grinding fineness of d90=37 μm,which was cleaned in 40 m L of pure deionised water under an inert atmosphere,the total average concentrations of Cu,Pb,Zn,Fe,Ca,Mg and Cl-in the aqueous solution are 32.09×10^-7,16.51×10^-7,19.45×10^-7,516.52×10^-7,129.50×10^-7,35.30×10^-7 and 433.80×10^-7 mol/L,respectively,for pyrite and 19.20×10^-7,8.88×10^-7,8.31×10^-7,82.71×10^-7,16.21×10^-7,4.28×10^-7 and 731.26×10^-7 mol/L,respectively,for quartz.These values are significantly greater than those from the experimental non-oxidative dissolution of the pyrite or quartz,respectively.Therefore,the metallogenic fluid in volume defects of mineral crystal is concluded to represent the dominant contribution to the solution chemistry of sulfide flotation pulp.The present investigation will help to deeply understand the flotation theory of sulfide minerals.展开更多
Diamonds are renowned as the record of Earth's evolution history.Natural diamonds on the Earth can be distinguished in light of genetic types as kimberlitic diamonds(including peridotitic diamonds and eclogitic di...Diamonds are renowned as the record of Earth's evolution history.Natural diamonds on the Earth can be distinguished in light of genetic types as kimberlitic diamonds(including peridotitic diamonds and eclogitic diamonds),ultrahigh-pressure metamorphic diamonds and ophiolitic diamonds.According to the inclusion mineralogy,most diamonds originated from continental lithospheric mantle at depths of 140-250 km.Several localities,however,yield ultradeep diamonds with inclusion compositions that require a sublithospheric origin(>~250 km).Ultradeep diamonds exhibit distinctions in terms of carbon isotope composition,N-concentration,mineral inclusions and so on.The present study provides a systematic compilation concerning the features of ultradeep diamonds,based on which to expound their genesis affinity with mantle-carbonate melts.The diamond-parental carbonate melts are proposed to be stemmed from the Earth's crust through subduction of oceanic lithosphere.Ultradeep diamonds are classified into a subgroup attaching to kimberlitic diamonds grounded by formation mechanism,and present connections in respect of carbon origin to eclogitic diamonds,ultrahigh-pressure metamorphic diamonds and ophiolitic diamonds.展开更多
By the combination of high-temperature organometallic synthesis and phase transfer through complete ligand-exchange withmixed phosphate, highly water-dispersible Fe3O4nanoparticles with narrow size distribution are ob...By the combination of high-temperature organometallic synthesis and phase transfer through complete ligand-exchange withmixed phosphate, highly water-dispersible Fe3O4nanoparticles with narrow size distribution are obtained, which show appli-cable response to magnetic field. IR and -potential characterization of this system provides insights into ligand structures onparticle surface.展开更多
基金Project(51464029)supported by the National Natural Science Foundation of ChinaProject(2014M562343)supported by the China Postdoctoral Science FoundationProject(KKSY201421110)supported the Scholar Development Project of Yunnan Province,China
文摘The volume defects in pure pyrite and quartz from a classical Cu-Pb-Zn-Fe sulfide deposit were investigated.The results indicate that a large number of volume defects exist in natural pyrite and quartz.The volume defects assume a variety of shapes,including long strips,oval shapes and irregular shapes,with sizes ranging from a few microns to dozens of microns.These volume defects are rich in metallogenic elements as a result of the capture of metallogenic and mineralizing fluid during the defect-forming process.The volume defects are fractured during the grinding process,and their chemical components are released into the solution,as confirmed by the abundant presence of various metal and non-metal components in the cleaning water and EDS results.Under the experimental conditions of 10 g pyrite or quartz with grinding fineness of d90=37 μm,which was cleaned in 40 m L of pure deionised water under an inert atmosphere,the total average concentrations of Cu,Pb,Zn,Fe,Ca,Mg and Cl-in the aqueous solution are 32.09×10^-7,16.51×10^-7,19.45×10^-7,516.52×10^-7,129.50×10^-7,35.30×10^-7 and 433.80×10^-7 mol/L,respectively,for pyrite and 19.20×10^-7,8.88×10^-7,8.31×10^-7,82.71×10^-7,16.21×10^-7,4.28×10^-7 and 731.26×10^-7 mol/L,respectively,for quartz.These values are significantly greater than those from the experimental non-oxidative dissolution of the pyrite or quartz,respectively.Therefore,the metallogenic fluid in volume defects of mineral crystal is concluded to represent the dominant contribution to the solution chemistry of sulfide flotation pulp.The present investigation will help to deeply understand the flotation theory of sulfide minerals.
基金supported by National Natural Science Foundation of China (Grant Nos.U1232204 & 41473056)
文摘Diamonds are renowned as the record of Earth's evolution history.Natural diamonds on the Earth can be distinguished in light of genetic types as kimberlitic diamonds(including peridotitic diamonds and eclogitic diamonds),ultrahigh-pressure metamorphic diamonds and ophiolitic diamonds.According to the inclusion mineralogy,most diamonds originated from continental lithospheric mantle at depths of 140-250 km.Several localities,however,yield ultradeep diamonds with inclusion compositions that require a sublithospheric origin(>~250 km).Ultradeep diamonds exhibit distinctions in terms of carbon isotope composition,N-concentration,mineral inclusions and so on.The present study provides a systematic compilation concerning the features of ultradeep diamonds,based on which to expound their genesis affinity with mantle-carbonate melts.The diamond-parental carbonate melts are proposed to be stemmed from the Earth's crust through subduction of oceanic lithosphere.Ultradeep diamonds are classified into a subgroup attaching to kimberlitic diamonds grounded by formation mechanism,and present connections in respect of carbon origin to eclogitic diamonds,ultrahigh-pressure metamorphic diamonds and ophiolitic diamonds.
基金supported by the National Natural Science Foundation of China (Grant No. 20673031)the National Basic Research Program of China (Grant No. 2011CB932803)
文摘By the combination of high-temperature organometallic synthesis and phase transfer through complete ligand-exchange withmixed phosphate, highly water-dispersible Fe3O4nanoparticles with narrow size distribution are obtained, which show appli-cable response to magnetic field. IR and -potential characterization of this system provides insights into ligand structures onparticle surface.
