Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and ...Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and pseudomorphic conversion to SrC2 O4·H2O occurs. In the second step, SrC2 O4·H2O reacts with H2C2O4 to form H[Sr(C2 O4)1.5(H2O)]. Sr(HC2 O4)(C2 O4)0.5·H2 O crystallizes during cooling of the reaction mixture to room temperature if the solution reaches the saturation concentration of (H[Sr(C2O4)1.5(H2O)]. The aims of this study are the derivation of reaction rate equations and the determination of the kinetic parameters such as pre-exponential factor, apparent activation energy and order of H2C2O4 concentration for each reaction step.Fractional conversions of SrSO4 were calculated using the quantitative amounts of dissolved S and Sr. It was determined that the reaction rate increased at the initial time of reaction by increasing the temperature using solutions with approximately same H2C2O4 concentrations. The reaction extends very slowly after a certain time in solutions with low H2C2O4 concentration and ends by the formation of a protective layer of SrC2O4-H2O around the surfaces of solid particles. Fractional conversion of SrSO4 is increased by increasing concentration of H2C2O4 at constant temperature. Kinetic model equations were derived using shrinking core model for each step.展开更多
Prediction of the drilling penetration rate is one of the important parameters in mining operations. This parameter has a direct impact on the mine planning and cost of mining operations, Generally, effective paramete...Prediction of the drilling penetration rate is one of the important parameters in mining operations. This parameter has a direct impact on the mine planning and cost of mining operations, Generally, effective parameters on the penetration rate is divided into two classes： rock mass properties and specifications of the machine, The chemical components of intact rock have a direct effect in determining rock mechan- ical properties, Theses parameters usually have not been investigated in any research on the rock drill- ability, In this study, physical and mechanical properties of iron ore were studied based on the amount of magnetite percent, According to the results of the tests, the effective parameters on the pen- etration rate of the rotary drilling machines were divided into three classes： specifications of the machi- nes, rock mass properties and chemical component of intact rock, Then, the rock drillahility was studied using rock engineering systems, The results showed that feed, rotation, rock mass index and iron oxide percent have important effect on penetration rate, Then a quadratic equation with 0,896 determination coefficient has been obtained, Also, the results showed that chemical components can he described as new parameters in rotary drill penetration rate,展开更多
The conversion mechanism of Al-goethite under the action of different additives(lime or reductant for typical or reductive Bayer digestion)was investigated by thermodynamic calculation,XRD,and SEM-EDS.The results show...The conversion mechanism of Al-goethite under the action of different additives(lime or reductant for typical or reductive Bayer digestion)was investigated by thermodynamic calculation,XRD,and SEM-EDS.The results show that the formation of Fe-substituted hydrocalumite is crucial to converting Al-goethite to hematite during Bayer digestion by adding lime.However,the conversion proceeds more easily under the action of reductant due to the rapid formation of magnetite.Additionally,Bayer liquor composition significantly affects the product composition and also the conversion rate of Al-goethite.Compared to typical Bayer digestion with Al-goethite containing gibbsitic bauxite as raw material,the red mud yield of reductive Bayer digestion decreases from 39.02%to 31.19%,and the grade of TFe in red mud increases from 41.66%to 53.80%.展开更多
基金the financial support of the Scientific Research Projects Coordination Unit of Istanbul University (Project number: 17344 and 31088)
文摘Conversion of SrSO4 to acidic strontium oxalate hydrate(H[Sr(C2O4)1.5(H2O)]) in aqueous H2C2O4 solutions proceeds as a consecutive reaction. In the first step of the consecutive reaction, SrSO4 reacts with H2C2O4 and pseudomorphic conversion to SrC2 O4·H2O occurs. In the second step, SrC2 O4·H2O reacts with H2C2O4 to form H[Sr(C2 O4)1.5(H2O)]. Sr(HC2 O4)(C2 O4)0.5·H2 O crystallizes during cooling of the reaction mixture to room temperature if the solution reaches the saturation concentration of (H[Sr(C2O4)1.5(H2O)]. The aims of this study are the derivation of reaction rate equations and the determination of the kinetic parameters such as pre-exponential factor, apparent activation energy and order of H2C2O4 concentration for each reaction step.Fractional conversions of SrSO4 were calculated using the quantitative amounts of dissolved S and Sr. It was determined that the reaction rate increased at the initial time of reaction by increasing the temperature using solutions with approximately same H2C2O4 concentrations. The reaction extends very slowly after a certain time in solutions with low H2C2O4 concentration and ends by the formation of a protective layer of SrC2O4-H2O around the surfaces of solid particles. Fractional conversion of SrSO4 is increased by increasing concentration of H2C2O4 at constant temperature. Kinetic model equations were derived using shrinking core model for each step.
文摘Prediction of the drilling penetration rate is one of the important parameters in mining operations. This parameter has a direct impact on the mine planning and cost of mining operations, Generally, effective parameters on the penetration rate is divided into two classes： rock mass properties and specifications of the machine, The chemical components of intact rock have a direct effect in determining rock mechan- ical properties, Theses parameters usually have not been investigated in any research on the rock drill- ability, In this study, physical and mechanical properties of iron ore were studied based on the amount of magnetite percent, According to the results of the tests, the effective parameters on the pen- etration rate of the rotary drilling machines were divided into three classes： specifications of the machi- nes, rock mass properties and chemical component of intact rock, Then, the rock drillahility was studied using rock engineering systems, The results showed that feed, rotation, rock mass index and iron oxide percent have important effect on penetration rate, Then a quadratic equation with 0,896 determination coefficient has been obtained, Also, the results showed that chemical components can he described as new parameters in rotary drill penetration rate,
基金support provided by the National Natural Science Foundation of China(No.52104353)。
文摘The conversion mechanism of Al-goethite under the action of different additives(lime or reductant for typical or reductive Bayer digestion)was investigated by thermodynamic calculation,XRD,and SEM-EDS.The results show that the formation of Fe-substituted hydrocalumite is crucial to converting Al-goethite to hematite during Bayer digestion by adding lime.However,the conversion proceeds more easily under the action of reductant due to the rapid formation of magnetite.Additionally,Bayer liquor composition significantly affects the product composition and also the conversion rate of Al-goethite.Compared to typical Bayer digestion with Al-goethite containing gibbsitic bauxite as raw material,the red mud yield of reductive Bayer digestion decreases from 39.02%to 31.19%,and the grade of TFe in red mud increases from 41.66%to 53.80%.
