环保型复配阻燃剂在木塑复合材料中的应用进展

木塑复合材料(WPC)兼具木材的生态性和塑料的可加工性,是一类生态环保材料。基于当前WPC易燃且燃烧后产生有害气体,从而造成了对人体健康的危害和对环境的污染等问题,围绕进一步提升WPC的阻燃效率和满足环保条件进行了讨论,着重介绍了WPC的燃烧特性,综述了碳系、金属系、矿质系、磷系、硼系环保型阻燃剂与其他元素阻燃剂进行复配协同提升WPC阻燃抑烟的研究进展,对比单一阻燃剂,环保型复配阻燃剂在阻燃和环保方面具有优越性。同时,还对环保型WPC阻燃剂的未来发展趋势提出了展望和建议。

Effects of Ca^(2+)concentrations on accumulations of mineral elements in the components of Pteroceltis tatarinowii

The bark of Pteroce/tis tatarinowii is a raw material for manufacturing XuanPaper. The effects of Ca^(2+) concentrations on the accumulation of mineral elements in the bark,leaf and root of Pteroceltis tatarinowii were studied under controlled conditions. The types ofHoagland nutrient solution with three Ca^(2+) concentrations levels (200, 400 and 600 μg·g^(-1))and a control (without Ca^(2+)) were designed to culture Pteroceltis tatarinowii. After 6 months,contents of seven mineral elements including Ca, K, Mg, Mn, Zn, Cu and Na in the root, leaf and barkwere analyzed. The results indicated that Ca accumulations content in the root, leaf and bark hadpositively relation with Ca^(2+) concentrations (200, 400, 600 μg · g^(-1)), and the order of theCa content in the three components was root>leaf>bark. Ca content in the root treated with 600 μg·g^(-1) Ca^(2+) concentrations was 5.5 times as high as that of the control, and about 1.4 times ashigh as that of the root treated in 200 and 400 μg/g Ca^(2+) concentrations respectively. On thecontrary, K and Mg contents in the root, leaf and bark were negatively related to Ca^(2+)concentrations, especially in the bark, and their accumulation trend followed the order ofleaf>root>bark. K content in the bark treated with 600 μg ·g^(-1) Ca^(2+) concentrations was 39.3%of that of the control, and was 79.0% and 91.8% of that of the bark treated with 200 μg ·g^(-1)and 400 μg ·g^(-1) Ca^(2+) concentrations respectively; Mg content in the bark treated with 600μg ·g^(-1) Ca^(2+) concentrations was 23.4% of that of the control, and was 27.1% and 35.4% ofthat of the bark treated with 200 and 400 μg·g^(-1) Ca^(2+) concentrations respectively. Comparedwith the control, the general tendency of Mn, Zn and Cu content decreased with increasing of Ca^(2+)concentrations and their contents were in the order: root>leaf>bark. Based on the results of thisstudy, the experiment has been useful for providing academic bases in improving the bark quality ofPteroceltis tatarinowii on non-limestone soil.

Rule of oxygen transmission in dump leaching

According to the chemical equations, the flux and concentration of oxygen required during bacterial lea- ching sulfuric mineral were investigated; the rule of air bubble transmitted in granular was researched in the Dump Leaching Plant of Dexing Copper Mine. The results show that lack of oxygen in dump leaching is the critical factor of restricting leaching reaction. Pyrite is the primary oxygen-consuming mineral in bioleaching. When its content is too high, it needs a great deal of oxygen for reaction and competes for the finite oxygen with objective minerals, and thus the leaching velocity decreases greatly. The average size of ore particles and diameter of bubbles are the key parameters affecting the mass transfer coefficient. Reverse analysis was adopted, and it shows that 44.8 m^3 air per unit ore can meet the requirement of production if the molar ratio of pyrite to chalcopyrite is 10.

Two Arbuscular Mycorrhizal Fungi Colonizing Maize Under Different Phosphorus Regimes in a Compartment Cultivation System

A modified glass bead compartment cultivation system was used tocompare some chemical and biolog- ical properties of the twoarbuscular mycorrhizal (AM) fungi Glmomus mosseae and Glomusversiforme using maize (Zea mays) as the host plant with four addedlevels of available phosphorus (P). The proportion of host plant rootlength infected was determined t harvest. Shoot and root yields andnutrient concentra- tions were determined, together with the nutrientconcentrations in the AM fungal external mycelium. The morphology ofvarious mycorrhizal structures of the two AM fungi was also comparedby microscopic obser- vation.

Improve power quality of coal mine power network based on gray system theory

Unified Power Quality Controller（UPQC） was proposed to comprehensively improve power quality of coal mine power network and its basic structure and operation principle was introduced. In order to overcome time lag of Active Power Filter（APF） in compensating harmonic and reactive current, a novel method based on gray system theory was proposed to predict harmonic current and other distortion component. The mathematical model of component to be compensated was constructed by data sequence of distortion component, which could exactly forecast compensation signal of next period. The optimal control strategy was selected according to the principle of output signal approaching component to be compensated as near as possible. Before predicating each time the oldest data was eliminated while the latest data was added to data sequence. Then new predication model was established once again. The results show that the method can always construct mathematical model with variation of system parameters, reflect the latest state of system and not increase calculation quantity. The feasible and effective control strategy can improve power quality of coal mine power network.

Application of GPS technology to build a mine-subsidence observation station

We propose the design of an observation station to establish a reliable datum for displacement and deformation analysis at the first working-face subsidence observation station of Liuzhuang Mine. The design considers various geologic and mining con-ditions. Having analyzed the aims of the joint survey and the comprehensive survey, we propose design principles, and work modes, for adopting GPS technology as the position measuring technique to be used in these two stages. Baseline vectors and spatial ad-justments of the GPS network were calculated after study of data processing and quality estimation methods. A coordinate system transformation and error estimates of the transformed GPS network data are discussed. The error estimates in all stages show that the GPS control network of the observation station has sufficient accuracy and is highly efficient. The network thus provides a reli-able datum for analyzing the laws of surface displacement and deformation induced by mining.

3D HIGH RESOLUTION SEISMIC PROSPECTING IN MINING AREAS,XIEQIAO COLLIERY

3D seismic prospecting in mining areas of Xieqiao Colliery is a successfulmodel for an advancement from the resource prospecting to mining prospecting stagein coal fields. Its results have proved that faults with a throw of 5-10 m can be detected in an area with good seismogeologic conditions by using 3D seismic technique.Detection of underground tunnels for the first time utilizing 3D seismic data indicates that subsided columns, gotten and mine goaf can be detected using 3D seismic technique, so it has a broad applied prospect.

Numerical simulation of deepwater deployment for offshore structures with deploying cables

Deepwater deployment of offshore structures in different sea states was investigated. The whole deployment system was modeled as a lumped mass model, and discretization scheme for cable geometry and methodology for calculating the internal and external force acting on deploying cable were presented. The deployment model suitable for the time-varying length of deploying cable was specified. The free-surface flow fields together with the ship motions were used to calculate dynamic tension in the deploying cable during deployment of the structure. The deployment of deep sea mining system which was a typical subsea working system was employed. Based on lumped mass analysis model and parameters of deep sea mining system, numerical simulations were performed, and dynamic load and dynamic amplification factor(DAF) with different cable parameters, deploying velocities and sea states were obtained. It is shown that cable parameters and amplitudes of ocean waves can significantly influence the dynamic load and DAF, and the time-varying natural period of deploying system is a dominant factor, while the effect of deploying velocity is not obvious.

Slope stability analysis of Southern slope of Chengmenshan copper mine,China

The engineering geology and hydrogeology in the southern slope of Chengmenshan copper mine are very complicated,because there is a soft-weak layer between two kinds of sandstones.Field investigations demonstrate that some instability problems might occur in the slope.In this research,the southern slope,which is divided into six sections(I-0,I-1,I-2,II-0,II-1 and II-2),is selected for slope stability analysis using limit equilibrium and numerical method.Stability results show that the values of factor of safety(FOS) of sections I-0,I-1 and I-2 are very low and slope failure is likely to happen.Therefore reinforcement subjected to seismic,water and weak layer according to sections were carried out to increase the factor of safety of the three sections,two methods were used;grouting with hydration of cement and water to increase the cohesion(c) and pre-stressed anchor.Results of reinforcement showed that factor of safety increased more than 1.15.

Zeolite diagenesis and its control on petroleum reservoir quality of Permian in northwestern margin of Junggar Basin,China

Recently, silicate diagenesis has been the focus of many studies because of its impact on porosity and permeability in sedimentary rocks. In the process of diagenetic evolution, the crystallization, cementation, and corrosion of zeolite （as a diagenetic mineral） have different effects on properties of Permian reservoirs in the study area. In the Permian sediments in the no,inwestern margin of the Junggar Basin, Zeolite minerals have formed during diagenesis in an open hydrologic system, related to the hydration of abundant volcanic glass. Chemical property of groundwater, pH of pore water, cation property and ratios have directly influenced the transformation among various zeolites and the dissolution of zeolite mineral. The main species of zeolite include analcime, heulandite, and laumontite. Transformations of these minerals during diagenesis are： volcanic glass→ clinoptilolite→analcime→heulandite→laumontite. Corrosion of analcime obviously improved reservoir quality. Extensive heulandite cementation developed and intensively reduced reservoir pore spaces. Early zeolite cementation protected pore structure against compaction and provided substance for late dissolution. The dissolution of analcime was closely related with the organic acid recharged by hydrocarbon source rocks and the NaHCO3 type formation water in the Permian, and was sensitive to permeability of rocks. Within the CaCl2 type formation water, heulandite and laumontite were hardly dissolved. In the study area, the belt with dissolved analcime is the area for the development of secondary pores and favorable reservoirs.

Tribological evaluation of refined,bleached and deodorized palm stearin using four-ball tribotester with different normal loads

The effects of the mechanical factors with applied loads on the tribological performance of refined,bleached and deodorised(RBD) palm stearin(PS) were studied using a four-ball tribotester.All the RBD PS results were simultaneously compared with the additive-free paraffinic mineral oil(PMO).The experiments were carried out using different loads with a constant speed in order to gain a better understanding of the mechanical processes that occurred during the experiment.For each experiment,the temperature was increased to 75 °C and was run for 1 h.In a mechanical system,lubricant plays an important role in reducing wear and friction.PS exists as a semi-solid at room temperature after the fractionation process from oil palm.Due to the increasing rate of pollution to the environment,vegetable oil was chosen as the test lubricant with regard to its biodegradability.Other advantages of vegetable oil are that it is more easily harvestable and non-toxic compared to petroleum-based oil,which made it a suitable candidate.From the experiment,RBD PS is found to have a better friction constraint reduction compared with additive-free PMO.

Modulation of Soil Particle Size and Nutrient Availability in the Maize Rhizosheath

Root exudates,microorganism colonization and soil aggregates together form the rhizosheath,a special cylinder of micro-ecosystem adhering to the root surface.To study how the rhizosheath affects soil structure and nutrient distribution,we analyzed the impact of maize rhizosheath on soil particle size and nutrient availability in pot and field experiments.The results showed that there was a significant size decrease of soil particles in the rhizosheath.Meanwhile,the soil mineral nitrogen in the rhizosheath was significantly higher than that in the rhizosphere or bulk soil at tasseling and maturity stages of maize.The contents of Fe and Mn were also differentially altered in the rhizosheath.Rhizosheath development,indicated by a dry weight ratio of rhizosheath soil to the root,was relatively independent of root development during the whole experimental period.The formation of maize rhizosheath contributed to the modulation of soil particle size and nutrient availability.The subtle local changes of soil physical and chemical properties may have profound influence on soil formation,rhizospheric ecosystem initiation,and mineral nutrient mobilization over the long history of plant evolution and domestication.