Skarn is the main altered rock type and is of great importance to mineralization and ore-prospecting in the Shizhuyuan area of Hunan province, China. Its features of petrography, mineralogy and geochemistry were st...Skarn is the main altered rock type and is of great importance to mineralization and ore-prospecting in the Shizhuyuan area of Hunan province, China. Its features of petrography, mineralogy and geochemistry were studied systematically. The results show that the skarn mainly consists of garnet skarn, secondary wollastonite-garnet skarn, tremolite-clinozoisite skarn, and few wolframine garnet skarn, idocrase-garnet skarn and wollastonite skarn with granoblastic texture, granular sheet crystalloblastic texture, and massive structure, disseminated structure, mesh-vein structure, comb structure, and banded structure. And, it is mainly composed of garnet, fluorite, chlorite, hornblende, epidote, tremolite, plagioclase, biotite, muscovite, plagioclase, quartz, idocrase, and calcite and so on. The chemical components mainly include SiO2, Al2O3, Fe2O3, MgO and CaO, and the trace elements and REEs consist of Li, Be, V, Co, Zn, Ga, Rb, Sr, Y, Ce, Nd, Pb and Bi, etc. And, the obvious fractionation exists between LREE and HREE, and it shows typical features of Nanling ore-forming granite for W？Sn polymetallic deposit. Skarn is derived from the sedimentary rock, such as limestone, mudstone, argillaceous rock, and few pelitic strips. It is affected by both Shetianqiao formation strata and Qianlishan granite during the diagenesis, indicating a strong reduction environment. The occurrence of skarn, whose mutation site is favorable to the mineralization enrichment, is closely related to the mineralization and prospecting.展开更多
The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located...The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.展开更多
South China is famous for the extensive magmatism and polymetallic mineralization that took place there in the Mesozoic. Shilu is a large porphyry–skarn Cu–Mo deposit in the Yangchun Basin, South China. The litholog...South China is famous for the extensive magmatism and polymetallic mineralization that took place there in the Mesozoic. Shilu is a large porphyry–skarn Cu–Mo deposit in the Yangchun Basin, South China. The lithology of the Shilu intrusion is granodiorite and quartz diorite, both of which are high-K calc-alkaline series, with high Sr([400 ppm) content along with low Y and Yb contents. Most of the samples have characteristics of adakite except for a few samples that have slightly higher Y and Yb contents, which may be plausibly explained by crustal contamination. Laser Ablation Inductively Coupled Plasma Mass Spectrometry zircon U–Pb dating revealed ages between 106.6 ± 1.3 and 103.9 ± 0.5 Ma, with multiple magmatic pulses. Molybdenite Re–Os isochron age of 102.2 ± 2.9 Ma(MSWD = 9.4) was determined, which is identical to the youngest zircon U–Pb age(103.9 ± 0.5 Ma) within error.The Shilu intrusion has high oxygen fugacity as indicated by high zircon Ce^(4+)/Ce^(3+) and Eu_N/Eu_N* ratios. Considering the geochemical characteristics(high Sr, and low Y and Yb contents), high oxygen fugacity, and copper mineralization of the Shilu intrusion, it was most likely formed by partial melting of a subducted young oceanic slab. Whole-rock Sr–Nd isotope-, zircon Hf isotope-, and whole-rock trace element analyses show that Shilu adakitic magmas may have interacted with type II enriched mantle and/or crustal materials during ascent. South China was affected by the Pacific tectonic regime to the east and the Neo-Tethys tectonic regime to the south in the Cretaceous. Based on the Pacific Plate drifting and rotation history, it is hard to explain how the Pacific Plate would have subducted and melted, forming adakitic rocks in the Shilu region. Considering the tectonic history of Southeast Asia and the South China Sea, the Neo-Tethys trench should have been much closer to the South China Block in the Cretaceous, and thus have had a greater impact on the South China Block. Based on the subduction direction, time of subduction,and distance between the Neo-Tethys subduction zone and the Shilu deposit, subduction of the Neo-Tethys ridge is the best mechanism for explaining the Shilu adakitic rocks and Cu–Mo mineralization.展开更多
The unconventional oil and gas resources presented in oil shales have meant these potential sources of hydrocarbons, which has become a research focus. China contains abundant oil shale resources, ranking fourth in th...The unconventional oil and gas resources presented in oil shales have meant these potential sources of hydrocarbons, which has become a research focus. China contains abundant oil shale resources, ranking fourth in the world, with ca. 7 254.48 x 108 t within 24 provinces, including 48 basins and 81 oil shale deposits. A- bout 48% of the total oil shale resources are concentrated in the eastern resource region, with a further 22% in the central resource region. 65 % of the total quantity of oil shale resources is present at depths of 0-500 m, with 17% of the total resources being defined as high-quality oil shales yielding more than 10% oil by weight. Chinese oil shale resources are generally hosted by Mesozoic sediments that account for 78% of the total re- sources. In terms of the geographical distribution of these resources, some 45% are located in plain regions, and different oil shale basins have various characteristics. The oil shale resources in China represent a highly prospective future source of hydrocarbons. These resources having potential use not only in power generation and oil refining but also in agriculture, metal and chemical productions, and environmental protection.展开更多
The southern Jiangxi Province(SJP) and northern Jiangxi-southern Anhui provinces(NJSAP) are the two most important tungsten metallogenic districts in South China. The SJP district is a well-known tungsten producer in ...The southern Jiangxi Province(SJP) and northern Jiangxi-southern Anhui provinces(NJSAP) are the two most important tungsten metallogenic districts in South China. The SJP district is a well-known tungsten producer in South China where distributes several ore concentrated areas such as the "Chongyi-Dayu-Shangyou", "Yudu" and "Longnan-Quanan-Dingnan"areas, with many large and super large tungsten deposits including the famous Xihuashan, Piaotang, Pangushan and Dajishan deposits. In recent years, major prospecting breakthrough for W-polymetallic resources has been made in the NJSAP district.Several large and super large W-Cu(Mo) deposits, such as the Dahutang, Zhuxi, Dongyuan and Baizhangyan deposits, are discovered. These deposits are all genetically associated with the Yanshanian(Mesozoic) granitic magmatism. In this study, a systematic comparison of the temporal and spatial distribution, petrology, geochronology, and geochemical characteristics of the tungsten-bearing granites between the SJP and NJSAP districts has been made, with an aim to improving the understanding of the petrogenesis of the granites and associated metal enrichment mechanisms in the two tungsten ore districts in South China. The following conclusions can be drawn:(1) The ages of the tungsten-bearing granites and associated mineralization are different in the two districts, in the SJP district the ages are mainly concentrated in 165–150 Ma, whereas in the NJSAP district it displays two age periods, one is 150–140 Ma(Late Jurassic-Early Cretaceous), and the other is 135–120 Ma(Early Cretaceous).(2) The tungsten-bearing granites from both the NJSAP and SJP districts are highly fractionated granitic rocks, but the SJP granites have experienced higher degree of fractional crystallization and more extensive fluid metasomatism than the NJSAP granites.(3) The petrogeneses of the tungsten-bearing granites from the two districts are different, those from the NJSAP district originated from partial melting of less mature sandstone-mudstone intercalated with meta-volcanic rocks of the Neoproterozoic Shuangqiaoshan Group which are both W and Cu enriched, in contrast those from the SJP district were likely derived from the highly mature,clay-rich mudstones of the Mesoproterozoic age which are only W enriched. In summary, the different source rocks with different metal enrichment features and different magmatic evolution and fractional degrees for the granites in the two districts might be the key factors that controlled the different matallogenic characteristics of tungsten ore deposits in the two districts in South China.展开更多
基金Project(41202051)supported by the National Natural Science Foundation of ChinaProject(2015CX008)supported by the Innovation-driven Plan in Central South University,China+4 种基金Project(2016JJ1022)supported by Hunan Provincial Natural Science Outstanding Youth Foundation of ChinaProject(CSUZC201601)supported by the Open-end Fund for the Valuable and Precision Instruments of Central South University,ChinaProject(2014T70886)supported by the Special Program of the Postdoctoral Science Foundation of ChinaProject(2012M521721)supported by China Postdoctoral Science FoundationProject(XKRZ[2014]76)supported by the Platform of Scientific and Technological Innovation for Hunan Youth,China
文摘Skarn is the main altered rock type and is of great importance to mineralization and ore-prospecting in the Shizhuyuan area of Hunan province, China. Its features of petrography, mineralogy and geochemistry were studied systematically. The results show that the skarn mainly consists of garnet skarn, secondary wollastonite-garnet skarn, tremolite-clinozoisite skarn, and few wolframine garnet skarn, idocrase-garnet skarn and wollastonite skarn with granoblastic texture, granular sheet crystalloblastic texture, and massive structure, disseminated structure, mesh-vein structure, comb structure, and banded structure. And, it is mainly composed of garnet, fluorite, chlorite, hornblende, epidote, tremolite, plagioclase, biotite, muscovite, plagioclase, quartz, idocrase, and calcite and so on. The chemical components mainly include SiO2, Al2O3, Fe2O3, MgO and CaO, and the trace elements and REEs consist of Li, Be, V, Co, Zn, Ga, Rb, Sr, Y, Ce, Nd, Pb and Bi, etc. And, the obvious fractionation exists between LREE and HREE, and it shows typical features of Nanling ore-forming granite for W？Sn polymetallic deposit. Skarn is derived from the sedimentary rock, such as limestone, mudstone, argillaceous rock, and few pelitic strips. It is affected by both Shetianqiao formation strata and Qianlishan granite during the diagenesis, indicating a strong reduction environment. The occurrence of skarn, whose mutation site is favorable to the mineralization enrichment, is closely related to the mineralization and prospecting.
基金supported by grants by the National Natural Science Foundation of China (No.41272097)the China Geological Survey Project (No.12120114016601)+1 种基金the Special Fund for Basic Scientific Research of Central Colleges, China University of Geosciences (Wuhan) (No.CUG120702)the Teaching Laboratory Foundation of China University of Geosciences (Wuhan) (No.SKJ2013085,SKJ2014010)
文摘The Yunkai Area is located at the southern South China Block and is part of the Qinzhou Bay-Hangzhou Bay Metallogenic Belt, which is a famous polymetallic mineralization belt. The Xinhua Pb–Zn–(Ag)deposit is located in the western part of Yunkai Area, with an abundance of Pubei batholiths. Zircon U–Pb geochronology of Pubei batholiths shows that crystallization age ranges from 251.9 ± 2.2 to 244.3 ± 1.8 Ma, thus belonging to Indosinian orogeny. Geochemistry and Sr isotopic compositions of the Pubei batholiths show that it is derived from the partial melting of large scale crustal melting during the stage of exhumation and uplifting of the lower-middle crust. In addition, strontium isotope of sphalerite from the Xinhua Pb–Zn–(Ag) deposit, has limited ranges in ^(87)Rb/^(86)Sr and ^(87)Sr/^(86)Sr, ranging from 0.4077 to 1.0449, and 0.718720 to 0.725245, respectively. The initial ^(87)Sr/^(86)Sr ratios of sphalerite ranges between 0.718720 and 0.725245, which is higher than that of upper continental crust and lower than that of the Pubei batholiths, illustrating the fluid might be derived from the mixing of Pubei pluton and upper continental crust.
基金supported by the DREAM project of MOST China 2016YFC0600408NSFC 91328204,41421062China Geological Survey (12120114015801)
文摘South China is famous for the extensive magmatism and polymetallic mineralization that took place there in the Mesozoic. Shilu is a large porphyry–skarn Cu–Mo deposit in the Yangchun Basin, South China. The lithology of the Shilu intrusion is granodiorite and quartz diorite, both of which are high-K calc-alkaline series, with high Sr([400 ppm) content along with low Y and Yb contents. Most of the samples have characteristics of adakite except for a few samples that have slightly higher Y and Yb contents, which may be plausibly explained by crustal contamination. Laser Ablation Inductively Coupled Plasma Mass Spectrometry zircon U–Pb dating revealed ages between 106.6 ± 1.3 and 103.9 ± 0.5 Ma, with multiple magmatic pulses. Molybdenite Re–Os isochron age of 102.2 ± 2.9 Ma(MSWD = 9.4) was determined, which is identical to the youngest zircon U–Pb age(103.9 ± 0.5 Ma) within error.The Shilu intrusion has high oxygen fugacity as indicated by high zircon Ce^(4+)/Ce^(3+) and Eu_N/Eu_N* ratios. Considering the geochemical characteristics(high Sr, and low Y and Yb contents), high oxygen fugacity, and copper mineralization of the Shilu intrusion, it was most likely formed by partial melting of a subducted young oceanic slab. Whole-rock Sr–Nd isotope-, zircon Hf isotope-, and whole-rock trace element analyses show that Shilu adakitic magmas may have interacted with type II enriched mantle and/or crustal materials during ascent. South China was affected by the Pacific tectonic regime to the east and the Neo-Tethys tectonic regime to the south in the Cretaceous. Based on the Pacific Plate drifting and rotation history, it is hard to explain how the Pacific Plate would have subducted and melted, forming adakitic rocks in the Shilu region. Considering the tectonic history of Southeast Asia and the South China Sea, the Neo-Tethys trench should have been much closer to the South China Block in the Cretaceous, and thus have had a greater impact on the South China Block. Based on the subduction direction, time of subduction,and distance between the Neo-Tethys subduction zone and the Shilu deposit, subduction of the Neo-Tethys ridge is the best mechanism for explaining the Shilu adakitic rocks and Cu–Mo mineralization.
基金Supported by the Ministry of Education of China Grants(OSR-1-03)
文摘The unconventional oil and gas resources presented in oil shales have meant these potential sources of hydrocarbons, which has become a research focus. China contains abundant oil shale resources, ranking fourth in the world, with ca. 7 254.48 x 108 t within 24 provinces, including 48 basins and 81 oil shale deposits. A- bout 48% of the total oil shale resources are concentrated in the eastern resource region, with a further 22% in the central resource region. 65 % of the total quantity of oil shale resources is present at depths of 0-500 m, with 17% of the total resources being defined as high-quality oil shales yielding more than 10% oil by weight. Chinese oil shale resources are generally hosted by Mesozoic sediments that account for 78% of the total re- sources. In terms of the geographical distribution of these resources, some 45% are located in plain regions, and different oil shale basins have various characteristics. The oil shale resources in China represent a highly prospective future source of hydrocarbons. These resources having potential use not only in power generation and oil refining but also in agriculture, metal and chemical productions, and environmental protection.
基金supported by the National Natural Science Foundation of China (Grant Nos. 41473042, 41503019)National Key R$D Program of China (Grant No. 2016YFC0600204)China Postdoctoral Science Foundation (Grant No. 2015M582297)
文摘The southern Jiangxi Province(SJP) and northern Jiangxi-southern Anhui provinces(NJSAP) are the two most important tungsten metallogenic districts in South China. The SJP district is a well-known tungsten producer in South China where distributes several ore concentrated areas such as the "Chongyi-Dayu-Shangyou", "Yudu" and "Longnan-Quanan-Dingnan"areas, with many large and super large tungsten deposits including the famous Xihuashan, Piaotang, Pangushan and Dajishan deposits. In recent years, major prospecting breakthrough for W-polymetallic resources has been made in the NJSAP district.Several large and super large W-Cu(Mo) deposits, such as the Dahutang, Zhuxi, Dongyuan and Baizhangyan deposits, are discovered. These deposits are all genetically associated with the Yanshanian(Mesozoic) granitic magmatism. In this study, a systematic comparison of the temporal and spatial distribution, petrology, geochronology, and geochemical characteristics of the tungsten-bearing granites between the SJP and NJSAP districts has been made, with an aim to improving the understanding of the petrogenesis of the granites and associated metal enrichment mechanisms in the two tungsten ore districts in South China. The following conclusions can be drawn:(1) The ages of the tungsten-bearing granites and associated mineralization are different in the two districts, in the SJP district the ages are mainly concentrated in 165–150 Ma, whereas in the NJSAP district it displays two age periods, one is 150–140 Ma(Late Jurassic-Early Cretaceous), and the other is 135–120 Ma(Early Cretaceous).(2) The tungsten-bearing granites from both the NJSAP and SJP districts are highly fractionated granitic rocks, but the SJP granites have experienced higher degree of fractional crystallization and more extensive fluid metasomatism than the NJSAP granites.(3) The petrogeneses of the tungsten-bearing granites from the two districts are different, those from the NJSAP district originated from partial melting of less mature sandstone-mudstone intercalated with meta-volcanic rocks of the Neoproterozoic Shuangqiaoshan Group which are both W and Cu enriched, in contrast those from the SJP district were likely derived from the highly mature,clay-rich mudstones of the Mesoproterozoic age which are only W enriched. In summary, the different source rocks with different metal enrichment features and different magmatic evolution and fractional degrees for the granites in the two districts might be the key factors that controlled the different matallogenic characteristics of tungsten ore deposits in the two districts in South China.
