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矿物质组分对低品质生物质热解过程的影响 被引量:5
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作者 彭定茂 张守玉 +4 位作者 王秀军 王健 谷立莹 刘洋 戴锋 《环境科学学报》 CAS CSCD 北大核心 2011年第10期2275-2281,共7页
通过酸洗脱除低品质生物质(鸡粪与猪粪)中的矿物质组分,并使用热重分析仪对酸洗前后样品的热解行为进行了研究.结果表明,由于两种农林废物的有机组成和矿物质含量不同,导致其热解行为差异较大.鸡粪中含有大量的CaCO3,其在高温下分解放出... 通过酸洗脱除低品质生物质(鸡粪与猪粪)中的矿物质组分,并使用热重分析仪对酸洗前后样品的热解行为进行了研究.结果表明,由于两种农林废物的有机组成和矿物质含量不同,导致其热解行为差异较大.鸡粪中含有大量的CaCO3,其在高温下分解放出CO2,并与鸡粪半焦中的碳发生气化反应.酸洗不但改变了禽畜粪便中矿物质的含量,而且改变了该废物中的有机组成,导致酸洗后样品热解行为的改变.运用一级反应动力学模型求取了热解动力学参数,发现模型的拟合度较好,酸洗后鸡粪的热解活化能较原样降低,而猪粪则相反. 展开更多
关键词 物质 禽畜粪便 热解 矿物质组分 预处理
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ICP-MS测定多组分维生素矿物质片中镁、铁、锌、铜、硒五种元素分析方法研究 被引量:1
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作者 李勇 黄泽贤 陈平 《生物化工》 2019年第3期88-91,共4页
目的:建立电感耦合等离子体质谱(ICP-MS)法测定多组分维生素矿物质片中镁、铁、锌、铜、硒5种元素含量。方法:用微波消解进行样品前处理;以铑(103Rh)为内标,采用ICP-MS进行测定,测量模式为碰撞池模式(KED),碰撞气流速5mL/min,采样深度5... 目的:建立电感耦合等离子体质谱(ICP-MS)法测定多组分维生素矿物质片中镁、铁、锌、铜、硒5种元素含量。方法:用微波消解进行样品前处理;以铑(103Rh)为内标,采用ICP-MS进行测定,测量模式为碰撞池模式(KED),碰撞气流速5mL/min,采样深度5mm,辅助气流速0.8L/min,雾化器流速1L/min;对所建立的方法进行了方法学验证。结果:5种元素标准曲线的相关系数均大于0.999;加标回收率在95.0%~105.0%;精密度试验RSD≤4%。结论:本文建立的方法样品用量少,分析速度快,灵敏度高,可用于多组分维生素矿物质片中5种元素的含量测定。 展开更多
关键词 元素 电感耦合等离子体质谱仪 组分维生素矿物质 微波消解 方法学验证
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制备条件对低品质生物质半焦燃烧特性的影响 被引量:4
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作者 王健 张守玉 +6 位作者 彭定茂 王秀军 颜慧磊 卢缘 卢运 郑帅 张哲鑫 《太阳能学报》 EI CAS CSCD 北大核心 2013年第11期1950-1956,共7页
研究利用热重分析仪考查不同制备条件(热解温度、热解升温速率、热解气氛)下制得的低品质生物质废物(鸡粪与猪粪)半焦的燃烧特性,并考察其中的矿物质组分对半焦燃烧性能的影响。结果表明:鸡粪半焦较猪粪半焦燃烧性能更好;制备条件不同,... 研究利用热重分析仪考查不同制备条件(热解温度、热解升温速率、热解气氛)下制得的低品质生物质废物(鸡粪与猪粪)半焦的燃烧特性,并考察其中的矿物质组分对半焦燃烧性能的影响。结果表明:鸡粪半焦较猪粪半焦燃烧性能更好;制备条件不同,所制半焦的燃烧特性不同;制焦过程中,升温速率的提高及水蒸气气氛均能提高禽畜粪便半焦的燃烧性能;禽畜粪便中矿物质组分对其半焦的反应性能具有极大的促进作用;随着制焦温度的升高,猪粪半焦的燃烧性能呈先增强后减弱的趋势。 展开更多
关键词 物质 半焦 燃烧特性 热解 矿物质组分
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气流床粉煤气化熔渣与其原煤灰特性比较 被引量:3
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作者 刘霞 许建良 +4 位作者 梁钦锋 刘海峰 于广锁 龚欣 王辅臣 《煤化工》 CAS 2017年第1期5-9,共5页
对气流床粉煤气化熔渣及其原煤灰特性进行了对比研究。采用X射线荧光光谱仪(XRF)、X射线衍射仪(XRD)分析了熔渣及煤灰的化学成分和矿物组成。测试了熔渣及煤灰的熔融及黏温特性,并利用热力学软件Fact Sage模拟计算了二者对应的四元平衡... 对气流床粉煤气化熔渣及其原煤灰特性进行了对比研究。采用X射线荧光光谱仪(XRF)、X射线衍射仪(XRD)分析了熔渣及煤灰的化学成分和矿物组成。测试了熔渣及煤灰的熔融及黏温特性,并利用热力学软件Fact Sage模拟计算了二者对应的四元平衡相图和特殊温度下熔体中的矿物质组成及其含量。结果表明,由于熔渣经历了高温气化、激冷过程,原煤灰与熔渣的化学成分和矿物质组成并不存在明显的对应关系;两样品熔融温度差别较小,真液相时黏温特性曲线几乎重合,在临界黏度温度(Tcv)时出现差异,随着温度的降低,熔渣的Tcv出现较早,黏度急剧增大至固相的温度较高。热力学模拟计算结果与实验结果相吻合。对原煤煤灰熔融性及黏温特性的分析,可以为工业气化炉的开车运行提供指导。 展开更多
关键词 气流床粉煤气化 熔渣 煤灰 灰熔融性温度 黏度 矿物质组分 化学成分
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Effects of Ca2+concentrations on accumulations of mineral elements in the components of Pteroceltis tatarinowii 被引量:4
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作者 方升佐 候常英 洑香香 《Journal of Forestry Research》 SCIE CAS CSCD 2003年第1期46-50,94,共页
The bark of Pteroceltis tatarinowii is a raw material for manufacturing Xuan Paper. The effects of Ca2+ concentrations on the accumulation of mineral elements in the bark, leaf and root of Pteroceltis tatarinowii were... The bark of Pteroceltis tatarinowii is a raw material for manufacturing Xuan Paper. The effects of Ca2+ concentrations on the accumulation of mineral elements in the bark, leaf and root of Pteroceltis tatarinowii were studied under controlled condi-tions. The types of Hoagland nutrient solution with three Ca2+ concentrations levels (200, 400 and 600 靏g-1) and a control (without Ca2+) were designed to culture Pteroceltis tatarinowii. After 6 months, contents of seven mineral elements including Ca, K, Mg, Mn, Zn, Cu and Na in the root, leaf and bark were analyzed. The results indicated that Ca accumulations content in the root, leaf and bark had positively relation with Ca2+ concentrations (200, 400, 600 靏g-1), and the order of the Ca content in the three components was root】leaf】bark. Ca content in the root treated with 600 靏g-1 Ca2+ concentrations was 5.5 times as high as that of the control, and about 1.4 times as high as that of the root treated in 200 and 400 靏/g Ca2+ concentrations respectively. On the contrary, K and Mg contents in the root, leaf and bark were negatively related to Ca2+ concentrations, especially in the bark, and their accumulation trend followed the order of leaf】root】bark. K content in the bark treated with 600 靏g-1 Ca2+ con-centrations was 39.3% of that of the control, and was 79.0% and 91.8% of that of the bark treated with 200 靏g-1 and 400靏g-1 Ca2+ concentrations respectively; Mg content in the bark treated with 600 靏g-1 Ca2+ concentrations was 23.4% of that of the control, and was 27.1% and 35.4% of that of the bark treated with 200 and 400 靏g-1 Ca2+ concentrations respectively. Com-pared with the control, the general tendency of Mn, Zn and Cu content decreased with increasing of Ca2+ concentrations and their contents were in the order: root】leaf】bark. Based on the results of this study, the experiment has been useful for providing academic bases in improving the bark quality of Pteroceltis tatarinowii on non-limestone soil. 展开更多
关键词 Pteroceltis tatarinowii Hoagland nutrient solution Ca2+ concentrations Mineral element COMPONENT
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Characteristics of humin fractions associated with inorganic minerals obtained by NaOH,and NaOH assisted with anthraquinone extraction procedures 被引量:1
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作者 韩桂洪 姜涛 +2 位作者 黄艳芳 张元波 李光辉 《Journal of Central South University》 SCIE EI CAS 2012年第8期2286-2290,共5页
The differences in XRD patterns, elemental compositions, FT-IR spectra and TG-DSC curves of extract residues obtained by NaOH, and NaOH assisted with anthraguinone (AQ) extraction procedures were studied. The extrac... The differences in XRD patterns, elemental compositions, FT-IR spectra and TG-DSC curves of extract residues obtained by NaOH, and NaOH assisted with anthraguinone (AQ) extraction procedures were studied. The extract residues are mainly comprised of humin fractions associated with inorganic minerals. XRD analysis shows that there is no typical peak of organic carbon because those organic humin fractions appear as a highly disordered substance. The peak of quartz is dominant. The elementary analysis shows that assistant AQ in NaOH solution can break the link of organic humic substances with inorganic minerals. And aromatization degree of humin fractions obtained by NaOH is smaller than that obtained by NaOH assisted with AQ. FT-IR analysis displays that various groups exist in those two humin fractions obtained by different extraction procedures. There are some differences in FT-IR curves between two humin fractions. TG-DSC analysis shows that thermal decomposition occurs during the heating of testing samples. By contrast, the humin fractions associated with inorganic minerals obtained by NaOH possess a higher thermal decomposition range. 展开更多
关键词 organic binder humin fraction infrared spectrum oxidized pellets
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