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中性pH值下CuO-H_2O_2催化矿化苯酚 被引量:3
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作者 徐夫元 陈英文 +3 位作者 王志良 吴海锁 祝社民 沈树宝 《化学工程》 CAS CSCD 北大核心 2010年第3期80-85,共6页
中性常压条件下研究了不同因素对CuO-H2O2矿化模型底物苯酚的影响。引入H2O2矿化指数(X)、矿化半衰期(t1/2)概念,结合总碳(TOC)去除及氧化剂分解规律,对催化矿化进行分析。结果表明:温度、催化剂、氧化剂、初始TOC质量浓度的增加均能不... 中性常压条件下研究了不同因素对CuO-H2O2矿化模型底物苯酚的影响。引入H2O2矿化指数(X)、矿化半衰期(t1/2)概念,结合总碳(TOC)去除及氧化剂分解规律,对催化矿化进行分析。结果表明:温度、催化剂、氧化剂、初始TOC质量浓度的增加均能不同程度地加速TOC去除,矿化半衰期t1/2更短。随温度、氧化剂浓度提高,H202矿化指数X先增加后减小,随初始TOC及催化剂质量浓度提高X分别增加和减小。提出了羟基自由基矿化机理,紫外可见分光光谱分析表明底物先被氧化为某些中间产物,再被矿化为CO2和H2O。 展开更多
关键词 H2O2 指数 矿化半衰期 ·OH 总碳(TOC)
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Effect of Land Use Pattern on Mineralization of Residual C and N from Plant Materials Decomposing Under Field Conditions 被引量:1
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作者 CHENGLILI WENQIXIAO 《Pedosphere》 SCIE CAS CSCD 1998年第4期311-316,共6页
Four kinds of plant materials (astragalus, azolla, rice straw and water hyacinth) were allowed to decompose for 10 years in two soils with different mineralogical characteristics in fields under upland and submerged c... Four kinds of plant materials (astragalus, azolla, rice straw and water hyacinth) were allowed to decompose for 10 years in two soils with different mineralogical characteristics in fields under upland and submerged conditions. Greater amounts of C and N from azolla were retained in soils throughout the 10-year experimental period compared to those from the other plant materials. The residual C Of all the plant materials in the two soils under upland conditions mineralized st rates corresponding to half-lives between 4.4-6.6 years,while the corresponding figures for thine under submerged conditions were between 6.5-13.1 years. Minerallization of residual organic N followed the same pattern as residual C. Compared to residual C, however, the mineralization rates of residual organic N in most cases were significantly lower and the percentages of added N regained in sons were higher. More N from plat materials was retained in the yellow-brown soil than in the red soil, but no consistent differences in the amounts of C from plant materials and in the mineralization rates of both residual C and residual organic N between the two soils could be found. 展开更多
关键词 HALF-LIFE MINERALIZATION residual C residual organic N
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